Microstructure, domain structure, ferroelectric and piezoelectric properties of textured bismuth-containing ceramics
In this report, the processes of texture formation in grain-oriented ferroelectric ceramics based on layer-structured ferroelectric Bi4Ti3O2 (LSBT) prepared by hot forging method are considered. The microstructural and X-ray methods revealed the axial textured formation in ferroelectric ceramic that...
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World Scientific Publishing
2023-06-01
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| Series: | Journal of Advanced Dielectrics |
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| Online Access: | https://www.worldscientific.com/doi/10.1142/S2010135X2350011X |
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| author | E. I. Sitalo O. A. Bunina V. G. Smotrakov N. V. Malomyzheva N. A. Boldyrev |
| author_facet | E. I. Sitalo O. A. Bunina V. G. Smotrakov N. V. Malomyzheva N. A. Boldyrev |
| author_sort | E. I. Sitalo |
| collection | DOAJ |
| description | In this report, the processes of texture formation in grain-oriented ferroelectric ceramics based on layer-structured ferroelectric Bi4Ti3O2 (LSBT) prepared by hot forging method are considered. The microstructural and X-ray methods revealed the axial textured formation in ferroelectric ceramic that are used to estimate the orientation factor of ceramics. For the first time, the domain structure changes when poling the anisotropic ferroelectric ceramics are investigated. The anisotropy of electromechanical, piezoelectric and ferroelectric properties of ferroelectric ceramics due to the crystal texture existence in it is studied. The aim of this study is to study the processes of crystalline texture formation in polycrystalline BLSF and to establish the dependence of the electrophysical properties of ceramics on the degree of texturing. Ceramics were textured using the hot stamping (HS) method developed at the Research Institute of Physics. The mechanism of the method is that the workpiece is subjected to uniaxial pressure and free radial deformation occurs due to the plastic flow of the material until the workpiece fills the free volume of the mold, which is created by placing the workpiece in the mold with a gap. The study of the microstructure of ceramics showed that an increase in the firing temperature in the range 950–1050[Formula: see text]C causes a sharp decrease in porosity and increases the density to 7.95 g/[Formula: see text], which is 98% of theoretical. An X-ray analysis was performed and microstructural studies were carried out, which revealed the formation of an axial texture in ceramics. The features of the switching processes of textured ceramics are revealed. The characteristics of the polarization switching of ceramics in the directions parallel and perpendicular ([Formula: see text]) of the pressure axis during hot processing were obtained from the dielectric hysteresis [Formula: see text]([Formula: see text]) loops, i.e., axis axial texture. The [Formula: see text]-cut ceramics are characterized by a more complete polarization switching, which is associated with the additional orientation of the (001) crystallographic planes in the textured material, as well as the presence of a threshold switching field. In the temperature range from -196 to + 600[Formula: see text]C, the anisotropy of the electro physical properties of ceramics due to the presence of a crystalline texture in it was studied. The dielectric constant, electrical conductivity, piezoelectric and elastic coefficients were measured for sections of ceramics of different orientations relative to the axis of the texture. The anisotropy of the dielectric constant and electrical conductivity manifests itself weakly at room temperature and increases sharply when approaching the Curie temperature. In the temperature range +20–400[Formula: see text]C, the high thermal stability of the piezoelectric module [Formula: see text], measured by the quasistatic method, was established. |
| first_indexed | 2024-03-13T03:54:59Z |
| format | Article |
| id | doaj.art-80452bc57c614505969d26eea9762588 |
| institution | Directory Open Access Journal |
| issn | 2010-135X 2010-1368 |
| language | English |
| last_indexed | 2024-03-13T03:54:59Z |
| publishDate | 2023-06-01 |
| publisher | World Scientific Publishing |
| record_format | Article |
| series | Journal of Advanced Dielectrics |
| spelling | doaj.art-80452bc57c614505969d26eea97625882023-06-22T06:45:45ZengWorld Scientific PublishingJournal of Advanced Dielectrics2010-135X2010-13682023-06-01130310.1142/S2010135X2350011XMicrostructure, domain structure, ferroelectric and piezoelectric properties of textured bismuth-containing ceramicsE. I. Sitalo0O. A. Bunina1V. G. Smotrakov2N. V. Malomyzheva3N. A. Boldyrev4Research Institute of Physics, Southern Federal University, No. 194 Stachki Avenue, Rostov-on-Don 344090, RussiaResearch Institute of Physics, Southern Federal University, No. 194 Stachki Avenue, Rostov-on-Don 344090, RussiaResearch Institute of Physics, Southern Federal University, No. 194 Stachki Avenue, Rostov-on-Don 344090, RussiaResearch Institute of Physics, Southern Federal University, No. 194 Stachki Avenue, Rostov-on-Don 344090, RussiaResearch Institute of Physics, Southern Federal University, No. 194 Stachki Avenue, Rostov-on-Don 344090, RussiaIn this report, the processes of texture formation in grain-oriented ferroelectric ceramics based on layer-structured ferroelectric Bi4Ti3O2 (LSBT) prepared by hot forging method are considered. The microstructural and X-ray methods revealed the axial textured formation in ferroelectric ceramic that are used to estimate the orientation factor of ceramics. For the first time, the domain structure changes when poling the anisotropic ferroelectric ceramics are investigated. The anisotropy of electromechanical, piezoelectric and ferroelectric properties of ferroelectric ceramics due to the crystal texture existence in it is studied. The aim of this study is to study the processes of crystalline texture formation in polycrystalline BLSF and to establish the dependence of the electrophysical properties of ceramics on the degree of texturing. Ceramics were textured using the hot stamping (HS) method developed at the Research Institute of Physics. The mechanism of the method is that the workpiece is subjected to uniaxial pressure and free radial deformation occurs due to the plastic flow of the material until the workpiece fills the free volume of the mold, which is created by placing the workpiece in the mold with a gap. The study of the microstructure of ceramics showed that an increase in the firing temperature in the range 950–1050[Formula: see text]C causes a sharp decrease in porosity and increases the density to 7.95 g/[Formula: see text], which is 98% of theoretical. An X-ray analysis was performed and microstructural studies were carried out, which revealed the formation of an axial texture in ceramics. The features of the switching processes of textured ceramics are revealed. The characteristics of the polarization switching of ceramics in the directions parallel and perpendicular ([Formula: see text]) of the pressure axis during hot processing were obtained from the dielectric hysteresis [Formula: see text]([Formula: see text]) loops, i.e., axis axial texture. The [Formula: see text]-cut ceramics are characterized by a more complete polarization switching, which is associated with the additional orientation of the (001) crystallographic planes in the textured material, as well as the presence of a threshold switching field. In the temperature range from -196 to + 600[Formula: see text]C, the anisotropy of the electro physical properties of ceramics due to the presence of a crystalline texture in it was studied. The dielectric constant, electrical conductivity, piezoelectric and elastic coefficients were measured for sections of ceramics of different orientations relative to the axis of the texture. The anisotropy of the dielectric constant and electrical conductivity manifests itself weakly at room temperature and increases sharply when approaching the Curie temperature. In the temperature range +20–400[Formula: see text]C, the high thermal stability of the piezoelectric module [Formula: see text], measured by the quasistatic method, was established.https://www.worldscientific.com/doi/10.1142/S2010135X2350011XTextured ceramicsmicrostructuredomain structurepermittivitypiezoelectric moduleselastic coefficients |
| spellingShingle | E. I. Sitalo O. A. Bunina V. G. Smotrakov N. V. Malomyzheva N. A. Boldyrev Microstructure, domain structure, ferroelectric and piezoelectric properties of textured bismuth-containing ceramics Journal of Advanced Dielectrics Textured ceramics microstructure domain structure permittivity piezoelectric modules elastic coefficients |
| title | Microstructure, domain structure, ferroelectric and piezoelectric properties of textured bismuth-containing ceramics |
| title_full | Microstructure, domain structure, ferroelectric and piezoelectric properties of textured bismuth-containing ceramics |
| title_fullStr | Microstructure, domain structure, ferroelectric and piezoelectric properties of textured bismuth-containing ceramics |
| title_full_unstemmed | Microstructure, domain structure, ferroelectric and piezoelectric properties of textured bismuth-containing ceramics |
| title_short | Microstructure, domain structure, ferroelectric and piezoelectric properties of textured bismuth-containing ceramics |
| title_sort | microstructure domain structure ferroelectric and piezoelectric properties of textured bismuth containing ceramics |
| topic | Textured ceramics microstructure domain structure permittivity piezoelectric modules elastic coefficients |
| url | https://www.worldscientific.com/doi/10.1142/S2010135X2350011X |
| work_keys_str_mv | AT eisitalo microstructuredomainstructureferroelectricandpiezoelectricpropertiesoftexturedbismuthcontainingceramics AT oabunina microstructuredomainstructureferroelectricandpiezoelectricpropertiesoftexturedbismuthcontainingceramics AT vgsmotrakov microstructuredomainstructureferroelectricandpiezoelectricpropertiesoftexturedbismuthcontainingceramics AT nvmalomyzheva microstructuredomainstructureferroelectricandpiezoelectricpropertiesoftexturedbismuthcontainingceramics AT naboldyrev microstructuredomainstructureferroelectricandpiezoelectricpropertiesoftexturedbismuthcontainingceramics |