Recovery of Oil in Limestone with Cationic Surfactant: Investigation of the Adsorption, Wettability, and Spontaneous Imbibition

The performance of petroleum recovery methods is dependent on the characteristics of the reservoir rock, oil quality, and formation water. One fundamental feature for considering petroleum recovery methods is the wettability of the rock reservoir. Also, this feature impacts the displacement of fluid...

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Main Authors: Vanessa Santanna, Tereza Castro Dantas, Allan Neves, Juliana Lima, Camila Nóbrega Pessoa
Format: Article
Language:English
Published: Reaserch Institute of Petroleum Industry 2018-07-01
Series:Journal of Petroleum Science and Technology
Subjects:
Online Access:https://jpst.ripi.ir/article_889_f5062a31f0f6636aa150f5b93e97f058.pdf
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author Vanessa Santanna
Tereza Castro Dantas
Allan Neves
Juliana Lima
Camila Nóbrega Pessoa
author_facet Vanessa Santanna
Tereza Castro Dantas
Allan Neves
Juliana Lima
Camila Nóbrega Pessoa
author_sort Vanessa Santanna
collection DOAJ
description The performance of petroleum recovery methods is dependent on the characteristics of the reservoir rock, oil quality, and formation water. One fundamental feature for considering petroleum recovery methods is the wettability of the rock reservoir. Also, this feature impacts the displacement of fluids in the rock reservior. In the case of the limestone, which normally features oil wettability, enhanced recovery methods are responsible for altering surface wettability. In this study, the effect of concentration of a cationic surfactant in the oil recovery from limestone is shown. In these tests, finite-bath technique was used to investigate adsorption by varying the amount of adsorbent and contact time. By carrying out contact angle assays, the wettability of the limestone was assessed. In addition, the oil recovery was effected by spontaneous imbibition. In this study, the limestone samples with solutions of CTAB in the concentrations of 0.8596 g/L and 1.2280 g/L, using a 2% KCl solution are treated. The results showed enhanced adsorption of CTAB at the CMC. The nature of this phenomenon did not induce changes in the wettability of the rock, which was confirmed by the contact angle measurements. In the spontaneous imbibition, more oil could be recovered when using a CTAB below the CMC, possibly due to less intense adsorption by the limestone.
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spelling doaj.art-7f6ec68258214397a5d4668fc05e71bb2022-12-22T03:41:08ZengReaserch Institute of Petroleum IndustryJournal of Petroleum Science and Technology2251-659X2645-33122018-07-0183728010.22078/jpst.2017.2701.1460889Recovery of Oil in Limestone with Cationic Surfactant: Investigation of the Adsorption, Wettability, and Spontaneous ImbibitionVanessa Santanna0Tereza Castro Dantas1Allan Neves2Juliana Lima3Camila Nóbrega Pessoa4Federal University of Rio Grande do NorteFederal University of Rio Grande do NorteFederal University of Rio Grande do NorteFederal University of Rio Grande do NorteDepartment of Petroleum Engineering, Federal University of Rio Grande do Norte, Natal, BrazilThe performance of petroleum recovery methods is dependent on the characteristics of the reservoir rock, oil quality, and formation water. One fundamental feature for considering petroleum recovery methods is the wettability of the rock reservoir. Also, this feature impacts the displacement of fluids in the rock reservior. In the case of the limestone, which normally features oil wettability, enhanced recovery methods are responsible for altering surface wettability. In this study, the effect of concentration of a cationic surfactant in the oil recovery from limestone is shown. In these tests, finite-bath technique was used to investigate adsorption by varying the amount of adsorbent and contact time. By carrying out contact angle assays, the wettability of the limestone was assessed. In addition, the oil recovery was effected by spontaneous imbibition. In this study, the limestone samples with solutions of CTAB in the concentrations of 0.8596 g/L and 1.2280 g/L, using a 2% KCl solution are treated. The results showed enhanced adsorption of CTAB at the CMC. The nature of this phenomenon did not induce changes in the wettability of the rock, which was confirmed by the contact angle measurements. In the spontaneous imbibition, more oil could be recovered when using a CTAB below the CMC, possibly due to less intense adsorption by the limestone.https://jpst.ripi.ir/article_889_f5062a31f0f6636aa150f5b93e97f058.pdfimbibitionsurfactantoil recoveryadsorptionlimestone
spellingShingle Vanessa Santanna
Tereza Castro Dantas
Allan Neves
Juliana Lima
Camila Nóbrega Pessoa
Recovery of Oil in Limestone with Cationic Surfactant: Investigation of the Adsorption, Wettability, and Spontaneous Imbibition
Journal of Petroleum Science and Technology
imbibition
surfactant
oil recovery
adsorption
limestone
title Recovery of Oil in Limestone with Cationic Surfactant: Investigation of the Adsorption, Wettability, and Spontaneous Imbibition
title_full Recovery of Oil in Limestone with Cationic Surfactant: Investigation of the Adsorption, Wettability, and Spontaneous Imbibition
title_fullStr Recovery of Oil in Limestone with Cationic Surfactant: Investigation of the Adsorption, Wettability, and Spontaneous Imbibition
title_full_unstemmed Recovery of Oil in Limestone with Cationic Surfactant: Investigation of the Adsorption, Wettability, and Spontaneous Imbibition
title_short Recovery of Oil in Limestone with Cationic Surfactant: Investigation of the Adsorption, Wettability, and Spontaneous Imbibition
title_sort recovery of oil in limestone with cationic surfactant investigation of the adsorption wettability and spontaneous imbibition
topic imbibition
surfactant
oil recovery
adsorption
limestone
url https://jpst.ripi.ir/article_889_f5062a31f0f6636aa150f5b93e97f058.pdf
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