Bis(2,4-dichlorophenoxyacetato-κ2O1,O1′)(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)cobalt(II)
In the title compound, [Co(C8H5Cl2O3)(C12H12N2)], the CoII atom, lying on a twofold rotation axis, is coordinated by four O atoms from two chelating 2,4-dichlorophenoxyacetate ligands and two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand, displaying a distorted octa...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811010579 |
| _version_ | 1818948252636020736 |
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| author | Li-Li Ji Jian-She Liu Wen-Dong Song |
| author_facet | Li-Li Ji Jian-She Liu Wen-Dong Song |
| author_sort | Li-Li Ji |
| collection | DOAJ |
| description | In the title compound, [Co(C8H5Cl2O3)(C12H12N2)], the CoII atom, lying on a twofold rotation axis, is coordinated by four O atoms from two chelating 2,4-dichlorophenoxyacetate ligands and two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand, displaying a distorted octahedral geometry. A three-dimensional supramolecular structure is formed through intermolecular C—H...O hydrogen bonds and π–π stacking interactions between the pyridine and benzene rings [centroid–centroid distance = 3.779 (2) Å]. |
| first_indexed | 2024-12-20T08:43:51Z |
| format | Article |
| id | doaj.art-810e94afc41749e4a84ae7525a8d4a5c |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T08:43:51Z |
| publishDate | 2011-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-810e94afc41749e4a84ae7525a8d4a5c2022-12-21T19:46:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-04-01674m493m49310.1107/S1600536811010579Bis(2,4-dichlorophenoxyacetato-κ2O1,O1′)(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)cobalt(II)Li-Li JiJian-She LiuWen-Dong SongIn the title compound, [Co(C8H5Cl2O3)(C12H12N2)], the CoII atom, lying on a twofold rotation axis, is coordinated by four O atoms from two chelating 2,4-dichlorophenoxyacetate ligands and two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand, displaying a distorted octahedral geometry. A three-dimensional supramolecular structure is formed through intermolecular C—H...O hydrogen bonds and π–π stacking interactions between the pyridine and benzene rings [centroid–centroid distance = 3.779 (2) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536811010579 |
| spellingShingle | Li-Li Ji Jian-She Liu Wen-Dong Song Bis(2,4-dichlorophenoxyacetato-κ2O1,O1′)(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)cobalt(II) Acta Crystallographica Section E |
| title | Bis(2,4-dichlorophenoxyacetato-κ2O1,O1′)(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)cobalt(II) |
| title_full | Bis(2,4-dichlorophenoxyacetato-κ2O1,O1′)(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)cobalt(II) |
| title_fullStr | Bis(2,4-dichlorophenoxyacetato-κ2O1,O1′)(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)cobalt(II) |
| title_full_unstemmed | Bis(2,4-dichlorophenoxyacetato-κ2O1,O1′)(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)cobalt(II) |
| title_short | Bis(2,4-dichlorophenoxyacetato-κ2O1,O1′)(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)cobalt(II) |
| title_sort | bis 2 4 dichlorophenoxyacetato amp 954 2o1 o1 amp 8242 5 5 amp 8242 dimethyl 2 2 amp 8242 bipyridine amp 954 2n n amp 8242 cobalt ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811010579 |
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