Self‐Supporting 3D Lithiophilic and Flexible Carbon Nanofiber Film as a High‐Loading Li Host
Herein, a Zn and N co‐doped carbon nanofiber film (Zn–N–CNF) is successfully fabricated via a convenient electrospinning technique, which can be used as hybrid lithiophilic current collector to accommodate high‐loading lithium. Contributing to the lithiophilic active sites and 3D network structure o...
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| Format: | Article |
| Language: | English |
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Wiley-VCH
2022-06-01
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| Series: | Advanced Energy & Sustainability Research |
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| Online Access: | https://doi.org/10.1002/aesr.202100186 |
| _version_ | 1811248385560150016 |
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| author | Ting Liu Ye-Qiang Zhang Ying Huang Run-Tong Wang Sheng-Qi Zhou Peng-Fei Sun Jia-Jia Chen |
| author_facet | Ting Liu Ye-Qiang Zhang Ying Huang Run-Tong Wang Sheng-Qi Zhou Peng-Fei Sun Jia-Jia Chen |
| author_sort | Ting Liu |
| collection | DOAJ |
| description | Herein, a Zn and N co‐doped carbon nanofiber film (Zn–N–CNF) is successfully fabricated via a convenient electrospinning technique, which can be used as hybrid lithiophilic current collector to accommodate high‐loading lithium. Contributing to the lithiophilic active sites and 3D network structure of Zn–N–CNF, metallic Li can be reversibly electrochemical plated and stripped. Consequently, the Zn–N–CNF@Li electrode exhibits a high exchange current density of 4.731 mA cm−2, providing fast charge‐transfer kinetics for Li plating and stripping. Then, an average Coulombic efficiency of 97.3 % can be achieved at 1.0 mA cm−2 with 1.0 mAh cm−2 in 150 cycles. The corresponding symmetrical battery can stably cycle for nearly 800 h with a voltage hysteresis less than 20 mV at 0.5 mA cm−2 and 0.5 mAh cm−2. In addition, this flexible skeleton of 3D Zn–N–CNF can accommodate a high Li deposition capacity of 10 mAh cm−2 with a reversible electrochemical plating and stripping. Moreover, full cells based on the developed anode and a LiFePO4 cathode also demonstrate superior rate capability and stable cycle life. Herein, a promising strategy to construct dendrite‐free lithium metal anodes toward high‐performance lithium metal batteries is provided. |
| first_indexed | 2024-04-12T15:27:08Z |
| format | Article |
| id | doaj.art-7fd1019ea1494f78b35268567319b991 |
| institution | Directory Open Access Journal |
| issn | 2699-9412 |
| language | English |
| last_indexed | 2024-04-12T15:27:08Z |
| publishDate | 2022-06-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | Advanced Energy & Sustainability Research |
| spelling | doaj.art-7fd1019ea1494f78b35268567319b9912022-12-22T03:27:13ZengWiley-VCHAdvanced Energy & Sustainability Research2699-94122022-06-0136n/an/a10.1002/aesr.202100186Self‐Supporting 3D Lithiophilic and Flexible Carbon Nanofiber Film as a High‐Loading Li HostTing Liu0Ye-Qiang Zhang1Ying Huang2Run-Tong Wang3Sheng-Qi Zhou4Peng-Fei Sun5Jia-Jia Chen6State Key Laboratory of Physical Chemistry of Solid Surfaces Department of Chemistry College of Chemistry and Chemical Engineering Collaborative Innovation Center of Chemistry for Energy Materials (iChem) Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Engineering Research Center of Electrochemical Technologies of Ministry of Education Xiamen University Xiamen Fujian 361005 ChinaState Key Laboratory of Physical Chemistry of Solid Surfaces Department of Chemistry College of Chemistry and Chemical Engineering Collaborative Innovation Center of Chemistry for Energy Materials (iChem) Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Engineering Research Center of Electrochemical Technologies of Ministry of Education Xiamen University Xiamen Fujian 361005 ChinaState Key Laboratory of Physical Chemistry of Solid Surfaces Department of Chemistry College of Chemistry and Chemical Engineering Collaborative Innovation Center of Chemistry for Energy Materials (iChem) Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Engineering Research Center of Electrochemical Technologies of Ministry of Education Xiamen University Xiamen Fujian 361005 ChinaState Key Laboratory of Physical Chemistry of Solid Surfaces Department of Chemistry College of Chemistry and Chemical Engineering Collaborative Innovation Center of Chemistry for Energy Materials (iChem) Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Engineering Research Center of Electrochemical Technologies of Ministry of Education Xiamen University Xiamen Fujian 361005 ChinaState Key Laboratory of Physical Chemistry of Solid Surfaces Department of Chemistry College of Chemistry and Chemical Engineering Collaborative Innovation Center of Chemistry for Energy Materials (iChem) Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Engineering Research Center of Electrochemical Technologies of Ministry of Education Xiamen University Xiamen Fujian 361005 ChinaState Key Laboratory of Physical Chemistry of Solid Surfaces Department of Chemistry College of Chemistry and Chemical Engineering Collaborative Innovation Center of Chemistry for Energy Materials (iChem) Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Engineering Research Center of Electrochemical Technologies of Ministry of Education Xiamen University Xiamen Fujian 361005 ChinaState Key Laboratory of Physical Chemistry of Solid Surfaces Department of Chemistry College of Chemistry and Chemical Engineering Collaborative Innovation Center of Chemistry for Energy Materials (iChem) Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Engineering Research Center of Electrochemical Technologies of Ministry of Education Xiamen University Xiamen Fujian 361005 ChinaHerein, a Zn and N co‐doped carbon nanofiber film (Zn–N–CNF) is successfully fabricated via a convenient electrospinning technique, which can be used as hybrid lithiophilic current collector to accommodate high‐loading lithium. Contributing to the lithiophilic active sites and 3D network structure of Zn–N–CNF, metallic Li can be reversibly electrochemical plated and stripped. Consequently, the Zn–N–CNF@Li electrode exhibits a high exchange current density of 4.731 mA cm−2, providing fast charge‐transfer kinetics for Li plating and stripping. Then, an average Coulombic efficiency of 97.3 % can be achieved at 1.0 mA cm−2 with 1.0 mAh cm−2 in 150 cycles. The corresponding symmetrical battery can stably cycle for nearly 800 h with a voltage hysteresis less than 20 mV at 0.5 mA cm−2 and 0.5 mAh cm−2. In addition, this flexible skeleton of 3D Zn–N–CNF can accommodate a high Li deposition capacity of 10 mAh cm−2 with a reversible electrochemical plating and stripping. Moreover, full cells based on the developed anode and a LiFePO4 cathode also demonstrate superior rate capability and stable cycle life. Herein, a promising strategy to construct dendrite‐free lithium metal anodes toward high‐performance lithium metal batteries is provided.https://doi.org/10.1002/aesr.2021001863D carbon-based current collectorselectrospinning techniqueslithiophilic hostsmetallic lithium anodes |
| spellingShingle | Ting Liu Ye-Qiang Zhang Ying Huang Run-Tong Wang Sheng-Qi Zhou Peng-Fei Sun Jia-Jia Chen Self‐Supporting 3D Lithiophilic and Flexible Carbon Nanofiber Film as a High‐Loading Li Host Advanced Energy & Sustainability Research 3D carbon-based current collectors electrospinning techniques lithiophilic hosts metallic lithium anodes |
| title | Self‐Supporting 3D Lithiophilic and Flexible Carbon Nanofiber Film as a High‐Loading Li Host |
| title_full | Self‐Supporting 3D Lithiophilic and Flexible Carbon Nanofiber Film as a High‐Loading Li Host |
| title_fullStr | Self‐Supporting 3D Lithiophilic and Flexible Carbon Nanofiber Film as a High‐Loading Li Host |
| title_full_unstemmed | Self‐Supporting 3D Lithiophilic and Flexible Carbon Nanofiber Film as a High‐Loading Li Host |
| title_short | Self‐Supporting 3D Lithiophilic and Flexible Carbon Nanofiber Film as a High‐Loading Li Host |
| title_sort | self supporting 3d lithiophilic and flexible carbon nanofiber film as a high loading li host |
| topic | 3D carbon-based current collectors electrospinning techniques lithiophilic hosts metallic lithium anodes |
| url | https://doi.org/10.1002/aesr.202100186 |
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