Environmental concentrations as ratios of random variables

Human-induced environmental change increasingly threatens the stability of socio-ecological systems. Careful statistical characterization of environmental concentrations is critical to quantify and predict the consequences of such changes on human and ecosystems conditions. However, while concentrat...

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Main Authors: Saverio Perri, Amilcare Porporato
Format: Article
Language:English
Published: IOP Publishing 2022-01-01
Series:Environmental Research Letters
Subjects:
Online Access:https://doi.org/10.1088/1748-9326/ac4a9f
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author Saverio Perri
Amilcare Porporato
author_facet Saverio Perri
Amilcare Porporato
author_sort Saverio Perri
collection DOAJ
description Human-induced environmental change increasingly threatens the stability of socio-ecological systems. Careful statistical characterization of environmental concentrations is critical to quantify and predict the consequences of such changes on human and ecosystems conditions. However, while concentrations are naturally defined as the ratio between solute mass and solvent volume, they have rarely been treated as such, typically limiting the analysis to familiar distributions generically used for any other environmental variable. To address this gap, we propose a more general framework that leverages their definition explicitly as ratios of random variables. We show that the resulting models accurately describe the behavior of nitrate plus nitrite in US rivers and salt concentration in estuaries in the Everglades by accounting for heavy tails potentially emerging when the water volume fluctuates around low values. Models that preclude the presence of heavy tails and the related high probability of extreme concentrations could significantly undermine the accuracy of diagnostic frameworks and the effectiveness of mitigation interventions, especially for soil contamination characterized by a water volume (i.e. soil moisture) frequently approaching zero.
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spelling doaj.art-805743827a9c4421a149b4afe231902f2023-08-09T15:25:48ZengIOP PublishingEnvironmental Research Letters1748-93262022-01-0117202401110.1088/1748-9326/ac4a9fEnvironmental concentrations as ratios of random variablesSaverio Perri0https://orcid.org/0000-0001-6382-1381Amilcare Porporato1https://orcid.org/0000-0001-9378-207XHigh Meadows Environmental Institute, Princeton University , Princeton, NJ 08544, United States of AmericaHigh Meadows Environmental Institute, Princeton University , Princeton, NJ 08544, United States of America; Department of Civil and Environmental Engineering, Princeton University , Princeton, NJ 08540, United States of AmericaHuman-induced environmental change increasingly threatens the stability of socio-ecological systems. Careful statistical characterization of environmental concentrations is critical to quantify and predict the consequences of such changes on human and ecosystems conditions. However, while concentrations are naturally defined as the ratio between solute mass and solvent volume, they have rarely been treated as such, typically limiting the analysis to familiar distributions generically used for any other environmental variable. To address this gap, we propose a more general framework that leverages their definition explicitly as ratios of random variables. We show that the resulting models accurately describe the behavior of nitrate plus nitrite in US rivers and salt concentration in estuaries in the Everglades by accounting for heavy tails potentially emerging when the water volume fluctuates around low values. Models that preclude the presence of heavy tails and the related high probability of extreme concentrations could significantly undermine the accuracy of diagnostic frameworks and the effectiveness of mitigation interventions, especially for soil contamination characterized by a water volume (i.e. soil moisture) frequently approaching zero.https://doi.org/10.1088/1748-9326/ac4a9fenvironmental concentrationsratio distributionsrisk assessmentnitratessalinityenvironmental change
spellingShingle Saverio Perri
Amilcare Porporato
Environmental concentrations as ratios of random variables
Environmental Research Letters
environmental concentrations
ratio distributions
risk assessment
nitrates
salinity
environmental change
title Environmental concentrations as ratios of random variables
title_full Environmental concentrations as ratios of random variables
title_fullStr Environmental concentrations as ratios of random variables
title_full_unstemmed Environmental concentrations as ratios of random variables
title_short Environmental concentrations as ratios of random variables
title_sort environmental concentrations as ratios of random variables
topic environmental concentrations
ratio distributions
risk assessment
nitrates
salinity
environmental change
url https://doi.org/10.1088/1748-9326/ac4a9f
work_keys_str_mv AT saverioperri environmentalconcentrationsasratiosofrandomvariables
AT amilcareporporato environmentalconcentrationsasratiosofrandomvariables