Enhanced Naproxen Elimination in Water by Catalytic Ozonation Based on NiO Films
This study evaluates naproxen (NP) degradation efficiency by ozonation using nickel oxide films (<inline-formula><math display="inline"><semantics><mrow><mi>N</mi><mi>i</mi><msub><mi>O</mi><mrow><mo>(</mo>&...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2020-08-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/10/8/884 |
| _version_ | 1797560268630261760 |
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| author | Claudia M. Aguilar-Melo Julia L. Rodríguez Isaac Chairez Iván Salgado J. A. Andraca Adame J. A. Galaviz-Pérez Jorge Vazquez-Arenas Tatyana Poznyak |
| author_facet | Claudia M. Aguilar-Melo Julia L. Rodríguez Isaac Chairez Iván Salgado J. A. Andraca Adame J. A. Galaviz-Pérez Jorge Vazquez-Arenas Tatyana Poznyak |
| author_sort | Claudia M. Aguilar-Melo |
| collection | DOAJ |
| description | This study evaluates naproxen (NP) degradation efficiency by ozonation using nickel oxide films (<inline-formula><math display="inline"><semantics><mrow><mi>N</mi><mi>i</mi><msub><mi>O</mi><mrow><mo>(</mo><mi>F</mi><mo>)</mo></mrow></msub></mrow></semantics></math></inline-formula>) as a catalyst. The <i>NiO</i> films were synthesized by chemical vapor deposition and characterized by X-ray diffraction, scanning electron microscopy, atomic force microscopy and X-ray photoelectron spectroscopy. NP degradation was conducted for 5 min using 10 films of <inline-formula><math display="inline"><semantics><mrow><mi>N</mi><mi>i</mi><msub><mi>O</mi><mrow><mo>(</mo><mi>F</mi><mo>)</mo></mrow></msub></mrow></semantics></math></inline-formula> comparing against ozonation using 100 mg/L <inline-formula><math display="inline"><semantics><mrow><mi>N</mi><mi>i</mi><mi>O</mi></mrow></semantics></math></inline-formula> powder in suspension (<inline-formula><math display="inline"><semantics><mrow><mi>N</mi><mi>i</mi><msub><mi>O</mi><mrow><mo>(</mo><mi>S</mi><mo>)</mo></mrow></msub></mrow></semantics></math></inline-formula>) and conventional ozonation (<inline-formula><math display="inline"><semantics><msub><mi>O</mi><mn>3</mn></msub></semantics></math></inline-formula>-conv). Total organic carbon analysis demonstrated a mineralization degree of 12% with <inline-formula><math display="inline"><semantics><msub><mi>O</mi><mn>3</mn></msub></semantics></math></inline-formula>-conv, 35% with <inline-formula><math display="inline"><semantics><mrow><mi>N</mi><mi>i</mi><mi>O</mi></mrow></semantics></math></inline-formula> as powder and 22% with <inline-formula><math display="inline"><semantics><mrow><mi>N</mi><mi>i</mi><msub><mi>O</mi><mrow><mo>(</mo><mi>F</mi><mo>)</mo></mrow></msub></mrow></semantics></math></inline-formula> after 60 min of reaction. The films of <inline-formula><math display="inline"><semantics><mrow><mi>N</mi><mi>i</mi><msub><mi>O</mi><mrow><mo>(</mo><mi>F</mi><mo>)</mo></mrow></msub></mrow></semantics></math></inline-formula> were sequentially used 4 times in ozonation demonstrating the stability of the synthesized material, as well as its properties as a catalyst for ozonation. A proposed modeling strategy using robust parametric identification techniques allows the comparison of NP decomposition pseudo-monomolecular reaction rates. |
| first_indexed | 2024-03-10T17:57:05Z |
| format | Article |
| id | doaj.art-809605bff6954329877ca90eb499d765 |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-10T17:57:05Z |
| publishDate | 2020-08-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-809605bff6954329877ca90eb499d7652023-11-20T09:08:36ZengMDPI AGCatalysts2073-43442020-08-0110888410.3390/catal10080884Enhanced Naproxen Elimination in Water by Catalytic Ozonation Based on NiO FilmsClaudia M. Aguilar-Melo0Julia L. Rodríguez1Isaac Chairez2Iván Salgado3J. A. Andraca Adame4J. A. Galaviz-Pérez5Jorge Vazquez-Arenas6Tatyana Poznyak7Departamento de Ingeniería de Procesos e Hidráulica, Universidad Autónoma Metropolitana-Itzapalapa, Ciudad de México 09340, MexicoLaboratorio de Ing. Química Ambiental, ESIQIE—Instituto Politécnico Nacional, Ciudad de México 07340, MexicoDepartamento de Bioprocesos, UPIBI—Instituto Politécnico Nacional, Ciudad de México 07340, MexicoCIDETEC—Instituto Politécnico Nacional, Ciudad de México 07340, MexicoDepartamento Ciencias Básicas, UPIIH—Instituto Politécnico Nacional, Hidalgo 42050, MexicoDivisión Académica Multidisciplinaria de Jalpa de Méndez, Universidad Juárez Autónoma de Tabasco, Villahermosa 86049, MexicoCatedra Conacyt—Departamento de Química, Universidad Autónoma Metropolitana—Iztapalapa, Av. San Rafael Atlixco No. 186, Ciudad de México 09340, MexicoLaboratorio de Ing. Química Ambiental, ESIQIE—Instituto Politécnico Nacional, Ciudad de México 07340, MexicoThis study evaluates naproxen (NP) degradation efficiency by ozonation using nickel oxide films (<inline-formula><math display="inline"><semantics><mrow><mi>N</mi><mi>i</mi><msub><mi>O</mi><mrow><mo>(</mo><mi>F</mi><mo>)</mo></mrow></msub></mrow></semantics></math></inline-formula>) as a catalyst. The <i>NiO</i> films were synthesized by chemical vapor deposition and characterized by X-ray diffraction, scanning electron microscopy, atomic force microscopy and X-ray photoelectron spectroscopy. NP degradation was conducted for 5 min using 10 films of <inline-formula><math display="inline"><semantics><mrow><mi>N</mi><mi>i</mi><msub><mi>O</mi><mrow><mo>(</mo><mi>F</mi><mo>)</mo></mrow></msub></mrow></semantics></math></inline-formula> comparing against ozonation using 100 mg/L <inline-formula><math display="inline"><semantics><mrow><mi>N</mi><mi>i</mi><mi>O</mi></mrow></semantics></math></inline-formula> powder in suspension (<inline-formula><math display="inline"><semantics><mrow><mi>N</mi><mi>i</mi><msub><mi>O</mi><mrow><mo>(</mo><mi>S</mi><mo>)</mo></mrow></msub></mrow></semantics></math></inline-formula>) and conventional ozonation (<inline-formula><math display="inline"><semantics><msub><mi>O</mi><mn>3</mn></msub></semantics></math></inline-formula>-conv). Total organic carbon analysis demonstrated a mineralization degree of 12% with <inline-formula><math display="inline"><semantics><msub><mi>O</mi><mn>3</mn></msub></semantics></math></inline-formula>-conv, 35% with <inline-formula><math display="inline"><semantics><mrow><mi>N</mi><mi>i</mi><mi>O</mi></mrow></semantics></math></inline-formula> as powder and 22% with <inline-formula><math display="inline"><semantics><mrow><mi>N</mi><mi>i</mi><msub><mi>O</mi><mrow><mo>(</mo><mi>F</mi><mo>)</mo></mrow></msub></mrow></semantics></math></inline-formula> after 60 min of reaction. The films of <inline-formula><math display="inline"><semantics><mrow><mi>N</mi><mi>i</mi><msub><mi>O</mi><mrow><mo>(</mo><mi>F</mi><mo>)</mo></mrow></msub></mrow></semantics></math></inline-formula> were sequentially used 4 times in ozonation demonstrating the stability of the synthesized material, as well as its properties as a catalyst for ozonation. A proposed modeling strategy using robust parametric identification techniques allows the comparison of NP decomposition pseudo-monomolecular reaction rates.https://www.mdpi.com/2073-4344/10/8/884naproxencatalytic ozonationnickel oxide filmsmineralizationreaction kinetics |
| spellingShingle | Claudia M. Aguilar-Melo Julia L. Rodríguez Isaac Chairez Iván Salgado J. A. Andraca Adame J. A. Galaviz-Pérez Jorge Vazquez-Arenas Tatyana Poznyak Enhanced Naproxen Elimination in Water by Catalytic Ozonation Based on NiO Films Catalysts naproxen catalytic ozonation nickel oxide films mineralization reaction kinetics |
| title | Enhanced Naproxen Elimination in Water by Catalytic Ozonation Based on NiO Films |
| title_full | Enhanced Naproxen Elimination in Water by Catalytic Ozonation Based on NiO Films |
| title_fullStr | Enhanced Naproxen Elimination in Water by Catalytic Ozonation Based on NiO Films |
| title_full_unstemmed | Enhanced Naproxen Elimination in Water by Catalytic Ozonation Based on NiO Films |
| title_short | Enhanced Naproxen Elimination in Water by Catalytic Ozonation Based on NiO Films |
| title_sort | enhanced naproxen elimination in water by catalytic ozonation based on nio films |
| topic | naproxen catalytic ozonation nickel oxide films mineralization reaction kinetics |
| url | https://www.mdpi.com/2073-4344/10/8/884 |
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