Greatly enhanced breakdown strength and energy density in ultraviolet‐irradiated polypropylene

Abstract Polymer dielectrics have drawn great attentions for applications in advanced electronic devices and power grids because of their high breakdown strength, low dielectric loss, and excellent flexibility. However, the low energy density in polymer dielectric capacitors will hinder the continuo...

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Main Authors: Jiayu Chen, Bao‐Wen Li, Yi Sun, Pengxiang Zhang, Zhonghui Shen, Xin Zhang, Ce‐Wen Nan, Shujun Zhang
Format: Article
Language:English
Published: Wiley 2021-12-01
Series:IET Nanodielectrics
Subjects:
Online Access:https://doi.org/10.1049/nde2.12022
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author Jiayu Chen
Bao‐Wen Li
Yi Sun
Pengxiang Zhang
Zhonghui Shen
Xin Zhang
Ce‐Wen Nan
Shujun Zhang
author_facet Jiayu Chen
Bao‐Wen Li
Yi Sun
Pengxiang Zhang
Zhonghui Shen
Xin Zhang
Ce‐Wen Nan
Shujun Zhang
author_sort Jiayu Chen
collection DOAJ
description Abstract Polymer dielectrics have drawn great attentions for applications in advanced electronic devices and power grids because of their high breakdown strength, low dielectric loss, and excellent flexibility. However, the low energy density in polymer dielectric capacitors will hinder the continuous miniaturization of electrical systems. In this work, ultraviolet irradiation is demonstrated to greatly enhance the breakdown strength and energy density of polypropylene. Dramatically improved breakdown strength of 867 MV/m and discharged energy density of 8.0 J/cm3, together with the high energy efficiency of >90%, were simultaneously achieved in polypropylene after ultraviolet irradiation. Our research shows that proper ultraviolet irradiation can effectively improve the energy density of polypropylene without sacrificing its high charge‐discharge efficiency, being potential for applications in power electronics and pulse electric systems.
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spelling doaj.art-8033db0120ba4f11b476e190365b01652022-12-22T00:11:21ZengWileyIET Nanodielectrics2514-32552021-12-014422322810.1049/nde2.12022Greatly enhanced breakdown strength and energy density in ultraviolet‐irradiated polypropyleneJiayu Chen0Bao‐Wen Li1Yi Sun2Pengxiang Zhang3Zhonghui Shen4Xin Zhang5Ce‐Wen Nan6Shujun Zhang7State Key Laboratory of Silicate Materials for Architectures School of Materials Science and Engineering, Wuhan University of Technology Wuhan ChinaState Key Laboratory of Silicate Materials for Architectures School of Materials Science and Engineering, Wuhan University of Technology Wuhan ChinaState Key Laboratory of Silicate Materials for Architectures School of Materials Science and Engineering, Wuhan University of Technology Wuhan ChinaState Key Laboratory of Advanced Technology for Materials Synthesis and Processing Center of Smart Materials and Devices Wuhan University of Technology Wuhan ChinaState Key Laboratory of Advanced Technology for Materials Synthesis and Processing Center of Smart Materials and Devices Wuhan University of Technology Wuhan ChinaState Key Laboratory of Advanced Technology for Materials Synthesis and Processing Center of Smart Materials and Devices Wuhan University of Technology Wuhan ChinaState Key Laboratory of New Ceramics and Fine Processing School of Materials Science and Engineering, Tsinghua University Beijing ChinaInstitute for Superconducting and Electronic Materials Australian Institute of Innovative Materials University of Wollongong North Wollongong New South Wales AustraliaAbstract Polymer dielectrics have drawn great attentions for applications in advanced electronic devices and power grids because of their high breakdown strength, low dielectric loss, and excellent flexibility. However, the low energy density in polymer dielectric capacitors will hinder the continuous miniaturization of electrical systems. In this work, ultraviolet irradiation is demonstrated to greatly enhance the breakdown strength and energy density of polypropylene. Dramatically improved breakdown strength of 867 MV/m and discharged energy density of 8.0 J/cm3, together with the high energy efficiency of >90%, were simultaneously achieved in polypropylene after ultraviolet irradiation. Our research shows that proper ultraviolet irradiation can effectively improve the energy density of polypropylene without sacrificing its high charge‐discharge efficiency, being potential for applications in power electronics and pulse electric systems.https://doi.org/10.1049/nde2.12022electric breakdowncapacitorspolymersdielectric lossespermittivityultraviolet radiation effects
spellingShingle Jiayu Chen
Bao‐Wen Li
Yi Sun
Pengxiang Zhang
Zhonghui Shen
Xin Zhang
Ce‐Wen Nan
Shujun Zhang
Greatly enhanced breakdown strength and energy density in ultraviolet‐irradiated polypropylene
IET Nanodielectrics
electric breakdown
capacitors
polymers
dielectric losses
permittivity
ultraviolet radiation effects
title Greatly enhanced breakdown strength and energy density in ultraviolet‐irradiated polypropylene
title_full Greatly enhanced breakdown strength and energy density in ultraviolet‐irradiated polypropylene
title_fullStr Greatly enhanced breakdown strength and energy density in ultraviolet‐irradiated polypropylene
title_full_unstemmed Greatly enhanced breakdown strength and energy density in ultraviolet‐irradiated polypropylene
title_short Greatly enhanced breakdown strength and energy density in ultraviolet‐irradiated polypropylene
title_sort greatly enhanced breakdown strength and energy density in ultraviolet irradiated polypropylene
topic electric breakdown
capacitors
polymers
dielectric losses
permittivity
ultraviolet radiation effects
url https://doi.org/10.1049/nde2.12022
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AT pengxiangzhang greatlyenhancedbreakdownstrengthandenergydensityinultravioletirradiatedpolypropylene
AT zhonghuishen greatlyenhancedbreakdownstrengthandenergydensityinultravioletirradiatedpolypropylene
AT xinzhang greatlyenhancedbreakdownstrengthandenergydensityinultravioletirradiatedpolypropylene
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