Fully Integrated Photoacoustic NO<sub>2</sub> Sensor for Sub-ppb Level Measurement

A fully integrated photoacoustic nitrogen dioxide (NO<sub>2</sub>) sensor is developed and demonstrated. In this sensor, an embedded photoacoustic cell was manufactured by using an up-to-date 3D printing technique. A blue laser diode was used as a light source for excitation of photoacou...

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Bibliographic Details
Main Authors: Yang Dong, Mingsi Gu, Gongdong Zhu, Tu Tan, Kun Liu, Xiaoming Gao
Format: Article
Language:English
Published: MDPI AG 2020-02-01
Series:Sensors
Subjects:
Online Access:https://www.mdpi.com/1424-8220/20/5/1270
Description
Summary:A fully integrated photoacoustic nitrogen dioxide (NO<sub>2</sub>) sensor is developed and demonstrated. In this sensor, an embedded photoacoustic cell was manufactured by using an up-to-date 3D printing technique. A blue laser diode was used as a light source for excitation of photoacoustic wave in the photoacoustic cell. The photoacoustic wave is detected by a sensitive microelectromechanical system (MEMS) microphone. Homemade circuits are integrated into the sensor for laser diode driving and signal processing. The sensor was calibrated by using a chemiluminescence NO&#8722;NO<sub>2</sub>&#8722;NO<sub>X</sub> gas analyzer. And the performance of this sensor was evaluated. The linear relationship between photoacoustic signals and NO<sub>2</sub> concentrations was verified in a range of below 202 ppb. The limit of detection was determined to 0.86 ppb with an integration time of 1 s. The corresponding normalized noise equivalent absorption was 2.0 &#215; 10<sup>&#8722;8</sup> cm<sup>&#8722;1</sup>∙W∙Hz<sup>&#8722;1/2</sup>. The stability and the optimal integration time were evaluated with an Allan deviation analysis, from which a detection limit of 0.25 ppb at the optimal integration time of 240 s was obtained. The sensor was used to measure outdoor air and the results agree with that obtained from the NO&#8722;NO<sub>2</sub>&#8722;NO<sub>X</sub> gas analyzer. The low-cost and portable photoacoustic NO<sub>2</sub> sensor has a potential application for atmospheric NO<sub>2</sub> monitoring.
ISSN:1424-8220