Self‐Assembly of Hydrogen‐Bonded Organic Crystals on Arbitrary Surfaces for Efficient Amplified Spontaneous Emission
Organic lasers attract much attention due to their high efficiency, low energy consumption, and structural flexibility. However, long‐term stability and the creation of the lasers on arbitrary surfaces remain a challenge. Here, a synthesis of amide‐based organic molecules that provides packing into...
| Main Authors: | , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley-VCH
2024-02-01
|
| Series: | Advanced Photonics Research |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/adpr.202300173 |
| _version_ | 1797329452135350272 |
|---|---|
| author | Yuliya Kenzhebayeva Irina Gorbunova Arthur Dolgopolov Maksim V. Dmitriev Timur Sh. Atabaev Evgeniia A. Stepanidenko Anastasiia S. Efimova Alexander S. Novikov Sergei Shipilovskikh Valentin A. Milichko |
| author_facet | Yuliya Kenzhebayeva Irina Gorbunova Arthur Dolgopolov Maksim V. Dmitriev Timur Sh. Atabaev Evgeniia A. Stepanidenko Anastasiia S. Efimova Alexander S. Novikov Sergei Shipilovskikh Valentin A. Milichko |
| author_sort | Yuliya Kenzhebayeva |
| collection | DOAJ |
| description | Organic lasers attract much attention due to their high efficiency, low energy consumption, and structural flexibility. However, long‐term stability and the creation of the lasers on arbitrary surfaces remain a challenge. Here, a synthesis of amide‐based organic molecules that provides packing into hydrogen‐bonded organic crystals (OCs) is reported. The resulting OCs demonstrate an amplified spontaneous emission (ASE) regime with 0.55 μJ cm−2 threshold under the normal conditions due to 5%–13% quantum yield and high emission rate (1.02 ns). The simple process of self‐assembly of the hydrogen‐bonded OCs and highly stable ASE (over 30 min of continuous operation) allow fabricating fibers, flexible polymers, and hard planar periodic optical systems based on them, which paves the way to creating organic laser diodes of an arbitrary design. |
| first_indexed | 2024-03-08T07:05:50Z |
| format | Article |
| id | doaj.art-8082eba64eb84f5382792e17324629bc |
| institution | Directory Open Access Journal |
| issn | 2699-9293 |
| language | English |
| last_indexed | 2024-03-08T07:05:50Z |
| publishDate | 2024-02-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | Advanced Photonics Research |
| spelling | doaj.art-8082eba64eb84f5382792e17324629bc2024-02-03T04:49:20ZengWiley-VCHAdvanced Photonics Research2699-92932024-02-0152n/an/a10.1002/adpr.202300173Self‐Assembly of Hydrogen‐Bonded Organic Crystals on Arbitrary Surfaces for Efficient Amplified Spontaneous EmissionYuliya Kenzhebayeva0Irina Gorbunova1Arthur Dolgopolov2Maksim V. Dmitriev3Timur Sh. Atabaev4Evgeniia A. Stepanidenko5Anastasiia S. Efimova6Alexander S. Novikov7Sergei Shipilovskikh8Valentin A. Milichko9School of Physics and Engineering ITMO University St. Petersburg 197101 RussiaSchool of Physics and Engineering ITMO University St. Petersburg 197101 RussiaSchool of Physics and Engineering ITMO University St. Petersburg 197101 RussiaDepartment of Chemistry Perm State University Perm 614990 RussiaDepartment of Chemistry Nazarbayev University Astana 010000 KazakhstanInternational Research and Educational Center for Physics of Nanostructures ITMO University St. Petersburg 197101 RussiaSchool of Physics and Engineering ITMO University St. Petersburg 197101 RussiaInstitute of Chemistry Saint Petersburg State University St. Petersburg 199034 RussiaSchool of Physics and Engineering ITMO University St. Petersburg 197101 RussiaInstitut Jean Lamour Universite de Lorraine CNRS F-54000 Nancy FranceOrganic lasers attract much attention due to their high efficiency, low energy consumption, and structural flexibility. However, long‐term stability and the creation of the lasers on arbitrary surfaces remain a challenge. Here, a synthesis of amide‐based organic molecules that provides packing into hydrogen‐bonded organic crystals (OCs) is reported. The resulting OCs demonstrate an amplified spontaneous emission (ASE) regime with 0.55 μJ cm−2 threshold under the normal conditions due to 5%–13% quantum yield and high emission rate (1.02 ns). The simple process of self‐assembly of the hydrogen‐bonded OCs and highly stable ASE (over 30 min of continuous operation) allow fabricating fibers, flexible polymers, and hard planar periodic optical systems based on them, which paves the way to creating organic laser diodes of an arbitrary design.https://doi.org/10.1002/adpr.202300173amidesamplified spontaneous emissionnonlinear opticsorganic crystalsself-assembly |
| spellingShingle | Yuliya Kenzhebayeva Irina Gorbunova Arthur Dolgopolov Maksim V. Dmitriev Timur Sh. Atabaev Evgeniia A. Stepanidenko Anastasiia S. Efimova Alexander S. Novikov Sergei Shipilovskikh Valentin A. Milichko Self‐Assembly of Hydrogen‐Bonded Organic Crystals on Arbitrary Surfaces for Efficient Amplified Spontaneous Emission Advanced Photonics Research amides amplified spontaneous emission nonlinear optics organic crystals self-assembly |
| title | Self‐Assembly of Hydrogen‐Bonded Organic Crystals on Arbitrary Surfaces for Efficient Amplified Spontaneous Emission |
| title_full | Self‐Assembly of Hydrogen‐Bonded Organic Crystals on Arbitrary Surfaces for Efficient Amplified Spontaneous Emission |
| title_fullStr | Self‐Assembly of Hydrogen‐Bonded Organic Crystals on Arbitrary Surfaces for Efficient Amplified Spontaneous Emission |
| title_full_unstemmed | Self‐Assembly of Hydrogen‐Bonded Organic Crystals on Arbitrary Surfaces for Efficient Amplified Spontaneous Emission |
| title_short | Self‐Assembly of Hydrogen‐Bonded Organic Crystals on Arbitrary Surfaces for Efficient Amplified Spontaneous Emission |
| title_sort | self assembly of hydrogen bonded organic crystals on arbitrary surfaces for efficient amplified spontaneous emission |
| topic | amides amplified spontaneous emission nonlinear optics organic crystals self-assembly |
| url | https://doi.org/10.1002/adpr.202300173 |
| work_keys_str_mv | AT yuliyakenzhebayeva selfassemblyofhydrogenbondedorganiccrystalsonarbitrarysurfacesforefficientamplifiedspontaneousemission AT irinagorbunova selfassemblyofhydrogenbondedorganiccrystalsonarbitrarysurfacesforefficientamplifiedspontaneousemission AT arthurdolgopolov selfassemblyofhydrogenbondedorganiccrystalsonarbitrarysurfacesforefficientamplifiedspontaneousemission AT maksimvdmitriev selfassemblyofhydrogenbondedorganiccrystalsonarbitrarysurfacesforefficientamplifiedspontaneousemission AT timurshatabaev selfassemblyofhydrogenbondedorganiccrystalsonarbitrarysurfacesforefficientamplifiedspontaneousemission AT evgeniiaastepanidenko selfassemblyofhydrogenbondedorganiccrystalsonarbitrarysurfacesforefficientamplifiedspontaneousemission AT anastasiiasefimova selfassemblyofhydrogenbondedorganiccrystalsonarbitrarysurfacesforefficientamplifiedspontaneousemission AT alexandersnovikov selfassemblyofhydrogenbondedorganiccrystalsonarbitrarysurfacesforefficientamplifiedspontaneousemission AT sergeishipilovskikh selfassemblyofhydrogenbondedorganiccrystalsonarbitrarysurfacesforefficientamplifiedspontaneousemission AT valentinamilichko selfassemblyofhydrogenbondedorganiccrystalsonarbitrarysurfacesforefficientamplifiedspontaneousemission |