Preparation and ring-opening reactions of N-diphenylphosphinyl vinyl aziridines

Preparation and ring-opening reactions of N-diphenylphosphinyl vinyl aziridines

Predominantly (E)-N-diphenylphosphinyl vinyl aziridines are prepared by a reaction of N-diphenylphosphinyl imines with α-bromoallyllithium in the presence of freshly fused ZnCl2. These aziridines undergo a ring-opening reaction with a variety of carbon and heteronucleophiles, in good yield, and gene...

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Bibliographic Details
Main Authors: Ashley N. Jarvis, Andrew B. McLaren, Helen M. I. Osborn, Joseph Sweeney
Format: Article
Language:English
Published: Beilstein-Institut 2013-05-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
aziridines
catalytic
heterocycles
palladium
ring opening
Online Access:https://doi.org/10.3762/bjoc.9.98

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