Redetermination of μ-oxido-bis[bis(N,N-diethylhydroxylaminato)oxidovanadium(V)]
In comparison with the previous determination [Saussine, Mimoun, Mitschler & Fisher (1980). Nouv. J. Chim. 4, 235–237] of the title compound, [V2(C4H10NO)4O3], the current study reports an improved precision of the derived geometric parameters, along with the deposition of...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811020551 |
| _version_ | 1818974012621979648 |
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| author | Heng-Qiang Zhang Zhong-Min Jin Xin Fan Qi-Ying Zhang |
| author_facet | Heng-Qiang Zhang Zhong-Min Jin Xin Fan Qi-Ying Zhang |
| author_sort | Heng-Qiang Zhang |
| collection | DOAJ |
| description | In comparison with the previous determination [Saussine, Mimoun, Mitschler & Fisher (1980). Nouv. J. Chim. 4, 235–237] of the title compound, [V2(C4H10NO)4O3], the current study reports an improved precision of the derived geometric parameters, along with the deposition of all coordinates and displacement parameters. The two VV atoms are each surrounded by two deprotonated N,O-bidentate diethylhydroxylaminate groups, and a terminal and a bridging oxide ligand, in a distorted octahedral coordination geometry. The crystal packing is accomplished by van der Waals interactions. |
| first_indexed | 2024-12-20T15:33:18Z |
| format | Article |
| id | doaj.art-7f717838ea60430394fed1ebd0adb450 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T15:33:18Z |
| publishDate | 2011-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-7f717838ea60430394fed1ebd0adb4502022-12-21T19:35:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m860m86110.1107/S1600536811020551Redetermination of μ-oxido-bis[bis(N,N-diethylhydroxylaminato)oxidovanadium(V)]Heng-Qiang ZhangZhong-Min JinXin FanQi-Ying ZhangIn comparison with the previous determination [Saussine, Mimoun, Mitschler & Fisher (1980). Nouv. J. Chim. 4, 235–237] of the title compound, [V2(C4H10NO)4O3], the current study reports an improved precision of the derived geometric parameters, along with the deposition of all coordinates and displacement parameters. The two VV atoms are each surrounded by two deprotonated N,O-bidentate diethylhydroxylaminate groups, and a terminal and a bridging oxide ligand, in a distorted octahedral coordination geometry. The crystal packing is accomplished by van der Waals interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536811020551 |
| spellingShingle | Heng-Qiang Zhang Zhong-Min Jin Xin Fan Qi-Ying Zhang Redetermination of μ-oxido-bis[bis(N,N-diethylhydroxylaminato)oxidovanadium(V)] Acta Crystallographica Section E |
| title | Redetermination of μ-oxido-bis[bis(N,N-diethylhydroxylaminato)oxidovanadium(V)] |
| title_full | Redetermination of μ-oxido-bis[bis(N,N-diethylhydroxylaminato)oxidovanadium(V)] |
| title_fullStr | Redetermination of μ-oxido-bis[bis(N,N-diethylhydroxylaminato)oxidovanadium(V)] |
| title_full_unstemmed | Redetermination of μ-oxido-bis[bis(N,N-diethylhydroxylaminato)oxidovanadium(V)] |
| title_short | Redetermination of μ-oxido-bis[bis(N,N-diethylhydroxylaminato)oxidovanadium(V)] |
| title_sort | redetermination of amp 956 oxido bis bis n n diethylhydroxylaminato oxidovanadium v |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811020551 |
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