2-N-Benzyl-2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-d-allononitrile
X-ray crystallography firmly established the relative stereochemistry of the title compound, C16H20N2O3. The acetonide ring adopts an envelope conformation with one of the O atoms as the flap and the piperidine ring adopts a slightly twisted boat conformation. The absolute configuration was determin...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-12-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813030584 |
| _version_ | 1819121827352412160 |
|---|---|
| author | Amber L. Thompson George W. J. Fleet Sarah F. Jenkinson Benjamin J. Ayers |
| author_facet | Amber L. Thompson George W. J. Fleet Sarah F. Jenkinson Benjamin J. Ayers |
| author_sort | Amber L. Thompson |
| collection | DOAJ |
| description | X-ray crystallography firmly established the relative stereochemistry of the title compound, C16H20N2O3. The acetonide ring adopts an envelope conformation with one of the O atoms as the flap and the piperidine ring adopts a slightly twisted boat conformation. The absolute configuration was determined by use of d-ribose as the starting material. The compound exists as O—H...O hydrogen-bonded chains of molecules running parallel to the b axis. |
| first_indexed | 2024-12-22T06:42:45Z |
| format | Article |
| id | doaj.art-7fe4f36ed0364e739fc92a76efa25528 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T06:42:45Z |
| publishDate | 2013-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-7fe4f36ed0364e739fc92a76efa255282022-12-21T18:35:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-12-016912o1772o177210.1107/S16005368130305842-N-Benzyl-2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-d-allononitrileAmber L. ThompsonGeorge W. J. FleetSarah F. JenkinsonBenjamin J. AyersX-ray crystallography firmly established the relative stereochemistry of the title compound, C16H20N2O3. The acetonide ring adopts an envelope conformation with one of the O atoms as the flap and the piperidine ring adopts a slightly twisted boat conformation. The absolute configuration was determined by use of d-ribose as the starting material. The compound exists as O—H...O hydrogen-bonded chains of molecules running parallel to the b axis.http://scripts.iucr.org/cgi-bin/paper?S1600536813030584 |
| spellingShingle | Amber L. Thompson George W. J. Fleet Sarah F. Jenkinson Benjamin J. Ayers 2-N-Benzyl-2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-d-allononitrile Acta Crystallographica Section E |
| title | 2-N-Benzyl-2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-d-allononitrile |
| title_full | 2-N-Benzyl-2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-d-allononitrile |
| title_fullStr | 2-N-Benzyl-2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-d-allononitrile |
| title_full_unstemmed | 2-N-Benzyl-2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-d-allononitrile |
| title_short | 2-N-Benzyl-2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-d-allononitrile |
| title_sort | 2 n benzyl 2 6 dideoxy 2 6 imino 3 4 o isopropylidene d allononitrile |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813030584 |
| work_keys_str_mv | AT amberlthompson 2nbenzyl26dideoxy26imino34oisopropylidenedallononitrile AT georgewjfleet 2nbenzyl26dideoxy26imino34oisopropylidenedallononitrile AT sarahfjenkinson 2nbenzyl26dideoxy26imino34oisopropylidenedallononitrile AT benjaminjayers 2nbenzyl26dideoxy26imino34oisopropylidenedallononitrile |