g-C<sub>3</sub>N<sub>4</sub> Based Photocatalyst for the Efficient Photodegradation of Toxic Methyl Orange Dye: Recent Modifications and Future Perspectives

Industrial effluents containing dyes are the dominant pollutants, making the drinking water unfit. Among the dyes, methylene orange (MO) dye is mutagenic, carcinogenic and toxic to aquatic organisms. Therefore, its removal from water bodies through effective and economical approach is gaining increa...

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Main Authors: Abdulelah Aljuaid, Mazen Almehmadi, Ahad Amer Alsaiari, Mamdouh Allahyani, Osama Abdulaziz, Abdulaziz Alsharif, Jawaher Amer Alsaiari, Magdi Saih, Rema Turki Alotaibi, Idrees Khan
Format: Article
Language:English
Published: MDPI AG 2023-04-01
Series:Molecules
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Online Access:https://www.mdpi.com/1420-3049/28/7/3199
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author Abdulelah Aljuaid
Mazen Almehmadi
Ahad Amer Alsaiari
Mamdouh Allahyani
Osama Abdulaziz
Abdulaziz Alsharif
Jawaher Amer Alsaiari
Magdi Saih
Rema Turki Alotaibi
Idrees Khan
author_facet Abdulelah Aljuaid
Mazen Almehmadi
Ahad Amer Alsaiari
Mamdouh Allahyani
Osama Abdulaziz
Abdulaziz Alsharif
Jawaher Amer Alsaiari
Magdi Saih
Rema Turki Alotaibi
Idrees Khan
author_sort Abdulelah Aljuaid
collection DOAJ
description Industrial effluents containing dyes are the dominant pollutants, making the drinking water unfit. Among the dyes, methylene orange (MO) dye is mutagenic, carcinogenic and toxic to aquatic organisms. Therefore, its removal from water bodies through effective and economical approach is gaining increased attention in the last decades. Photocatalytic degradation has the ability to convert economically complex dye molecules into non-toxic and smaller species via redox reactions, by using photocatalysts. g-C<sub>3</sub>N<sub>4</sub> is a metal-free n-type semiconductor, typical nonmetallic and non-toxici polymeric photocatalyst. It widely used in photocatalytic materials, due to its easy and simple synthesis, fascinating electronic band structure, high stability and abundant availability. As a photocatalyst, its major drawbacks are its limited efficiency in separating photo-excited electron–hole pairs, high separated charge recombination, low specific surface area, and low absorption coefficient. In this review, we report the recent modification strategies adopted for g-C<sub>3</sub>N<sub>4</sub> for the efficient photodegradation of MO dye. The different modification approaches, such as nanocomposites and heterojunctions, as well as doping and defect introductions, are briefly discussed. The mechanism of the photodegradation of MO dye by g-C<sub>3</sub>N<sub>4</sub> and future perspectives are discussed. This review paper will predict strategies for the fabrication of an efficient g-C<sub>3</sub>N<sub>4</sub>-based photocatalyst for the photodegradation of MO dye.
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spelling doaj.art-80362f09ce5949938b9cd2353cb36a062023-11-17T17:15:00ZengMDPI AGMolecules1420-30492023-04-01287319910.3390/molecules28073199g-C<sub>3</sub>N<sub>4</sub> Based Photocatalyst for the Efficient Photodegradation of Toxic Methyl Orange Dye: Recent Modifications and Future PerspectivesAbdulelah Aljuaid0Mazen Almehmadi1Ahad Amer Alsaiari2Mamdouh Allahyani3Osama Abdulaziz4Abdulaziz Alsharif5Jawaher Amer Alsaiari6Magdi Saih7Rema Turki Alotaibi8Idrees Khan9Department of Clinical Laboratory Sciences, College of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi ArabiaDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi ArabiaDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi ArabiaDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi ArabiaDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi ArabiaDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi ArabiaDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi ArabiaDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi ArabiaDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi ArabiaSchool of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi’an 710072, ChinaIndustrial effluents containing dyes are the dominant pollutants, making the drinking water unfit. Among the dyes, methylene orange (MO) dye is mutagenic, carcinogenic and toxic to aquatic organisms. Therefore, its removal from water bodies through effective and economical approach is gaining increased attention in the last decades. Photocatalytic degradation has the ability to convert economically complex dye molecules into non-toxic and smaller species via redox reactions, by using photocatalysts. g-C<sub>3</sub>N<sub>4</sub> is a metal-free n-type semiconductor, typical nonmetallic and non-toxici polymeric photocatalyst. It widely used in photocatalytic materials, due to its easy and simple synthesis, fascinating electronic band structure, high stability and abundant availability. As a photocatalyst, its major drawbacks are its limited efficiency in separating photo-excited electron–hole pairs, high separated charge recombination, low specific surface area, and low absorption coefficient. In this review, we report the recent modification strategies adopted for g-C<sub>3</sub>N<sub>4</sub> for the efficient photodegradation of MO dye. The different modification approaches, such as nanocomposites and heterojunctions, as well as doping and defect introductions, are briefly discussed. The mechanism of the photodegradation of MO dye by g-C<sub>3</sub>N<sub>4</sub> and future perspectives are discussed. This review paper will predict strategies for the fabrication of an efficient g-C<sub>3</sub>N<sub>4</sub>-based photocatalyst for the photodegradation of MO dye.https://www.mdpi.com/1420-3049/28/7/3199photodegradationphotocatalystg-C<sub>3</sub>N<sub>4</sub>modificationsmethyl orange
spellingShingle Abdulelah Aljuaid
Mazen Almehmadi
Ahad Amer Alsaiari
Mamdouh Allahyani
Osama Abdulaziz
Abdulaziz Alsharif
Jawaher Amer Alsaiari
Magdi Saih
Rema Turki Alotaibi
Idrees Khan
g-C<sub>3</sub>N<sub>4</sub> Based Photocatalyst for the Efficient Photodegradation of Toxic Methyl Orange Dye: Recent Modifications and Future Perspectives
Molecules
photodegradation
photocatalyst
g-C<sub>3</sub>N<sub>4</sub>
modifications
methyl orange
title g-C<sub>3</sub>N<sub>4</sub> Based Photocatalyst for the Efficient Photodegradation of Toxic Methyl Orange Dye: Recent Modifications and Future Perspectives
title_full g-C<sub>3</sub>N<sub>4</sub> Based Photocatalyst for the Efficient Photodegradation of Toxic Methyl Orange Dye: Recent Modifications and Future Perspectives
title_fullStr g-C<sub>3</sub>N<sub>4</sub> Based Photocatalyst for the Efficient Photodegradation of Toxic Methyl Orange Dye: Recent Modifications and Future Perspectives
title_full_unstemmed g-C<sub>3</sub>N<sub>4</sub> Based Photocatalyst for the Efficient Photodegradation of Toxic Methyl Orange Dye: Recent Modifications and Future Perspectives
title_short g-C<sub>3</sub>N<sub>4</sub> Based Photocatalyst for the Efficient Photodegradation of Toxic Methyl Orange Dye: Recent Modifications and Future Perspectives
title_sort g c sub 3 sub n sub 4 sub based photocatalyst for the efficient photodegradation of toxic methyl orange dye recent modifications and future perspectives
topic photodegradation
photocatalyst
g-C<sub>3</sub>N<sub>4</sub>
modifications
methyl orange
url https://www.mdpi.com/1420-3049/28/7/3199
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