Construction of Nitrogen Content Observer for Fuel Cell Hydrogen Circuit Based on Anode Recirculation Mode

The anode recirculation mode is increasingly being adopted in today’s fuel cell systems. The recycling of hydrogen gas can effectively improve fuel utilization and the wider economy. However, using the purge strategy for the recirculation exhaust has a significant impact on the operational performan...

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Main Authors: Weisong Li, Xuezhe Wei, Jiayuan Wang, Xueyuan Wang
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:World Electric Vehicle Journal
Subjects:
Online Access:https://www.mdpi.com/2032-6653/14/5/131
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author Weisong Li
Xuezhe Wei
Jiayuan Wang
Xueyuan Wang
author_facet Weisong Li
Xuezhe Wei
Jiayuan Wang
Xueyuan Wang
author_sort Weisong Li
collection DOAJ
description The anode recirculation mode is increasingly being adopted in today’s fuel cell systems. The recycling of hydrogen gas can effectively improve fuel utilization and the wider economy. However, using the purge strategy for the recirculation exhaust has a significant impact on the operational performance and economic efficiency of fuel cell systems.Experiments have shown that, when the purge interval increases from 6 s to 10 s, the recirculation pump power increases by about 20%, the nitrogen content in the exhaust gas increases, and the stack voltage shows a 10 V attenuation. The accumulation of nitrogen permeation in the anode circuit leads to the degradation of the fuel cell performance. Therefore, it is necessary to discharge the accumulated nitrogen through the purge valve in a timely manner. However, opening the exhaust valve with excessively high frequency can result in the unreacted hydrogen being discharged, which reduces the economic efficiency of the fuel cell. This paper is based on the principle of mass conservation and models each subsystem of the anode circuit in the recirculation pump mode of the fuel cell separately, including the proportional valve model, the hydrogen consumption model of the fuel cell, the nitrogen permeation model of the fuel cell, the neural network model of the circulating pump, and the purge valve model. These submodels are integrated to construct a nitrogen content observer for the hydrogen circuit, which can estimate the nitrogen content. The accuracy of the model is validated through experimental data. The estimation error is less than 5.5%. The nitrogen content in the anode circuit can be effectively estimated, providing a model reference for purge operations and improving hydrogen utilization.
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spelling doaj.art-81166226b8864aefb87ad82b7562868d2023-11-18T03:43:18ZengMDPI AGWorld Electric Vehicle Journal2032-66532023-05-0114513110.3390/wevj14050131Construction of Nitrogen Content Observer for Fuel Cell Hydrogen Circuit Based on Anode Recirculation ModeWeisong Li0Xuezhe Wei1Jiayuan Wang2Xueyuan Wang3School of Automotive Studies, Tongji University, Shanghai 201804, ChinaSchool of Automotive Studies, Tongji University, Shanghai 201804, ChinaShanghai Refire Energy and Technology Co., Ltd., Shanghai 201800, ChinaSchool of Automotive Studies, Tongji University, Shanghai 201804, ChinaThe anode recirculation mode is increasingly being adopted in today’s fuel cell systems. The recycling of hydrogen gas can effectively improve fuel utilization and the wider economy. However, using the purge strategy for the recirculation exhaust has a significant impact on the operational performance and economic efficiency of fuel cell systems.Experiments have shown that, when the purge interval increases from 6 s to 10 s, the recirculation pump power increases by about 20%, the nitrogen content in the exhaust gas increases, and the stack voltage shows a 10 V attenuation. The accumulation of nitrogen permeation in the anode circuit leads to the degradation of the fuel cell performance. Therefore, it is necessary to discharge the accumulated nitrogen through the purge valve in a timely manner. However, opening the exhaust valve with excessively high frequency can result in the unreacted hydrogen being discharged, which reduces the economic efficiency of the fuel cell. This paper is based on the principle of mass conservation and models each subsystem of the anode circuit in the recirculation pump mode of the fuel cell separately, including the proportional valve model, the hydrogen consumption model of the fuel cell, the nitrogen permeation model of the fuel cell, the neural network model of the circulating pump, and the purge valve model. These submodels are integrated to construct a nitrogen content observer for the hydrogen circuit, which can estimate the nitrogen content. The accuracy of the model is validated through experimental data. The estimation error is less than 5.5%. The nitrogen content in the anode circuit can be effectively estimated, providing a model reference for purge operations and improving hydrogen utilization.https://www.mdpi.com/2032-6653/14/5/131mass conservationnitrogen permeationnitrogen content observeranode recirculation
spellingShingle Weisong Li
Xuezhe Wei
Jiayuan Wang
Xueyuan Wang
Construction of Nitrogen Content Observer for Fuel Cell Hydrogen Circuit Based on Anode Recirculation Mode
World Electric Vehicle Journal
mass conservation
nitrogen permeation
nitrogen content observer
anode recirculation
title Construction of Nitrogen Content Observer for Fuel Cell Hydrogen Circuit Based on Anode Recirculation Mode
title_full Construction of Nitrogen Content Observer for Fuel Cell Hydrogen Circuit Based on Anode Recirculation Mode
title_fullStr Construction of Nitrogen Content Observer for Fuel Cell Hydrogen Circuit Based on Anode Recirculation Mode
title_full_unstemmed Construction of Nitrogen Content Observer for Fuel Cell Hydrogen Circuit Based on Anode Recirculation Mode
title_short Construction of Nitrogen Content Observer for Fuel Cell Hydrogen Circuit Based on Anode Recirculation Mode
title_sort construction of nitrogen content observer for fuel cell hydrogen circuit based on anode recirculation mode
topic mass conservation
nitrogen permeation
nitrogen content observer
anode recirculation
url https://www.mdpi.com/2032-6653/14/5/131
work_keys_str_mv AT weisongli constructionofnitrogencontentobserverforfuelcellhydrogencircuitbasedonanoderecirculationmode
AT xuezhewei constructionofnitrogencontentobserverforfuelcellhydrogencircuitbasedonanoderecirculationmode
AT jiayuanwang constructionofnitrogencontentobserverforfuelcellhydrogencircuitbasedonanoderecirculationmode
AT xueyuanwang constructionofnitrogencontentobserverforfuelcellhydrogencircuitbasedonanoderecirculationmode