Palladium-Based Contacts on p-GaN and Their Application in Laser Diodes

In this paper, we investigate the effect of Pd thickness and heat treatment on Pd/Ni/Au/p-GaN metal contacts. The as-deposited samples exhibit a smooth morphology and non-linear I–V characteristics. Heat treatment in a N<sub>2</sub> atmosphere leads to degradation of the contact microstr...

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Bibliographic Details
Main Authors: Iryna Levchenko, Serhii Kryvyi, Eliana Kamińska, Szymon Grzanka, Ewa Grzanka, Łucja Marona, Piotr Perlin
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/19/6568
Description
Summary:In this paper, we investigate the effect of Pd thickness and heat treatment on Pd/Ni/Au/p-GaN metal contacts. The as-deposited samples exhibit a smooth morphology and non-linear I–V characteristics. Heat treatment in a N<sub>2</sub> atmosphere leads to degradation of the contact microstructure, resulting in diffusion of Ga, void formation on the interface and mixing of metals. Annealing in a mixture of N<sub>2</sub> and O<sub>2</sub> improves adhesion and reduces contact resistance. However, this process also induces GaN decomposition and species mixing. The mixing of metal–Ga and metal–metal remains unaffected by the method of thermal treatment but depends on gas composition for thin Pd contacts. To achieve low-resistance contacts (≈1 × 10<sup>−4</sup> Ω cm<sup>2</sup>), we found that increasing the Pd thickness and using N<sub>2</sub> + O<sub>2</sub> as the annealing environment are effective measures. Nevertheless, the degradation effect of the annealed contact microstructure in the form of the void generation becomes evident as the thickness of Pd increases. Laser diodes (LDs) with optimized palladium-based contacts operate at a voltage of 4.1 V and a current density of 3.3 kA/cm².
ISSN:1996-1944