Recent Updates on Electrogenerated Hypervalent Iodine Derivatives and Their Applications as Mediators in Organic Electrosynthesis
With the renaissance of chemical electrosynthesis in the last decade, the electrochemistry of hypervalent iodine compounds has picked up the pace and achieved significant improvements. By employing traceless electrons instead of stoichiometric oxidants as the alternative clean “reagents”, many hyper...
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| Format: | Article |
| Language: | English |
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Frontiers Media S.A.
2022-04-01
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| Series: | Frontiers in Chemistry |
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| Online Access: | https://www.frontiersin.org/articles/10.3389/fchem.2022.883474/full |
| _version_ | 1828846168384208896 |
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| author | Chaoyue Chen Xin Wang Tinghai Yang Tinghai Yang |
| author_facet | Chaoyue Chen Xin Wang Tinghai Yang Tinghai Yang |
| author_sort | Chaoyue Chen |
| collection | DOAJ |
| description | With the renaissance of chemical electrosynthesis in the last decade, the electrochemistry of hypervalent iodine compounds has picked up the pace and achieved significant improvements. By employing traceless electrons instead of stoichiometric oxidants as the alternative clean “reagents”, many hypervalent iodine compounds were efficiently electro-synthesized via anodic oxidation methods and utilized as powerful redox mediators triggering valuable oxidative coupling reactions in a more sustainable way. This minireview gives an up-to-date overview of the recent advances during the past 3 years, encompassing enhanced electrosynthesis technologies, novel synthetic applications, and ideas for improving reaction sustainability. |
| first_indexed | 2024-12-12T21:42:21Z |
| format | Article |
| id | doaj.art-8002fc0e13344fdf947f1d91318acafa |
| institution | Directory Open Access Journal |
| issn | 2296-2646 |
| language | English |
| last_indexed | 2024-12-12T21:42:21Z |
| publishDate | 2022-04-01 |
| publisher | Frontiers Media S.A. |
| record_format | Article |
| series | Frontiers in Chemistry |
| spelling | doaj.art-8002fc0e13344fdf947f1d91318acafa2022-12-22T00:11:00ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462022-04-011010.3389/fchem.2022.883474883474Recent Updates on Electrogenerated Hypervalent Iodine Derivatives and Their Applications as Mediators in Organic ElectrosynthesisChaoyue Chen0Xin Wang1Tinghai Yang2Tinghai Yang3School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou, ChinaSchool of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou, ChinaSchool of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou, ChinaState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, ChinaWith the renaissance of chemical electrosynthesis in the last decade, the electrochemistry of hypervalent iodine compounds has picked up the pace and achieved significant improvements. By employing traceless electrons instead of stoichiometric oxidants as the alternative clean “reagents”, many hypervalent iodine compounds were efficiently electro-synthesized via anodic oxidation methods and utilized as powerful redox mediators triggering valuable oxidative coupling reactions in a more sustainable way. This minireview gives an up-to-date overview of the recent advances during the past 3 years, encompassing enhanced electrosynthesis technologies, novel synthetic applications, and ideas for improving reaction sustainability.https://www.frontiersin.org/articles/10.3389/fchem.2022.883474/fullhypervalent iodine reagentorganic electrosynthesisanodic oxidationredox mediatorsynthetic method |
| spellingShingle | Chaoyue Chen Xin Wang Tinghai Yang Tinghai Yang Recent Updates on Electrogenerated Hypervalent Iodine Derivatives and Their Applications as Mediators in Organic Electrosynthesis Frontiers in Chemistry hypervalent iodine reagent organic electrosynthesis anodic oxidation redox mediator synthetic method |
| title | Recent Updates on Electrogenerated Hypervalent Iodine Derivatives and Their Applications as Mediators in Organic Electrosynthesis |
| title_full | Recent Updates on Electrogenerated Hypervalent Iodine Derivatives and Their Applications as Mediators in Organic Electrosynthesis |
| title_fullStr | Recent Updates on Electrogenerated Hypervalent Iodine Derivatives and Their Applications as Mediators in Organic Electrosynthesis |
| title_full_unstemmed | Recent Updates on Electrogenerated Hypervalent Iodine Derivatives and Their Applications as Mediators in Organic Electrosynthesis |
| title_short | Recent Updates on Electrogenerated Hypervalent Iodine Derivatives and Their Applications as Mediators in Organic Electrosynthesis |
| title_sort | recent updates on electrogenerated hypervalent iodine derivatives and their applications as mediators in organic electrosynthesis |
| topic | hypervalent iodine reagent organic electrosynthesis anodic oxidation redox mediator synthetic method |
| url | https://www.frontiersin.org/articles/10.3389/fchem.2022.883474/full |
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