Mechanical Behaviour of Multifunctional Epoxy/Hollow Glass Microspheres/Paraffin Microcapsules Syntactic Foams for Thermal Management
Epoxy/hollow glass microsphere (HGM) syntactic foams (SFs) are peculiar materials developed to combine low density, low thermal conductivity, and elevated mechanical properties. In this work, multifunctional SFs endowed with both structural and thermal management properties were produced for the fir...
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| Format: | Article |
| Language: | English |
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MDPI AG
2021-08-01
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| Series: | Polymers |
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| Online Access: | https://www.mdpi.com/2073-4360/13/17/2896 |
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| author | Francesco Galvagnini Giulia Fredi Andrea Dorigato Luca Fambri Alessandro Pegoretti |
| author_facet | Francesco Galvagnini Giulia Fredi Andrea Dorigato Luca Fambri Alessandro Pegoretti |
| author_sort | Francesco Galvagnini |
| collection | DOAJ |
| description | Epoxy/hollow glass microsphere (HGM) syntactic foams (SFs) are peculiar materials developed to combine low density, low thermal conductivity, and elevated mechanical properties. In this work, multifunctional SFs endowed with both structural and thermal management properties were produced for the first time, by combining an epoxy matrix with HGM and a microencapsulated phase change material (PCM) having a melting temperature of 43 °C. Systems with a total filler content (HGM + PCM) up to 40 vol% were prepared and characterized from the mechanical point of view with a broad experimental campaign comprising quasi-static, impact, and fracture toughness tests. The experimental results were statistically treated and fitted with a linear model, to produce ternary phase diagrams to provide a comprehensive interpretation of the mechanical behaviour of the prepared foams. In quasi-static tests, HGM introduction helps to retain the specific tensile elastic modulus and to increase the specific compressive modulus. The brittle nature of HGMs decreases the Charpy impact properties of the SFs, while the PCM insertion improve their toughness. This result is confirmed in K<sub>IC</sub> and G<sub>IC</sub> tests, where the composition with 20 vol% of PCM shows an increase of 80% and 370% in K<sub>IC</sub> and G<sub>IC</sub> in to neat epoxy, respectively. The most promising compositions are those combining PCM and HGMs with a total particle volume fraction up to 40 vol%, thanks to their optimal combination of thermal management capability, lightness, thermal insulation, and mechanical properties. The ability to fine-tune the properties of the SFs, together with the acquired thermal energy storage (TES) capability, confirm the great potential of these multifunctional materials in automotive, electronics, and aerospace industries. |
| first_indexed | 2024-03-10T08:05:58Z |
| format | Article |
| id | doaj.art-7efbe2d69d714e4cad1966617e4291de |
| institution | Directory Open Access Journal |
| issn | 2073-4360 |
| language | English |
| last_indexed | 2024-03-10T08:05:58Z |
| publishDate | 2021-08-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Polymers |
| spelling | doaj.art-7efbe2d69d714e4cad1966617e4291de2023-11-22T11:04:58ZengMDPI AGPolymers2073-43602021-08-011317289610.3390/polym13172896Mechanical Behaviour of Multifunctional Epoxy/Hollow Glass Microspheres/Paraffin Microcapsules Syntactic Foams for Thermal ManagementFrancesco Galvagnini0Giulia Fredi1Andrea Dorigato2Luca Fambri3Alessandro Pegoretti4INSTM Research Unit, Department of Industrial Engineering, University of Trento, Via Sommarive 9, 38123 Trento, ItalyINSTM Research Unit, Department of Industrial Engineering, University of Trento, Via Sommarive 9, 38123 Trento, ItalyINSTM Research Unit, Department of Industrial Engineering, University of Trento, Via Sommarive 9, 38123 Trento, ItalyINSTM Research Unit, Department of Industrial Engineering, University of Trento, Via Sommarive 9, 38123 Trento, ItalyINSTM Research Unit, Department of Industrial Engineering, University of Trento, Via Sommarive 9, 38123 Trento, ItalyEpoxy/hollow glass microsphere (HGM) syntactic foams (SFs) are peculiar materials developed to combine low density, low thermal conductivity, and elevated mechanical properties. In this work, multifunctional SFs endowed with both structural and thermal management properties were produced for the first time, by combining an epoxy matrix with HGM and a microencapsulated phase change material (PCM) having a melting temperature of 43 °C. Systems with a total filler content (HGM + PCM) up to 40 vol% were prepared and characterized from the mechanical point of view with a broad experimental campaign comprising quasi-static, impact, and fracture toughness tests. The experimental results were statistically treated and fitted with a linear model, to produce ternary phase diagrams to provide a comprehensive interpretation of the mechanical behaviour of the prepared foams. In quasi-static tests, HGM introduction helps to retain the specific tensile elastic modulus and to increase the specific compressive modulus. The brittle nature of HGMs decreases the Charpy impact properties of the SFs, while the PCM insertion improve their toughness. This result is confirmed in K<sub>IC</sub> and G<sub>IC</sub> tests, where the composition with 20 vol% of PCM shows an increase of 80% and 370% in K<sub>IC</sub> and G<sub>IC</sub> in to neat epoxy, respectively. The most promising compositions are those combining PCM and HGMs with a total particle volume fraction up to 40 vol%, thanks to their optimal combination of thermal management capability, lightness, thermal insulation, and mechanical properties. The ability to fine-tune the properties of the SFs, together with the acquired thermal energy storage (TES) capability, confirm the great potential of these multifunctional materials in automotive, electronics, and aerospace industries.https://www.mdpi.com/2073-4360/13/17/2896syntactic foamsepoxyglass microspheresthermal energy storagephase change materialsthermal properties |
| spellingShingle | Francesco Galvagnini Giulia Fredi Andrea Dorigato Luca Fambri Alessandro Pegoretti Mechanical Behaviour of Multifunctional Epoxy/Hollow Glass Microspheres/Paraffin Microcapsules Syntactic Foams for Thermal Management Polymers syntactic foams epoxy glass microspheres thermal energy storage phase change materials thermal properties |
| title | Mechanical Behaviour of Multifunctional Epoxy/Hollow Glass Microspheres/Paraffin Microcapsules Syntactic Foams for Thermal Management |
| title_full | Mechanical Behaviour of Multifunctional Epoxy/Hollow Glass Microspheres/Paraffin Microcapsules Syntactic Foams for Thermal Management |
| title_fullStr | Mechanical Behaviour of Multifunctional Epoxy/Hollow Glass Microspheres/Paraffin Microcapsules Syntactic Foams for Thermal Management |
| title_full_unstemmed | Mechanical Behaviour of Multifunctional Epoxy/Hollow Glass Microspheres/Paraffin Microcapsules Syntactic Foams for Thermal Management |
| title_short | Mechanical Behaviour of Multifunctional Epoxy/Hollow Glass Microspheres/Paraffin Microcapsules Syntactic Foams for Thermal Management |
| title_sort | mechanical behaviour of multifunctional epoxy hollow glass microspheres paraffin microcapsules syntactic foams for thermal management |
| topic | syntactic foams epoxy glass microspheres thermal energy storage phase change materials thermal properties |
| url | https://www.mdpi.com/2073-4360/13/17/2896 |
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