Multipolar and bulk modes: fundamentals of single-particle plasmonics through the advances in electron and photon techniques
Recent developments in the application of plasmonic nanoparticles have showcased the importance of understanding in detail their plasmonic resonances at the single-particle level. These resonances can be excited and probed through various methods, which can be grouped in four categories, depending o...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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De Gruyter
2020-09-01
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| Series: | Nanophotonics |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/nanoph-2020-0326 |
| _version_ | 1830177204486537216 |
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| author | Tsoulos Ted V. Batson Philip E. Fabris Laura |
| author_facet | Tsoulos Ted V. Batson Philip E. Fabris Laura |
| author_sort | Tsoulos Ted V. |
| collection | DOAJ |
| description | Recent developments in the application of plasmonic nanoparticles have showcased the importance of understanding in detail their plasmonic resonances at the single-particle level. These resonances can be excited and probed through various methods, which can be grouped in four categories, depending on whether excitation and detection involve electrons (electron energy loss spectroscopy), photons (e.g., dark-field microscopy), or both (cathodoluminescence and photon-induced near-field electron microscopy). While both photon-based and electron-based methods have made great strides toward deepening our understanding of known plasmonic properties and discovering new ones, they have in general progressed in parallel, without much cross-pollination. This evolution can be primarily attributed to the different theoretical approaches driving these techniques, mainly dictated by the inherent different nature of electrons and photons. The discrepancies that still exist among them have hampered the development of a holistic approach to the characterization of plasmonic materials. In this review therefore, we aim to briefly present those electron-based and photon-based methods fundamental to the study of plasmonic properties at the single-particle level, with an eye to new behaviors involving multipolar, propagating, and bulk modes coexisting in colloidal nanostructures. By exploring the key fundamental discoveries in nanoparticle plasmonics achieved with these techniques, herein we assess how integrating this information could encourage the creation of a unified understanding of the various phenomena occurring in individual nanoparticles, which would benefit the plasmonics and electron microscopy communities alike. |
| first_indexed | 2024-12-17T19:20:11Z |
| format | Article |
| id | doaj.art-7f7d4ef85b2f4e8c9f43783a49eb65b3 |
| institution | Directory Open Access Journal |
| issn | 2192-8606 2192-8614 |
| language | English |
| last_indexed | 2024-12-17T19:20:11Z |
| publishDate | 2020-09-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Nanophotonics |
| spelling | doaj.art-7f7d4ef85b2f4e8c9f43783a49eb65b32022-12-21T21:35:34ZengDe GruyterNanophotonics2192-86062192-86142020-09-019154433444610.1515/nanoph-2020-0326Multipolar and bulk modes: fundamentals of single-particle plasmonics through the advances in electron and photon techniquesTsoulos Ted V.0Batson Philip E.1Fabris Laura2Ecole Polytechnique Federale de Lausanne, Lausanne, VD, SwitzerlandRutgers University, Piscataway, New Jersey, USAMaterials Science and Engineering, Rutgers University, 607 Taylor Rd, Piscataway, New Jersey 08854, USARecent developments in the application of plasmonic nanoparticles have showcased the importance of understanding in detail their plasmonic resonances at the single-particle level. These resonances can be excited and probed through various methods, which can be grouped in four categories, depending on whether excitation and detection involve electrons (electron energy loss spectroscopy), photons (e.g., dark-field microscopy), or both (cathodoluminescence and photon-induced near-field electron microscopy). While both photon-based and electron-based methods have made great strides toward deepening our understanding of known plasmonic properties and discovering new ones, they have in general progressed in parallel, without much cross-pollination. This evolution can be primarily attributed to the different theoretical approaches driving these techniques, mainly dictated by the inherent different nature of electrons and photons. The discrepancies that still exist among them have hampered the development of a holistic approach to the characterization of plasmonic materials. In this review therefore, we aim to briefly present those electron-based and photon-based methods fundamental to the study of plasmonic properties at the single-particle level, with an eye to new behaviors involving multipolar, propagating, and bulk modes coexisting in colloidal nanostructures. By exploring the key fundamental discoveries in nanoparticle plasmonics achieved with these techniques, herein we assess how integrating this information could encourage the creation of a unified understanding of the various phenomena occurring in individual nanoparticles, which would benefit the plasmonics and electron microscopy communities alike.https://doi.org/10.1515/nanoph-2020-0326bulk plasmonscathodoluminescenceeelslocalized plasmon resonancesmultipolar plasmon modesnanoparticle plasmonicspinem |
| spellingShingle | Tsoulos Ted V. Batson Philip E. Fabris Laura Multipolar and bulk modes: fundamentals of single-particle plasmonics through the advances in electron and photon techniques Nanophotonics bulk plasmons cathodoluminescence eels localized plasmon resonances multipolar plasmon modes nanoparticle plasmonics pinem |
| title | Multipolar and bulk modes: fundamentals of single-particle plasmonics through the advances in electron and photon techniques |
| title_full | Multipolar and bulk modes: fundamentals of single-particle plasmonics through the advances in electron and photon techniques |
| title_fullStr | Multipolar and bulk modes: fundamentals of single-particle plasmonics through the advances in electron and photon techniques |
| title_full_unstemmed | Multipolar and bulk modes: fundamentals of single-particle plasmonics through the advances in electron and photon techniques |
| title_short | Multipolar and bulk modes: fundamentals of single-particle plasmonics through the advances in electron and photon techniques |
| title_sort | multipolar and bulk modes fundamentals of single particle plasmonics through the advances in electron and photon techniques |
| topic | bulk plasmons cathodoluminescence eels localized plasmon resonances multipolar plasmon modes nanoparticle plasmonics pinem |
| url | https://doi.org/10.1515/nanoph-2020-0326 |
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