Variability of sea salt and methanesulfonate in firn cores from northern Victoria Land, Antarctica: Their links to oceanic and atmospheric condition variability in the Ross Sea

The potential ice core proxies of variability in oceanic and atmospheric conditions over the Ross Sea were evaluated. This study examined sea salt sodium (ss–Na+) and biogenic sulfur (methanesulfonate, MS–) records, covering 23 years between 1990 and 2012, from two firn cores drilled on the Styx Gla...

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Main Authors: Seokhyun Ro, Sang-Bum Hong, Joo-Hong Kim, Yeongcheol Han, Soon Do Hur, Jung-Ho Kang, Songyi Kim, Changkyu Lim, Chaewon Chang, Jangil Moon, Seong-Joong Kim, Sungmin Hong
Format: Article
Language:English
Published: Frontiers Media S.A. 2022-09-01
Series:Frontiers in Earth Science
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/feart.2022.896470/full
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author Seokhyun Ro
Seokhyun Ro
Sang-Bum Hong
Joo-Hong Kim
Yeongcheol Han
Soon Do Hur
Jung-Ho Kang
Songyi Kim
Songyi Kim
Changkyu Lim
Chaewon Chang
Jangil Moon
Seong-Joong Kim
Sungmin Hong
author_facet Seokhyun Ro
Seokhyun Ro
Sang-Bum Hong
Joo-Hong Kim
Yeongcheol Han
Soon Do Hur
Jung-Ho Kang
Songyi Kim
Songyi Kim
Changkyu Lim
Chaewon Chang
Jangil Moon
Seong-Joong Kim
Sungmin Hong
author_sort Seokhyun Ro
collection DOAJ
description The potential ice core proxies of variability in oceanic and atmospheric conditions over the Ross Sea were evaluated. This study examined sea salt sodium (ss–Na+) and biogenic sulfur (methanesulfonate, MS–) records, covering 23 years between 1990 and 2012, from two firn cores drilled on the Styx Glacier plateau (SGP), northern Victoria Land, East Antarctica, to examine the potential links between those records and datasets for various climate variables. The comparison showed that the interannual variability of the ss–Na+ record is closely related to Pacific–South American mode 2 (PSA2) in the Ross Sea sector, exhibiting an increased ss–Na+ flux, owing most likely to more frequent penetration of maritime air masses from the western Ross Sea to the SGP when the winter/spring PSA2 mode becomes more pronounced. The observed MS– record revealed statistically significant positive correlations with the changes in the summertime chlorophyll a concentration in the Ross Sea polynya (RSP) and wind speed in the southern Ross Sea region. This indicates the dominant role of a combination of changes in the summertime primary productivity and wind speed over the RSP in modulating the MS– deposition flux at the SGP. These results highlight the suitability of the ss–Na+ and MS– records from the SGP as proxies for characterizing the dominant patterns of variability in oceanic and atmospheric conditions and their underlying mechanisms on interannual and longer timescales beyond the instrumental limits over the Ross Sea region.
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spelling doaj.art-807dce82735847e08f08a480cef77e0c2022-12-22T01:43:41ZengFrontiers Media S.A.Frontiers in Earth Science2296-64632022-09-011010.3389/feart.2022.896470896470Variability of sea salt and methanesulfonate in firn cores from northern Victoria Land, Antarctica: Their links to oceanic and atmospheric condition variability in the Ross SeaSeokhyun Ro0Seokhyun Ro1Sang-Bum Hong2Joo-Hong Kim3Yeongcheol Han4Soon Do Hur5Jung-Ho Kang6Songyi Kim7Songyi Kim8Changkyu Lim9Chaewon Chang10Jangil Moon11Seong-Joong Kim12Sungmin Hong13Department of Ocean Sciences, College of Natural Sciences, Inha University, Incheon, South KoreaKorea Polar Research Institute, Incheon, South KoreaKorea Polar Research Institute, Incheon, South KoreaKorea Polar Research Institute, Incheon, South KoreaKorea Polar Research Institute, Incheon, South KoreaKorea Polar Research Institute, Incheon, South KoreaKorea Polar Research Institute, Incheon, South KoreaKorea Polar Research Institute, Incheon, South KoreaDepartment of Science Education, Ewha Womans University, Seoul, South KoreaKorea Polar Research Institute, Incheon, South KoreaKorea Polar Research Institute, Incheon, South KoreaKorea Polar Research Institute, Incheon, South KoreaKorea Polar Research Institute, Incheon, South KoreaDepartment of Ocean Sciences, College of Natural Sciences, Inha University, Incheon, South KoreaThe potential ice core proxies of variability in oceanic and atmospheric conditions over the Ross Sea were evaluated. This study examined sea salt sodium (ss–Na+) and biogenic sulfur (methanesulfonate, MS–) records, covering 23 years between 1990 and 2012, from two firn cores drilled on the Styx Glacier plateau (SGP), northern Victoria Land, East Antarctica, to examine the potential links between those records and datasets for various climate variables. The comparison showed that the interannual variability of the ss–Na+ record is closely related to Pacific–South American mode 2 (PSA2) in the Ross Sea sector, exhibiting an increased ss–Na+ flux, owing most likely to more frequent penetration of maritime air masses from the western Ross Sea to the SGP when the winter/spring PSA2 mode becomes more pronounced. The observed MS– record revealed statistically significant positive correlations with the changes in the summertime chlorophyll a concentration in the Ross Sea polynya (RSP) and wind speed in the southern Ross Sea region. This indicates the dominant role of a combination of changes in the summertime primary productivity and wind speed over the RSP in modulating the MS– deposition flux at the SGP. These results highlight the suitability of the ss–Na+ and MS– records from the SGP as proxies for characterizing the dominant patterns of variability in oceanic and atmospheric conditions and their underlying mechanisms on interannual and longer timescales beyond the instrumental limits over the Ross Sea region.https://www.frontiersin.org/articles/10.3389/feart.2022.896470/fullRoss SeaStyx firn coressea salt sodiummethanesulfonatePacific–South American modeRoss Sea polynya
spellingShingle Seokhyun Ro
Seokhyun Ro
Sang-Bum Hong
Joo-Hong Kim
Yeongcheol Han
Soon Do Hur
Jung-Ho Kang
Songyi Kim
Songyi Kim
Changkyu Lim
Chaewon Chang
Jangil Moon
Seong-Joong Kim
Sungmin Hong
Variability of sea salt and methanesulfonate in firn cores from northern Victoria Land, Antarctica: Their links to oceanic and atmospheric condition variability in the Ross Sea
Frontiers in Earth Science
Ross Sea
Styx firn cores
sea salt sodium
methanesulfonate
Pacific–South American mode
Ross Sea polynya
title Variability of sea salt and methanesulfonate in firn cores from northern Victoria Land, Antarctica: Their links to oceanic and atmospheric condition variability in the Ross Sea
title_full Variability of sea salt and methanesulfonate in firn cores from northern Victoria Land, Antarctica: Their links to oceanic and atmospheric condition variability in the Ross Sea
title_fullStr Variability of sea salt and methanesulfonate in firn cores from northern Victoria Land, Antarctica: Their links to oceanic and atmospheric condition variability in the Ross Sea
title_full_unstemmed Variability of sea salt and methanesulfonate in firn cores from northern Victoria Land, Antarctica: Their links to oceanic and atmospheric condition variability in the Ross Sea
title_short Variability of sea salt and methanesulfonate in firn cores from northern Victoria Land, Antarctica: Their links to oceanic and atmospheric condition variability in the Ross Sea
title_sort variability of sea salt and methanesulfonate in firn cores from northern victoria land antarctica their links to oceanic and atmospheric condition variability in the ross sea
topic Ross Sea
Styx firn cores
sea salt sodium
methanesulfonate
Pacific–South American mode
Ross Sea polynya
url https://www.frontiersin.org/articles/10.3389/feart.2022.896470/full
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