Optical and Morphological Study of Hydroxyapatite on Titanium Dioxide Particles for Photovoltaic Applications

In this study, a natural mineral termed hydroxyapatite (HA) (Ca10(PO4)6(OH)2) was produced with TiO2 stoichiometrically by normal sol-gel process. An investigation on how the different percentage weights of HA on TiO2 can affect its optical and morphological properties was carried out, while the...

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Main Authors: Yunana Tanko, Haruna Ali, Muhammad Y Onimisi
Format: Article
Language:English
Published: Department of Physics, Kaduna State University, Nigeria 2022-11-01
Series:Physics Access
Subjects:
Online Access:https://physicsaccess.com/articles/published/PA-JPET-SPECIAL_37.pdf
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author Yunana Tanko
Haruna Ali
Muhammad Y Onimisi
author_facet Yunana Tanko
Haruna Ali
Muhammad Y Onimisi
author_sort Yunana Tanko
collection DOAJ
description In this study, a natural mineral termed hydroxyapatite (HA) (Ca10(PO4)6(OH)2) was produced with TiO2 stoichiometrically by normal sol-gel process. An investigation on how the different percentage weights of HA on TiO2 can affect its optical and morphological properties was carried out, while the morphological nature and elemental composition were verified through scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDX) analysis. Consequently UV–visible spectroscopy was used to measure the absorbance data, where optical constants such as absorption coefficient, extension coefficient, refractive index, transmittance, absorbance, thermal conductivity, the electron-phonon interaction and steepness parameter were evaluated. According to the optical examination, the transmittance in the visible range is between (400 and 800 nm), and the absorption response in the UV region is between (200 and 400 nm) with an absorption edge occurring between (650 and 950 nm). The value of the absorption coefficient (α) and extension coefficient (k) of HA/TiO2 increased with an increase in the percentage weight (wt%) of HA. Equally, the optical conductivity increases with an increase in photon energy. In addition, the band gap energy decreases as the percentage weight of HA increases.
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spelling doaj.art-7eeb057dbbf6475697476f1d7c2f1de82023-02-02T16:20:55ZengDepartment of Physics, Kaduna State University, NigeriaPhysics Access2714-500X2756-38982022-11-0123 (SP/ISS/2022/01)172910.47514/phyaccess.sp.iss.2022.1.004Optical and Morphological Study of Hydroxyapatite on Titanium Dioxide Particles for Photovoltaic ApplicationsYunana Tanko0Haruna Ali1Muhammad Y Onimisi2Department of Physics, Kaduna State college of Education Gidan Waya, Kaduna, NigeriaDepartment of Physics, Nigerian Defence Academy, Kaduna, NigeriaDepartment of Physics, Nigerian Defence Academy, Kaduna, NigeriaIn this study, a natural mineral termed hydroxyapatite (HA) (Ca10(PO4)6(OH)2) was produced with TiO2 stoichiometrically by normal sol-gel process. An investigation on how the different percentage weights of HA on TiO2 can affect its optical and morphological properties was carried out, while the morphological nature and elemental composition were verified through scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDX) analysis. Consequently UV–visible spectroscopy was used to measure the absorbance data, where optical constants such as absorption coefficient, extension coefficient, refractive index, transmittance, absorbance, thermal conductivity, the electron-phonon interaction and steepness parameter were evaluated. According to the optical examination, the transmittance in the visible range is between (400 and 800 nm), and the absorption response in the UV region is between (200 and 400 nm) with an absorption edge occurring between (650 and 950 nm). The value of the absorption coefficient (α) and extension coefficient (k) of HA/TiO2 increased with an increase in the percentage weight (wt%) of HA. Equally, the optical conductivity increases with an increase in photon energy. In addition, the band gap energy decreases as the percentage weight of HA increases.https://physicsaccess.com/articles/published/PA-JPET-SPECIAL_37.pdfhydroxyapatitetitanium dioxideoptical band gapsteepnessnanoparticlesphonon
spellingShingle Yunana Tanko
Haruna Ali
Muhammad Y Onimisi
Optical and Morphological Study of Hydroxyapatite on Titanium Dioxide Particles for Photovoltaic Applications
Physics Access
hydroxyapatite
titanium dioxide
optical band gap
steepness
nanoparticles
phonon
title Optical and Morphological Study of Hydroxyapatite on Titanium Dioxide Particles for Photovoltaic Applications
title_full Optical and Morphological Study of Hydroxyapatite on Titanium Dioxide Particles for Photovoltaic Applications
title_fullStr Optical and Morphological Study of Hydroxyapatite on Titanium Dioxide Particles for Photovoltaic Applications
title_full_unstemmed Optical and Morphological Study of Hydroxyapatite on Titanium Dioxide Particles for Photovoltaic Applications
title_short Optical and Morphological Study of Hydroxyapatite on Titanium Dioxide Particles for Photovoltaic Applications
title_sort optical and morphological study of hydroxyapatite on titanium dioxide particles for photovoltaic applications
topic hydroxyapatite
titanium dioxide
optical band gap
steepness
nanoparticles
phonon
url https://physicsaccess.com/articles/published/PA-JPET-SPECIAL_37.pdf
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AT muhammadyonimisi opticalandmorphologicalstudyofhydroxyapatiteontitaniumdioxideparticlesforphotovoltaicapplications