Some laws of a system with a constant amount of energy
In this paper, different relationships and functional dependences of a system with a constant energy U=const., have been analyzed. The combinatorial nature of this analysis enables the conclusion that a family of entropy curves i.e. σ (N, U), for U = const, have an envelope. The envelope theory is v...
Main Authors: | , , , , |
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Format: | Article |
Language: | English |
Published: |
International Institute for the Science of Sintering, Beograd
2008-01-01
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Series: | Science of Sintering |
Subjects: | |
Online Access: | http://www.doiserbia.nb.rs/img/doi/0350-820X/2008/0350-820X0802123B.pdf |
Summary: | In this paper, different relationships and functional dependences of a system with a constant energy U=const., have been analyzed. The combinatorial nature of this analysis enables the conclusion that a family of entropy curves i.e. σ (N, U), for U = const, have an envelope. The envelope theory is very important for consideration of long & short range order of statistic thermodynamic systems. Since, we analyzed a system for U=const, we could explain some non-continual properties of a material. Like an example of this statement, we observed the situation, which is caused by anomaly filling of electronic orbits during the transfer from d to f elements. |
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ISSN: | 0350-820X |