Carbon dioxide fixation into cyclic carbonates at room temperature catalyzed by heteroscorpionate aluminum complexes
Novel mono- and bimetallic scorpionate aluminum compounds have been designed and characterized by spectroscopic methods. These organometallics complexes, in combination with tetrabutylammonium bromide as cocatalyst, displayed good catalytic activity for the cycloaddition of styrene oxide and CO2 und...
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| Format: | Article |
| Language: | English |
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KeAi Communications Co. Ltd.
2022-09-01
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| Series: | Green Chemical Engineering |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666952822000188 |
| _version_ | 1797976382902370304 |
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| author | Felipe de la Cruz-Martínez José A. Castro-Osma Agustín Lara-Sánchez |
| author_facet | Felipe de la Cruz-Martínez José A. Castro-Osma Agustín Lara-Sánchez |
| author_sort | Felipe de la Cruz-Martínez |
| collection | DOAJ |
| description | Novel mono- and bimetallic scorpionate aluminum compounds have been designed and characterized by spectroscopic methods. These organometallics complexes, in combination with tetrabutylammonium bromide as cocatalyst, displayed good catalytic activity for the cycloaddition of styrene oxide and CO2 under ambient conditions. Among the compounds tested, monometallic complex 3 featuring diethylamino groups showed the highest catalytic activity. This catalytic system catalyzed the formation of cyclic carbonate products from their corresponding epoxides at room temperature and 1 bar of CO2 pressure in the absence of a solvent in good yields and excellent selectivities. |
| first_indexed | 2024-04-11T04:50:03Z |
| format | Article |
| id | doaj.art-7fefaebfae4c4be2a06b6dc8c9292fa6 |
| institution | Directory Open Access Journal |
| issn | 2666-9528 |
| language | English |
| last_indexed | 2024-04-11T04:50:03Z |
| publishDate | 2022-09-01 |
| publisher | KeAi Communications Co. Ltd. |
| record_format | Article |
| series | Green Chemical Engineering |
| spelling | doaj.art-7fefaebfae4c4be2a06b6dc8c9292fa62022-12-27T04:40:22ZengKeAi Communications Co. Ltd.Green Chemical Engineering2666-95282022-09-0133280287Carbon dioxide fixation into cyclic carbonates at room temperature catalyzed by heteroscorpionate aluminum complexesFelipe de la Cruz-Martínez0José A. Castro-Osma1Agustín Lara-Sánchez2Universidad de Castilla-La Mancha, Departamento de Química Inorgánica, Orgánica y Bioquímica-Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Ciencias y Tecnologías Químicas, Ciudad Real, 13071, Spain; Instituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Consejo Superior de Investigaciones Científicas (CSIC) and University of Sevilla, Sevilla, 41092, SpainUniversidad de Castilla-La Mancha, Departamento de Química Inorgánica, Orgánica y Bioquímica-Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Farmacia, Albacete, 02071, Spain; Corresponding author.Universidad de Castilla-La Mancha, Departamento de Química Inorgánica, Orgánica y Bioquímica-Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Ciencias y Tecnologías Químicas, Ciudad Real, 13071, Spain; Corresponding author.Novel mono- and bimetallic scorpionate aluminum compounds have been designed and characterized by spectroscopic methods. These organometallics complexes, in combination with tetrabutylammonium bromide as cocatalyst, displayed good catalytic activity for the cycloaddition of styrene oxide and CO2 under ambient conditions. Among the compounds tested, monometallic complex 3 featuring diethylamino groups showed the highest catalytic activity. This catalytic system catalyzed the formation of cyclic carbonate products from their corresponding epoxides at room temperature and 1 bar of CO2 pressure in the absence of a solvent in good yields and excellent selectivities.http://www.sciencedirect.com/science/article/pii/S2666952822000188CO2EpoxidesCyclic carbonatesAluminum complexes |
| spellingShingle | Felipe de la Cruz-Martínez José A. Castro-Osma Agustín Lara-Sánchez Carbon dioxide fixation into cyclic carbonates at room temperature catalyzed by heteroscorpionate aluminum complexes Green Chemical Engineering CO2 Epoxides Cyclic carbonates Aluminum complexes |
| title | Carbon dioxide fixation into cyclic carbonates at room temperature catalyzed by heteroscorpionate aluminum complexes |
| title_full | Carbon dioxide fixation into cyclic carbonates at room temperature catalyzed by heteroscorpionate aluminum complexes |
| title_fullStr | Carbon dioxide fixation into cyclic carbonates at room temperature catalyzed by heteroscorpionate aluminum complexes |
| title_full_unstemmed | Carbon dioxide fixation into cyclic carbonates at room temperature catalyzed by heteroscorpionate aluminum complexes |
| title_short | Carbon dioxide fixation into cyclic carbonates at room temperature catalyzed by heteroscorpionate aluminum complexes |
| title_sort | carbon dioxide fixation into cyclic carbonates at room temperature catalyzed by heteroscorpionate aluminum complexes |
| topic | CO2 Epoxides Cyclic carbonates Aluminum complexes |
| url | http://www.sciencedirect.com/science/article/pii/S2666952822000188 |
| work_keys_str_mv | AT felipedelacruzmartinez carbondioxidefixationintocycliccarbonatesatroomtemperaturecatalyzedbyheteroscorpionatealuminumcomplexes AT joseacastroosma carbondioxidefixationintocycliccarbonatesatroomtemperaturecatalyzedbyheteroscorpionatealuminumcomplexes AT agustinlarasanchez carbondioxidefixationintocycliccarbonatesatroomtemperaturecatalyzedbyheteroscorpionatealuminumcomplexes |