Optimization of Low Salinity Water/Surfactant Flooding Design for Oil-Wet Carbonate Reservoirs by Introducing a Negative Salinity Gradient

Engineered water surfactant flooding (EWSF) is a novel EOR technique to reduce residual oil saturation; however, it becomes quite challenging to obtain Winsor Type III microemulsion and the lowest IFT under actual reservoir conditions if only low salinity water is used. The main objective of this st...

Full description

Bibliographic Details
Main Authors: Mariam Shakeel, Aida Samanova, Peyman Pourafshary, Muhammad Rehan Hashmet
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/15/24/9400
_version_ 1797459677384015872
author Mariam Shakeel
Aida Samanova
Peyman Pourafshary
Muhammad Rehan Hashmet
author_facet Mariam Shakeel
Aida Samanova
Peyman Pourafshary
Muhammad Rehan Hashmet
author_sort Mariam Shakeel
collection DOAJ
description Engineered water surfactant flooding (EWSF) is a novel EOR technique to reduce residual oil saturation; however, it becomes quite challenging to obtain Winsor Type III microemulsion and the lowest IFT under actual reservoir conditions if only low salinity water is used. The main objective of this study was to design a negative salinity gradient to optimize the performance of the hybrid method. Three corefloods were performed on carbonate outcrop samples. The injection sequence in the first test was conventional waterflooding followed by optimum engineered water injection (2900 ppm) and finally an EWSF stage. The second and third tests were conducted using a varying negative salinity gradient. Engineered water for this study was designed by 10 times dilution of Caspian Sea water and spiking with key active ions. A higher salinity gradient was used for the first negative salinity gradient test. A total of 4300 ppm brine with 1 wt% surfactant was injected as a pre-flush after waterflooding followed by a further reduced salinity brine (~1400 ppm). The second negative salinity gradient test consisted of three post-waterflooding injection stages with salinities of 4600, 3700, and 290 ppm, respectively. Up to 8% and 16% more incremental oil recovery after waterflooding was obtained in the second and third tests, respectively, as compared to the first test. The descending order of brine salinity helped to create an optimum salinity environment for the surfactant despite surfactant adsorption. This study provided an optimum design for a successful LSSF test by adjusting the brine salinity and creating a negative salinity gradient during surfactant flooding. A higher reduction in residual oil saturation can be achieved by carefully designing an LSSF test, improving project economics.
first_indexed 2024-03-09T16:55:51Z
format Article
id doaj.art-80ae0ac52d3e452499fdb9d63190f2eb
institution Directory Open Access Journal
issn 1996-1073
language English
last_indexed 2024-03-09T16:55:51Z
publishDate 2022-12-01
publisher MDPI AG
record_format Article
series Energies
spelling doaj.art-80ae0ac52d3e452499fdb9d63190f2eb2023-11-24T14:36:09ZengMDPI AGEnergies1996-10732022-12-011524940010.3390/en15249400Optimization of Low Salinity Water/Surfactant Flooding Design for Oil-Wet Carbonate Reservoirs by Introducing a Negative Salinity GradientMariam Shakeel0Aida Samanova1Peyman Pourafshary2Muhammad Rehan Hashmet3School of Mining and Geosciences, Nazarbayev University, Astana 010000, KazakhstanSchool of Mining and Geosciences, Nazarbayev University, Astana 010000, KazakhstanSchool of Mining and Geosciences, Nazarbayev University, Astana 010000, KazakhstanDepartment of Chemical & Petroleum Engineering, United Arab Emirates University, Al Ain 15551, United Arab EmiratesEngineered water surfactant flooding (EWSF) is a novel EOR technique to reduce residual oil saturation; however, it becomes quite challenging to obtain Winsor Type III microemulsion and the lowest IFT under actual reservoir conditions if only low salinity water is used. The main objective of this study was to design a negative salinity gradient to optimize the performance of the hybrid method. Three corefloods were performed on carbonate outcrop samples. The injection sequence in the first test was conventional waterflooding followed by optimum engineered water injection (2900 ppm) and finally an EWSF stage. The second and third tests were conducted using a varying negative salinity gradient. Engineered water for this study was designed by 10 times dilution of Caspian Sea water and spiking with key active ions. A higher salinity gradient was used for the first negative salinity gradient test. A total of 4300 ppm brine with 1 wt% surfactant was injected as a pre-flush after waterflooding followed by a further reduced salinity brine (~1400 ppm). The second negative salinity gradient test consisted of three post-waterflooding injection stages with salinities of 4600, 3700, and 290 ppm, respectively. Up to 8% and 16% more incremental oil recovery after waterflooding was obtained in the second and third tests, respectively, as compared to the first test. The descending order of brine salinity helped to create an optimum salinity environment for the surfactant despite surfactant adsorption. This study provided an optimum design for a successful LSSF test by adjusting the brine salinity and creating a negative salinity gradient during surfactant flooding. A higher reduction in residual oil saturation can be achieved by carefully designing an LSSF test, improving project economics.https://www.mdpi.com/1996-1073/15/24/9400surfactant floodinglow salinity waternegative salinity gradientWinsor phase behaviormicroemulsioninterfacial tension
spellingShingle Mariam Shakeel
Aida Samanova
Peyman Pourafshary
Muhammad Rehan Hashmet
Optimization of Low Salinity Water/Surfactant Flooding Design for Oil-Wet Carbonate Reservoirs by Introducing a Negative Salinity Gradient
Energies
surfactant flooding
low salinity water
negative salinity gradient
Winsor phase behavior
microemulsion
interfacial tension
title Optimization of Low Salinity Water/Surfactant Flooding Design for Oil-Wet Carbonate Reservoirs by Introducing a Negative Salinity Gradient
title_full Optimization of Low Salinity Water/Surfactant Flooding Design for Oil-Wet Carbonate Reservoirs by Introducing a Negative Salinity Gradient
title_fullStr Optimization of Low Salinity Water/Surfactant Flooding Design for Oil-Wet Carbonate Reservoirs by Introducing a Negative Salinity Gradient
title_full_unstemmed Optimization of Low Salinity Water/Surfactant Flooding Design for Oil-Wet Carbonate Reservoirs by Introducing a Negative Salinity Gradient
title_short Optimization of Low Salinity Water/Surfactant Flooding Design for Oil-Wet Carbonate Reservoirs by Introducing a Negative Salinity Gradient
title_sort optimization of low salinity water surfactant flooding design for oil wet carbonate reservoirs by introducing a negative salinity gradient
topic surfactant flooding
low salinity water
negative salinity gradient
Winsor phase behavior
microemulsion
interfacial tension
url https://www.mdpi.com/1996-1073/15/24/9400
work_keys_str_mv AT mariamshakeel optimizationoflowsalinitywatersurfactantfloodingdesignforoilwetcarbonatereservoirsbyintroducinganegativesalinitygradient
AT aidasamanova optimizationoflowsalinitywatersurfactantfloodingdesignforoilwetcarbonatereservoirsbyintroducinganegativesalinitygradient
AT peymanpourafshary optimizationoflowsalinitywatersurfactantfloodingdesignforoilwetcarbonatereservoirsbyintroducinganegativesalinitygradient
AT muhammadrehanhashmet optimizationoflowsalinitywatersurfactantfloodingdesignforoilwetcarbonatereservoirsbyintroducinganegativesalinitygradient