An experimental study of the effect of water and chlorine on plagioclase nucleation and growth in mafic magmas: application to mafic pegmatites
<p>In this study, the effects of H<span class="inline-formula"><sub>2</sub></span>O and Cl on the grain size and nucleation delay of plagioclase in basaltic magma were investigated using dynamic and equilibrium experiments at 1150 <span class="inline-f...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Copernicus Publications
2023-12-01
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| Series: | European Journal of Mineralogy |
| Online Access: | https://ejm.copernicus.org/articles/35/1111/2023/ejm-35-1111-2023.pdf |
| Summary: | <p>In this study, the effects of H<span class="inline-formula"><sub>2</sub></span>O and Cl on the grain size and nucleation delay of plagioclase in basaltic magma were investigated using dynamic and equilibrium experiments at 1150 <span class="inline-formula"><sup>∘</sup></span>C, 300 MPa, and oxygen fugacity between FMQ <span class="inline-formula">−</span> 1.65 and FMQ <span class="inline-formula">+</span> 0.05 (fayalite–magnetite–quartz). Each experiment consisted of five samples of basaltic composition (from the Hamn intrusion in Northern Norway) containing varying amounts of H<span class="inline-formula"><sub>2</sub></span>O (up to 2 wt %) and Cl (up to 1 wt %). The equilibrium experiments were used as a reference frame for the phase assemblage, geochemical composition, and liquidus temperatures and were compared to thermodynamic models using MELTS software. Experimental phase abundances and plagioclase compositions are in good agreement with the predictions of MELTS. The dynamic experiments were initially heated above the liquidus temperature to destroy crystal nuclei and then kept at 1150 <span class="inline-formula"><sup>∘</sup></span>C for 100, 250, or 1800 min. These experiments show that as the concentration of H<span class="inline-formula"><sub>2</sub></span>O in the melt increases, plagioclase nucleation is delayed, plagioclase abundance decreases, but its size increases. Therefore, the addition of H<span class="inline-formula"><sub>2</sub></span>O seems to favor plagioclase growth at the expense of nucleation. Thermodynamic and kinetic calculations corroborate an increase in the nucleation delay of plagioclase with increasing H<span class="inline-formula"><sub>2</sub></span>O content dissolved in the melt, suggesting that H<span class="inline-formula"><sub>2</sub></span>O decreases the undercooling of the silicate melt. The addition of Cl also seems to delay plagioclase nucleation, although this is not supported by kinetic calculations. Increasing the Cl content decreases plagioclase abundance but does not significantly affect its size.</p>
<p>The homogeneous pegmatitic pockets of the mafic–ultramafic Hamn intrusion exhibit several petrological and geochemical features, suggesting that H<span class="inline-formula"><sub>2</sub></span>O and Cl enrichment in the silicate melt was the origin of the pegmatitic texture. The experimental results presented here indicate that H<span class="inline-formula"><sub>2</sub></span>O, rather than Cl, may have played an important role in the formation of the pegmatitic texture.</p> |
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| ISSN: | 0935-1221 1617-4011 |