Comprehensive microstructural investigation during dissimilar transient liquid phase bonding cobalt-based superalloys by BNi-9 amorphous interlayer foil

Cobalt-based X-45 and FSX-414 superalloys with interlayer BNi-9 have been bonded by a transient liquid phase bonding process at a constant temperature of 1150 °C with the holding times of 1, 10, 60, 120, 180 and 240 min. Microstructural changes of base metals showed that the conditions of 1150 °C/24...

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Main Authors: Mojtaba Naalchian, Masoud Kasiri-Asgarani, Morteza Shamanian, Reza Bakhtiari, Hamid Reza Bakhsheshi-Rad
Format: Article
Language:English
Published: Elsevier 2021-07-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785421005093
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author Mojtaba Naalchian
Masoud Kasiri-Asgarani
Morteza Shamanian
Reza Bakhtiari
Hamid Reza Bakhsheshi-Rad
author_facet Mojtaba Naalchian
Masoud Kasiri-Asgarani
Morteza Shamanian
Reza Bakhtiari
Hamid Reza Bakhsheshi-Rad
author_sort Mojtaba Naalchian
collection DOAJ
description Cobalt-based X-45 and FSX-414 superalloys with interlayer BNi-9 have been bonded by a transient liquid phase bonding process at a constant temperature of 1150 °C with the holding times of 1, 10, 60, 120, 180 and 240 min. Microstructural changes of base metals showed that the conditions of 1150 °C/240 min can be used to joint base metals, in such a way that the primary carbides of M6C and M23C6 are significantly dissolved in the matrix, forming a supersaturated solid solution. Examination of the bonded specimens showed that during heating up to the bonding stage, Nickel-rich carbo-boride deposits are formed at the interface between the filler metal and the base alloys due to the solid-state diffusion of boron element. The next generation of carbo-borides is formed in the diffusion affected zone of the base metals, which are also Cobalt–Chromium–Tungsten–Molybdenum-rich carbo-borides. Bonding at 1150 °C/1 min resulted in lack of complete diffusion of boron element into the base metals; quasi-eutectic compounds γ, Ni3B and CrB were formed in the centerline of the bond and, increasing the holding time causes the interdiffusion of alloying elements of base metals and the interlayer and leads to the uniformity of the chemical composition along the joint. Bonding under standard solution heat treatment condition (1150 °C/240 min) completely removes the diffusion affected zone on the 45-X side.
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spelling doaj.art-8179c44515c141dc9f8d87d8892df14e2022-12-21T18:51:18ZengElsevierJournal of Materials Research and Technology2238-78542021-07-011321442160Comprehensive microstructural investigation during dissimilar transient liquid phase bonding cobalt-based superalloys by BNi-9 amorphous interlayer foilMojtaba Naalchian0Masoud Kasiri-Asgarani1Morteza Shamanian2Reza Bakhtiari3Hamid Reza Bakhsheshi-Rad4Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, IranAdvanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran; Corresponding author.Department of Materials Engineering, Isfahan University of Technology, Isfahan, 84156-83111, Iran; Corresponding author.Department of Materials Engineering, Faculty of Engineering, Razi University, Kermanshah, IranAdvanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, IranCobalt-based X-45 and FSX-414 superalloys with interlayer BNi-9 have been bonded by a transient liquid phase bonding process at a constant temperature of 1150 °C with the holding times of 1, 10, 60, 120, 180 and 240 min. Microstructural changes of base metals showed that the conditions of 1150 °C/240 min can be used to joint base metals, in such a way that the primary carbides of M6C and M23C6 are significantly dissolved in the matrix, forming a supersaturated solid solution. Examination of the bonded specimens showed that during heating up to the bonding stage, Nickel-rich carbo-boride deposits are formed at the interface between the filler metal and the base alloys due to the solid-state diffusion of boron element. The next generation of carbo-borides is formed in the diffusion affected zone of the base metals, which are also Cobalt–Chromium–Tungsten–Molybdenum-rich carbo-borides. Bonding at 1150 °C/1 min resulted in lack of complete diffusion of boron element into the base metals; quasi-eutectic compounds γ, Ni3B and CrB were formed in the centerline of the bond and, increasing the holding time causes the interdiffusion of alloying elements of base metals and the interlayer and leads to the uniformity of the chemical composition along the joint. Bonding under standard solution heat treatment condition (1150 °C/240 min) completely removes the diffusion affected zone on the 45-X side.http://www.sciencedirect.com/science/article/pii/S2238785421005093TLPMicrostructureCobalt-based superalloysBNi-9
spellingShingle Mojtaba Naalchian
Masoud Kasiri-Asgarani
Morteza Shamanian
Reza Bakhtiari
Hamid Reza Bakhsheshi-Rad
Comprehensive microstructural investigation during dissimilar transient liquid phase bonding cobalt-based superalloys by BNi-9 amorphous interlayer foil
Journal of Materials Research and Technology
TLP
Microstructure
Cobalt-based superalloys
BNi-9
title Comprehensive microstructural investigation during dissimilar transient liquid phase bonding cobalt-based superalloys by BNi-9 amorphous interlayer foil
title_full Comprehensive microstructural investigation during dissimilar transient liquid phase bonding cobalt-based superalloys by BNi-9 amorphous interlayer foil
title_fullStr Comprehensive microstructural investigation during dissimilar transient liquid phase bonding cobalt-based superalloys by BNi-9 amorphous interlayer foil
title_full_unstemmed Comprehensive microstructural investigation during dissimilar transient liquid phase bonding cobalt-based superalloys by BNi-9 amorphous interlayer foil
title_short Comprehensive microstructural investigation during dissimilar transient liquid phase bonding cobalt-based superalloys by BNi-9 amorphous interlayer foil
title_sort comprehensive microstructural investigation during dissimilar transient liquid phase bonding cobalt based superalloys by bni 9 amorphous interlayer foil
topic TLP
Microstructure
Cobalt-based superalloys
BNi-9
url http://www.sciencedirect.com/science/article/pii/S2238785421005093
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AT mortezashamanian comprehensivemicrostructuralinvestigationduringdissimilartransientliquidphasebondingcobaltbasedsuperalloysbybni9amorphousinterlayerfoil
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