A contribution to the chemical characterization of rivers in the Rio Negro Basin, Brazil

Water samples were collected in Middle Amazonia from the Amazon River, Rio Negro and 17 tributaries of Rio Negro. The analyses consisted of pH, conductivity, and dissolved organic (DOC) measurements, as well as plasma source mass spectrometry (ICP-MS). Factor analysis revealed three factors, which e...

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Main Authors: Küchler Ivo L., Miekeley Norbert, Forsberg Bruce R.
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2000-01-01
Series:Journal of the Brazilian Chemical Society
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300015
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author Küchler Ivo L.
Miekeley Norbert
Forsberg Bruce R.
author_facet Küchler Ivo L.
Miekeley Norbert
Forsberg Bruce R.
author_sort Küchler Ivo L.
collection DOAJ
description Water samples were collected in Middle Amazonia from the Amazon River, Rio Negro and 17 tributaries of Rio Negro. The analyses consisted of pH, conductivity, and dissolved organic (DOC) measurements, as well as plasma source mass spectrometry (ICP-MS). Factor analysis revealed three factors, which explained 94% of the total variance. A plot of factor scores presented a cluster containing mostly samples from the Rio Negro Basin. Ultrafiltration tests confirmed that organics from the Rio Negro have higher molecular mass than in the Amazon, and that some metals are associated with these compounds. Heavy rare-earth elements (REE) are enriched relative to light REE in the dissolved fraction of most rivers of the Negro Basin; the opposite occurred in suspended matter.
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spelling doaj.art-80ab68d0be44401a944c3c2d43dea2aa2022-12-21T18:41:59ZengSociedade Brasileira de QuímicaJournal of the Brazilian Chemical Society0103-50532000-01-01113286292A contribution to the chemical characterization of rivers in the Rio Negro Basin, BrazilKüchler Ivo L.Miekeley NorbertForsberg Bruce R.Water samples were collected in Middle Amazonia from the Amazon River, Rio Negro and 17 tributaries of Rio Negro. The analyses consisted of pH, conductivity, and dissolved organic (DOC) measurements, as well as plasma source mass spectrometry (ICP-MS). Factor analysis revealed three factors, which explained 94% of the total variance. A plot of factor scores presented a cluster containing mostly samples from the Rio Negro Basin. Ultrafiltration tests confirmed that organics from the Rio Negro have higher molecular mass than in the Amazon, and that some metals are associated with these compounds. Heavy rare-earth elements (REE) are enriched relative to light REE in the dissolved fraction of most rivers of the Negro Basin; the opposite occurred in suspended matter.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300015AmazoniaRio Negro (Brazil)blackwater riversmultivariate analysisrare-earth elements
spellingShingle Küchler Ivo L.
Miekeley Norbert
Forsberg Bruce R.
A contribution to the chemical characterization of rivers in the Rio Negro Basin, Brazil
Journal of the Brazilian Chemical Society
Amazonia
Rio Negro (Brazil)
blackwater rivers
multivariate analysis
rare-earth elements
title A contribution to the chemical characterization of rivers in the Rio Negro Basin, Brazil
title_full A contribution to the chemical characterization of rivers in the Rio Negro Basin, Brazil
title_fullStr A contribution to the chemical characterization of rivers in the Rio Negro Basin, Brazil
title_full_unstemmed A contribution to the chemical characterization of rivers in the Rio Negro Basin, Brazil
title_short A contribution to the chemical characterization of rivers in the Rio Negro Basin, Brazil
title_sort contribution to the chemical characterization of rivers in the rio negro basin brazil
topic Amazonia
Rio Negro (Brazil)
blackwater rivers
multivariate analysis
rare-earth elements
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300015
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