A collector-generator cell for in-situ detection of electrochemically produced H2
A collector-generator (C-G) cell used for the in-situ detection of H2 generated through electrochemical catalysis was described. The cell was mainly assembled with two fluorine-doped tin oxide (FTO) electrodes deposited with Pt nanoparticles, the magnitude of the current generated by the electrocata...
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Format: | Article |
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Elsevier
2024-03-01
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Series: | Heliyon |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2405844024030408 |
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author | Ling Fei Degao Wang |
author_facet | Ling Fei Degao Wang |
author_sort | Ling Fei |
collection | DOAJ |
description | A collector-generator (C-G) cell used for the in-situ detection of H2 generated through electrochemical catalysis was described. The cell was mainly assembled with two fluorine-doped tin oxide (FTO) electrodes deposited with Pt nanoparticles, the magnitude of the current generated by the electrocatalytic oxidation of H2 at the collector was used for quantitative analysis of H2 generated at the generator. When the generator potential was set at −0.5 ∼ −0.6 V vs. Ag/AgCl and the collector potential at 0.4 ∼ 0.5 V vs. Ag/AgCl, the total Faradaic efficiency of the C-G cell could stabilize about 70%, the detection limit was about 45 μmol/L and the sensitivity was about 1 mA/55 μmol L−1. This dual working electrode technology could provide a convenient and rapid method for H2 determination and evaluate the performance of H2 generation catalysts that assembled on the semiconductor thin-films. |
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id | doaj.art-8024be9a176f4cc0ab4394a4f9ab8d8d |
institution | Directory Open Access Journal |
issn | 2405-8440 |
language | English |
last_indexed | 2024-04-24T23:15:05Z |
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spelling | doaj.art-8024be9a176f4cc0ab4394a4f9ab8d8d2024-03-17T07:57:03ZengElsevierHeliyon2405-84402024-03-01105e27009A collector-generator cell for in-situ detection of electrochemically produced H2Ling Fei0Degao Wang1Engineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang, 315201, PR ChinaEngineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang, 315201, PR China; University of Chinese Academy of Science, Beijing, 100049, PR China; Research Center for Advanced Interdisciplinary Science of Ningbo Material Institute, Ningbo, Zhejiang, 315201, PR China; Corresponding author. Engineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang, 315201, PR China.A collector-generator (C-G) cell used for the in-situ detection of H2 generated through electrochemical catalysis was described. The cell was mainly assembled with two fluorine-doped tin oxide (FTO) electrodes deposited with Pt nanoparticles, the magnitude of the current generated by the electrocatalytic oxidation of H2 at the collector was used for quantitative analysis of H2 generated at the generator. When the generator potential was set at −0.5 ∼ −0.6 V vs. Ag/AgCl and the collector potential at 0.4 ∼ 0.5 V vs. Ag/AgCl, the total Faradaic efficiency of the C-G cell could stabilize about 70%, the detection limit was about 45 μmol/L and the sensitivity was about 1 mA/55 μmol L−1. This dual working electrode technology could provide a convenient and rapid method for H2 determination and evaluate the performance of H2 generation catalysts that assembled on the semiconductor thin-films.http://www.sciencedirect.com/science/article/pii/S2405844024030408ElectrocatalysisCollector-generator cellWater splittingH2 |
spellingShingle | Ling Fei Degao Wang A collector-generator cell for in-situ detection of electrochemically produced H2 Heliyon Electrocatalysis Collector-generator cell Water splitting H2 |
title | A collector-generator cell for in-situ detection of electrochemically produced H2 |
title_full | A collector-generator cell for in-situ detection of electrochemically produced H2 |
title_fullStr | A collector-generator cell for in-situ detection of electrochemically produced H2 |
title_full_unstemmed | A collector-generator cell for in-situ detection of electrochemically produced H2 |
title_short | A collector-generator cell for in-situ detection of electrochemically produced H2 |
title_sort | collector generator cell for in situ detection of electrochemically produced h2 |
topic | Electrocatalysis Collector-generator cell Water splitting H2 |
url | http://www.sciencedirect.com/science/article/pii/S2405844024030408 |
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