Experimental study on coupled caloric effect driven by dual fields in metamagnetic Heusler alloy Ni50Mn35In15

The multicaloric and coupled caloric effect of metamagnetic shape memory alloy Ni50Mn35In15 driven by hydrostatic pressure and magnetic field has been systematically investigated. The existence of pressure significantly changes the relationship between the magnetic volume coupling coefficient and te...

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Main Authors: Fei-Xiang Liang, Jia-Zheng Hao, Fei-Ran Shen, Hou-Bo Zhou, Jing Wang, Feng-Xia Hu, Jun He, Ji-Rong Sun, Bao-Gen Shen
Format: Article
Language:English
Published: AIP Publishing LLC 2019-05-01
Series:APL Materials
Online Access:http://dx.doi.org/10.1063/1.5090599
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author Fei-Xiang Liang
Jia-Zheng Hao
Fei-Ran Shen
Hou-Bo Zhou
Jing Wang
Feng-Xia Hu
Jun He
Ji-Rong Sun
Bao-Gen Shen
author_facet Fei-Xiang Liang
Jia-Zheng Hao
Fei-Ran Shen
Hou-Bo Zhou
Jing Wang
Feng-Xia Hu
Jun He
Ji-Rong Sun
Bao-Gen Shen
author_sort Fei-Xiang Liang
collection DOAJ
description The multicaloric and coupled caloric effect of metamagnetic shape memory alloy Ni50Mn35In15 driven by hydrostatic pressure and magnetic field has been systematically investigated. The existence of pressure significantly changes the relationship between the magnetic volume coupling coefficient and temperature. Thermodynamic analysis indicates that the magnetocaloric effect at a certain pressure is equivalent to the magnetocaloric effect at ambient pressure adjusted by the coupled caloric effect (ΔScp). This theoretical result is verified by magnetic measurements under various pressures for the Ni50Mn35In15 with the inverse magnetocaloric effect. When a pressure of 0.995 GPa is applied, the peak value of entropy change can be as high as |ΔS| ∼ 25.7 J kg−1 K−1 upon a magnetic field change of 5–0 T, which increases by 8% compared to that of ambient pressure though the magnetization change (ΔM) across martensitic transition reduces 20% owing to the shift of the transition to higher temperature by 30 K. Detailed analysis indicates that the coupled caloric effect involving the strengthened magnetostructural coupling under pressure is responsible for the enhanced entropy change. The quantitative analysis of cross coupling term driven by dual fields reveals the essence of regulated magnetocaloric effect by pressure, which will be helpful for designing new materials based on the magnetostructural coupling strength.
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spelling doaj.art-7f737ea3a16c4152854428e827d87eda2022-12-22T00:13:49ZengAIP Publishing LLCAPL Materials2166-532X2019-05-0175051102051102-810.1063/1.5090599002905APMExperimental study on coupled caloric effect driven by dual fields in metamagnetic Heusler alloy Ni50Mn35In15Fei-Xiang Liang0Jia-Zheng Hao1Fei-Ran Shen2Hou-Bo Zhou3Jing Wang4Feng-Xia Hu5Jun He6Ji-Rong Sun7Bao-Gen Shen8Beijing National Laboratory for Condensed Matter Physics and State Key Laboratory of Magnetism, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, People’s Republic of ChinaBeijing National Laboratory for Condensed Matter Physics and State Key Laboratory of Magnetism, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, People’s Republic of ChinaBeijing National Laboratory for Condensed Matter Physics and State Key Laboratory of Magnetism, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, People’s Republic of ChinaBeijing National Laboratory for Condensed Matter Physics and State Key Laboratory of Magnetism, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, People’s Republic of ChinaBeijing National Laboratory for Condensed Matter Physics and State Key Laboratory of Magnetism, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, People’s Republic of ChinaBeijing National Laboratory for Condensed Matter Physics and State Key Laboratory of Magnetism, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, People’s Republic of ChinaDivision of Functional Material Research, Central Iron and Steel Research Institute, Beijing 100081, People’s Republic of ChinaBeijing National Laboratory for Condensed Matter Physics and State Key Laboratory of Magnetism, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, People’s Republic of ChinaBeijing National Laboratory for Condensed Matter Physics and State Key Laboratory of Magnetism, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, People’s Republic of ChinaThe multicaloric and coupled caloric effect of metamagnetic shape memory alloy Ni50Mn35In15 driven by hydrostatic pressure and magnetic field has been systematically investigated. The existence of pressure significantly changes the relationship between the magnetic volume coupling coefficient and temperature. Thermodynamic analysis indicates that the magnetocaloric effect at a certain pressure is equivalent to the magnetocaloric effect at ambient pressure adjusted by the coupled caloric effect (ΔScp). This theoretical result is verified by magnetic measurements under various pressures for the Ni50Mn35In15 with the inverse magnetocaloric effect. When a pressure of 0.995 GPa is applied, the peak value of entropy change can be as high as |ΔS| ∼ 25.7 J kg−1 K−1 upon a magnetic field change of 5–0 T, which increases by 8% compared to that of ambient pressure though the magnetization change (ΔM) across martensitic transition reduces 20% owing to the shift of the transition to higher temperature by 30 K. Detailed analysis indicates that the coupled caloric effect involving the strengthened magnetostructural coupling under pressure is responsible for the enhanced entropy change. The quantitative analysis of cross coupling term driven by dual fields reveals the essence of regulated magnetocaloric effect by pressure, which will be helpful for designing new materials based on the magnetostructural coupling strength.http://dx.doi.org/10.1063/1.5090599
spellingShingle Fei-Xiang Liang
Jia-Zheng Hao
Fei-Ran Shen
Hou-Bo Zhou
Jing Wang
Feng-Xia Hu
Jun He
Ji-Rong Sun
Bao-Gen Shen
Experimental study on coupled caloric effect driven by dual fields in metamagnetic Heusler alloy Ni50Mn35In15
APL Materials
title Experimental study on coupled caloric effect driven by dual fields in metamagnetic Heusler alloy Ni50Mn35In15
title_full Experimental study on coupled caloric effect driven by dual fields in metamagnetic Heusler alloy Ni50Mn35In15
title_fullStr Experimental study on coupled caloric effect driven by dual fields in metamagnetic Heusler alloy Ni50Mn35In15
title_full_unstemmed Experimental study on coupled caloric effect driven by dual fields in metamagnetic Heusler alloy Ni50Mn35In15
title_short Experimental study on coupled caloric effect driven by dual fields in metamagnetic Heusler alloy Ni50Mn35In15
title_sort experimental study on coupled caloric effect driven by dual fields in metamagnetic heusler alloy ni50mn35in15
url http://dx.doi.org/10.1063/1.5090599
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