Effect of Al<sub>2</sub>O<sub>3</sub> on Sintering Reaction of Calcium Ferrite

Calcium ferrite containing aluminum (CFA) has been widely used in blast furnace production because it is an important compound that affects the quality of sinter. The influence of Al<sub>2</sub>O<sub>3</sub> on CFA preparation process was studied by the raw material of CaO-Fe...

पूर्ण विवरण

ग्रंथसूची विवरण
मुख्य लेखकों: Zhenwei Jing, Xiaofei Xing, Hongyan Yan, Ju Meng, Xiwei Qi, Hui Li, Jinglong Liang
स्वरूप: लेख
भाषा:English
प्रकाशित: MDPI AG 2022-08-01
श्रृंखला:Crystals
विषय:
ऑनलाइन पहुंच:https://www.mdpi.com/2073-4352/12/8/1172
विवरण
सारांश:Calcium ferrite containing aluminum (CFA) has been widely used in blast furnace production because it is an important compound that affects the quality of sinter. The influence of Al<sub>2</sub>O<sub>3</sub> on CFA preparation process was studied by the raw material of CaO-Fe<sub>2</sub>O<sub>3</sub>-Al<sub>2</sub>O<sub>3</sub>. Diffraction of x-rays (XRD), scanning electron microscope (SEM) and electrochemical impedance spectroscopy (EIS) analysis were used to analyze the phase, micro morphology and the reducibility of the products. The results showed that CaO tended to combine more with Fe<sub>2</sub>O<sub>3</sub> to form calcium ferrite with the increase of Fe<sub>2</sub>O<sub>3</sub>, whereas CaO tended to combine more with Al<sub>2</sub>O<sub>3</sub> to form calcium aluminate with the content of Al<sub>2</sub>O<sub>3</sub> above 45%. The micro morphology of sintered samples had a stable sintering skeleton structure due to the existence of calcium ferrite. Calcium ferrite was distributed between different particles in flakes, whereas calcium aluminate was attached to the Al<sub>2</sub>O<sub>3</sub> particle surface. The large amount of calcium aluminate inhibited the emergence of calcium ferrite, and it had an adverse impact on the reducibility of sinter and the preparation of CFA.
आईएसएसएन:2073-4352