Review of physicochemical processes involved in agrochemical spray retention

This review provides a broad view of the processes and parameters involved in applying agrochemicals to the leaves of field crops. Treatment efficiency is assessed using macroscopic and microscopic approaches to investigate spray retention. With the macroscopic approach, aspects related to spray coa...

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Main Authors: Massinon, M., Lebeau, F.
Format: Article
Language:English
Published: Presses Agronomiques de Gembloux 2013-01-01
Series:Biotechnologie, Agronomie, Société et Environnement
Subjects:
Online Access:http://hdl.handle.net/11006/96
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author Massinon, M.
Lebeau, F.
author_facet Massinon, M.
Lebeau, F.
author_sort Massinon, M.
collection DOAJ
description This review provides a broad view of the processes and parameters involved in applying agrochemicals to the leaves of field crops. Treatment efficiency is assessed using macroscopic and microscopic approaches to investigate spray retention. With the macroscopic approach, aspects related to spray coarseness, carrier volume, leaf wettability, plant architecture, crop density and additives are addressed. Comparative studies have highlighted the wide variability in spray retention as a function of these parameters. They have failed, however, to describe the underlying physical relationships clearly enough to generalize the results. These relationships are better investigated using a microscopic approach, where drop impact behavior is established in relation to target surface and fluid properties. The wetting regime (either Wenzel or Cassie-Baxter) depends on the leaf surface microscopic roughness ratio (r) and chemical nature, fluid dynamic surface tension and drop impact energy. Adhesion, rebound and disintegration have been observed successively with increasing drop impact energy. Transitions between impact outcomes are influenced by fluid rheology and the dynamic surface tension of the fluid. The effect of surface orientation remains poorly explored, but it seems to have a limited influence on retention. Recent fundamental studies on superhydrophobicity and wetting should help practitioners in their search for an ever more rational application of agrochemicals. They could also drive the development of new systematic retention testing methods.
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spelling doaj.art-80a0812e81e444e9b98b8af18576ecb02022-12-21T18:46:07ZengPresses Agronomiques de GemblouxBiotechnologie, Agronomie, Société et Environnement1370-62331780-45072013-01-01173494504Review of physicochemical processes involved in agrochemical spray retentionMassinon, M.Lebeau, F.This review provides a broad view of the processes and parameters involved in applying agrochemicals to the leaves of field crops. Treatment efficiency is assessed using macroscopic and microscopic approaches to investigate spray retention. With the macroscopic approach, aspects related to spray coarseness, carrier volume, leaf wettability, plant architecture, crop density and additives are addressed. Comparative studies have highlighted the wide variability in spray retention as a function of these parameters. They have failed, however, to describe the underlying physical relationships clearly enough to generalize the results. These relationships are better investigated using a microscopic approach, where drop impact behavior is established in relation to target surface and fluid properties. The wetting regime (either Wenzel or Cassie-Baxter) depends on the leaf surface microscopic roughness ratio (r) and chemical nature, fluid dynamic surface tension and drop impact energy. Adhesion, rebound and disintegration have been observed successively with increasing drop impact energy. Transitions between impact outcomes are influenced by fluid rheology and the dynamic surface tension of the fluid. The effect of surface orientation remains poorly explored, but it seems to have a limited influence on retention. Recent fundamental studies on superhydrophobicity and wetting should help practitioners in their search for an ever more rational application of agrochemicals. They could also drive the development of new systematic retention testing methods.http://hdl.handle.net/11006/96Pesticidefoliagesurface tensionsprayingsurface active agent
spellingShingle Massinon, M.
Lebeau, F.
Review of physicochemical processes involved in agrochemical spray retention
Biotechnologie, Agronomie, Société et Environnement
Pesticide
foliage
surface tension
spraying
surface active agent
title Review of physicochemical processes involved in agrochemical spray retention
title_full Review of physicochemical processes involved in agrochemical spray retention
title_fullStr Review of physicochemical processes involved in agrochemical spray retention
title_full_unstemmed Review of physicochemical processes involved in agrochemical spray retention
title_short Review of physicochemical processes involved in agrochemical spray retention
title_sort review of physicochemical processes involved in agrochemical spray retention
topic Pesticide
foliage
surface tension
spraying
surface active agent
url http://hdl.handle.net/11006/96
work_keys_str_mv AT massinonm reviewofphysicochemicalprocessesinvolvedinagrochemicalsprayretention
AT lebeauf reviewofphysicochemicalprocessesinvolvedinagrochemicalsprayretention