Affinity Ionic Liquids for Chemoselective Gas Sensing

Selective gas sensing is of great importance for applications in health, safety, military, industry and environment. Many man-made and naturally occurring volatile organic compounds (VOCs) can harmfully affect human health or cause impairment to the environment. Gas analysis based on different princ...

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Main Authors: Albert Chang, Hsin-Yi Li, I-Nan Chang, Yen-Ho Chu
Format: Article
Language:English
Published: MDPI AG 2018-09-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/23/9/2380
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author Albert Chang
Hsin-Yi Li
I-Nan Chang
Yen-Ho Chu
author_facet Albert Chang
Hsin-Yi Li
I-Nan Chang
Yen-Ho Chu
author_sort Albert Chang
collection DOAJ
description Selective gas sensing is of great importance for applications in health, safety, military, industry and environment. Many man-made and naturally occurring volatile organic compounds (VOCs) can harmfully affect human health or cause impairment to the environment. Gas analysis based on different principles has been developed to convert gaseous analytes into readable output signals. However, gas sensors such as metal-oxide semiconductors suffer from high operating temperatures that are impractical and therefore have limited its applications. The cost-effective quartz crystal microbalance (QCM) device represents an excellent platform if sensitive, selective and versatile sensing materials were available. Recent advances in affinity ionic liquids (AILs) have led them to incorporation with QCM to be highly sensitive for real-time detection of target gases at ambient temperature. The tailorable functional groups in AIL structures allow for chemoselective reaction with target analytes for single digit parts-per-billion detection on mass-sensitive QCM. This structural diversity makes AILs promising for the creation of a library of chemical sensor arrays that could be designed to efficiently detect gas mixtures simultaneously as a potential electronic in future. This review first provides brief introduction to some conventional gas sensing technologies and then delivers the latest results on our development of chemoselective AIL-on-QCM methods.
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spelling doaj.art-803fbaa6fa5f49cb8d779b8cc7dcd0672022-12-21T19:03:20ZengMDPI AGMolecules1420-30492018-09-01239238010.3390/molecules23092380molecules23092380Affinity Ionic Liquids for Chemoselective Gas SensingAlbert Chang0Hsin-Yi Li1I-Nan Chang2Yen-Ho Chu3Department of Chemistry and Biochemistry, National Chung Cheng University, 168 University Road, Minghsiung, Chiayi 62102, TaiwanDepartment of Chemistry and Biochemistry, National Chung Cheng University, 168 University Road, Minghsiung, Chiayi 62102, TaiwanANT Technology Co., Ltd., 137, Section 1, Fushing South Road, Taipei 10666, TaiwanDepartment of Chemistry and Biochemistry, National Chung Cheng University, 168 University Road, Minghsiung, Chiayi 62102, TaiwanSelective gas sensing is of great importance for applications in health, safety, military, industry and environment. Many man-made and naturally occurring volatile organic compounds (VOCs) can harmfully affect human health or cause impairment to the environment. Gas analysis based on different principles has been developed to convert gaseous analytes into readable output signals. However, gas sensors such as metal-oxide semiconductors suffer from high operating temperatures that are impractical and therefore have limited its applications. The cost-effective quartz crystal microbalance (QCM) device represents an excellent platform if sensitive, selective and versatile sensing materials were available. Recent advances in affinity ionic liquids (AILs) have led them to incorporation with QCM to be highly sensitive for real-time detection of target gases at ambient temperature. The tailorable functional groups in AIL structures allow for chemoselective reaction with target analytes for single digit parts-per-billion detection on mass-sensitive QCM. This structural diversity makes AILs promising for the creation of a library of chemical sensor arrays that could be designed to efficiently detect gas mixtures simultaneously as a potential electronic in future. This review first provides brief introduction to some conventional gas sensing technologies and then delivers the latest results on our development of chemoselective AIL-on-QCM methods.http://www.mdpi.com/1420-3049/23/9/2380volatile organic compoundchemoselective gas analysisionic liquidquartz crystal microbalance
spellingShingle Albert Chang
Hsin-Yi Li
I-Nan Chang
Yen-Ho Chu
Affinity Ionic Liquids for Chemoselective Gas Sensing
Molecules
volatile organic compound
chemoselective gas analysis
ionic liquid
quartz crystal microbalance
title Affinity Ionic Liquids for Chemoselective Gas Sensing
title_full Affinity Ionic Liquids for Chemoselective Gas Sensing
title_fullStr Affinity Ionic Liquids for Chemoselective Gas Sensing
title_full_unstemmed Affinity Ionic Liquids for Chemoselective Gas Sensing
title_short Affinity Ionic Liquids for Chemoselective Gas Sensing
title_sort affinity ionic liquids for chemoselective gas sensing
topic volatile organic compound
chemoselective gas analysis
ionic liquid
quartz crystal microbalance
url http://www.mdpi.com/1420-3049/23/9/2380
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AT hsinyili affinityionicliquidsforchemoselectivegassensing
AT inanchang affinityionicliquidsforchemoselectivegassensing
AT yenhochu affinityionicliquidsforchemoselectivegassensing