Genesis of Complex Polyiodide Networks: Insights on the Blue Box/I<sup>−</sup>/I<sub>2</sub> Ternary System
The Stoddart’s blue box (BB) (cyclobis(paraquat-p-phenylene))/iodide binary system was recently demonstrated to give rise to porous three-dimensional networks which can hardly be classified as common XOF-type materials (X = M, C, S, i.e., metal, covalent, or supramolecular organic frameworks), leadi...
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| Format: | Article |
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MDPI AG
2020-05-01
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| Series: | Crystals |
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| Online Access: | https://www.mdpi.com/2073-4352/10/5/387 |
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| author | Matteo Savastano Carla Bazzicalupi Cristina Gellini Antonio Bianchi |
| author_facet | Matteo Savastano Carla Bazzicalupi Cristina Gellini Antonio Bianchi |
| author_sort | Matteo Savastano |
| collection | DOAJ |
| description | The Stoddart’s blue box (BB) (cyclobis(paraquat-p-phenylene))/iodide binary system was recently demonstrated to give rise to porous three-dimensional networks which can hardly be classified as common XOF-type materials (X = M, C, S, i.e., metal, covalent, or supramolecular organic frameworks), leading to the definition of permutable organized frameworks (POFs). The ternary BB/iodide/iodine system was reported to generate pentaiodide-based structures constituted by the most complex interlocked polyiodides so far isolated (up to an infinite supramolecular pseudopolyrotaxane with a poly[3]catenane axle). The missing link, i.e., the XRD structure of the BB/triiodide complex, is herein reported: structural similarities and novel Raman evidence, opening perspectives in the genesis of solid-state BB-based complex polyiodide networks from solution. |
| first_indexed | 2024-03-10T19:56:31Z |
| format | Article |
| id | doaj.art-807b3d81f8d24c07a4bd776e81913209 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-03-10T19:56:31Z |
| publishDate | 2020-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-807b3d81f8d24c07a4bd776e819132092023-11-19T23:53:24ZengMDPI AGCrystals2073-43522020-05-0110538710.3390/cryst10050387Genesis of Complex Polyiodide Networks: Insights on the Blue Box/I<sup>−</sup>/I<sub>2</sub> Ternary SystemMatteo Savastano0Carla Bazzicalupi1Cristina Gellini2Antonio Bianchi3Department of Chemistry “Ugo Schiff”, University of Florence, Via della Lastruccia, 3-13, 50019 Sesto Fiorentino, ItalyDepartment of Chemistry “Ugo Schiff”, University of Florence, Via della Lastruccia, 3-13, 50019 Sesto Fiorentino, ItalyDepartment of Chemistry “Ugo Schiff”, University of Florence, Via della Lastruccia, 3-13, 50019 Sesto Fiorentino, ItalyDepartment of Chemistry “Ugo Schiff”, University of Florence, Via della Lastruccia, 3-13, 50019 Sesto Fiorentino, ItalyThe Stoddart’s blue box (BB) (cyclobis(paraquat-p-phenylene))/iodide binary system was recently demonstrated to give rise to porous three-dimensional networks which can hardly be classified as common XOF-type materials (X = M, C, S, i.e., metal, covalent, or supramolecular organic frameworks), leading to the definition of permutable organized frameworks (POFs). The ternary BB/iodide/iodine system was reported to generate pentaiodide-based structures constituted by the most complex interlocked polyiodides so far isolated (up to an infinite supramolecular pseudopolyrotaxane with a poly[3]catenane axle). The missing link, i.e., the XRD structure of the BB/triiodide complex, is herein reported: structural similarities and novel Raman evidence, opening perspectives in the genesis of solid-state BB-based complex polyiodide networks from solution.https://www.mdpi.com/2073-4352/10/5/387supramolecular chemistrypolyiodidesStoddart’s blue boxpentaiodideanion-π interactionsself-assembly |
| spellingShingle | Matteo Savastano Carla Bazzicalupi Cristina Gellini Antonio Bianchi Genesis of Complex Polyiodide Networks: Insights on the Blue Box/I<sup>−</sup>/I<sub>2</sub> Ternary System Crystals supramolecular chemistry polyiodides Stoddart’s blue box pentaiodide anion-π interactions self-assembly |
| title | Genesis of Complex Polyiodide Networks: Insights on the Blue Box/I<sup>−</sup>/I<sub>2</sub> Ternary System |
| title_full | Genesis of Complex Polyiodide Networks: Insights on the Blue Box/I<sup>−</sup>/I<sub>2</sub> Ternary System |
| title_fullStr | Genesis of Complex Polyiodide Networks: Insights on the Blue Box/I<sup>−</sup>/I<sub>2</sub> Ternary System |
| title_full_unstemmed | Genesis of Complex Polyiodide Networks: Insights on the Blue Box/I<sup>−</sup>/I<sub>2</sub> Ternary System |
| title_short | Genesis of Complex Polyiodide Networks: Insights on the Blue Box/I<sup>−</sup>/I<sub>2</sub> Ternary System |
| title_sort | genesis of complex polyiodide networks insights on the blue box i sup sup i sub 2 sub ternary system |
| topic | supramolecular chemistry polyiodides Stoddart’s blue box pentaiodide anion-π interactions self-assembly |
| url | https://www.mdpi.com/2073-4352/10/5/387 |
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