(Carbonato-κ2O,O′)bis(5,5′-dimethyl-2,2′-bipyridyl-κ2N,N′)cobalt(III) bromide trihydrate
In the title complex, [Co(CO3)(C12H12N2)2]Br·3H2O, the CoIII cation has a distorted octahedral coordination environment. It is chelated by four N atoms of two different 5,5′-dimethyl-2,2′-bipyridyl (dmbpy) ligands in axial and equatorial positions, and by two...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681200894X |
| _version_ | 1818959493087625216 |
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| author | Kannan Arun Kumar Parthsarathi Meera Madhavan Amutha Selvi Arunachalam Dayalan |
| author_facet | Kannan Arun Kumar Parthsarathi Meera Madhavan Amutha Selvi Arunachalam Dayalan |
| author_sort | Kannan Arun Kumar |
| collection | DOAJ |
| description | In the title complex, [Co(CO3)(C12H12N2)2]Br·3H2O, the CoIII cation has a distorted octahedral coordination environment. It is chelated by four N atoms of two different 5,5′-dimethyl-2,2′-bipyridyl (dmbpy) ligands in axial and equatorial positions, and by two O atoms of a carbonate anion completing the equatorial positions. Although the water molecules are disordered and their H atoms were not located, there are typical O...O distances between 2.8 and 3.0 Å, indicating O—H...O hydrogen bonding. The crystal packing is consolidated by C—H...O and C—H...Br hydrogen bonds, as well as π–π stacking interactions between adjacent pyridine rings of the dmbpy ligands, with centroid–centroid distances of 3.694 (3) and 3.7053 (3) Å. |
| first_indexed | 2024-12-20T11:42:31Z |
| format | Article |
| id | doaj.art-819d8b5145e64e5f931e778be870dd49 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:42:31Z |
| publishDate | 2012-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-819d8b5145e64e5f931e778be870dd492022-12-21T19:41:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m383m38410.1107/S160053681200894X(Carbonato-κ2O,O′)bis(5,5′-dimethyl-2,2′-bipyridyl-κ2N,N′)cobalt(III) bromide trihydrateKannan Arun KumarParthsarathi MeeraMadhavan Amutha SelviArunachalam DayalanIn the title complex, [Co(CO3)(C12H12N2)2]Br·3H2O, the CoIII cation has a distorted octahedral coordination environment. It is chelated by four N atoms of two different 5,5′-dimethyl-2,2′-bipyridyl (dmbpy) ligands in axial and equatorial positions, and by two O atoms of a carbonate anion completing the equatorial positions. Although the water molecules are disordered and their H atoms were not located, there are typical O...O distances between 2.8 and 3.0 Å, indicating O—H...O hydrogen bonding. The crystal packing is consolidated by C—H...O and C—H...Br hydrogen bonds, as well as π–π stacking interactions between adjacent pyridine rings of the dmbpy ligands, with centroid–centroid distances of 3.694 (3) and 3.7053 (3) Å.http://scripts.iucr.org/cgi-bin/paper?S160053681200894X |
| spellingShingle | Kannan Arun Kumar Parthsarathi Meera Madhavan Amutha Selvi Arunachalam Dayalan (Carbonato-κ2O,O′)bis(5,5′-dimethyl-2,2′-bipyridyl-κ2N,N′)cobalt(III) bromide trihydrate Acta Crystallographica Section E |
| title | (Carbonato-κ2O,O′)bis(5,5′-dimethyl-2,2′-bipyridyl-κ2N,N′)cobalt(III) bromide trihydrate |
| title_full | (Carbonato-κ2O,O′)bis(5,5′-dimethyl-2,2′-bipyridyl-κ2N,N′)cobalt(III) bromide trihydrate |
| title_fullStr | (Carbonato-κ2O,O′)bis(5,5′-dimethyl-2,2′-bipyridyl-κ2N,N′)cobalt(III) bromide trihydrate |
| title_full_unstemmed | (Carbonato-κ2O,O′)bis(5,5′-dimethyl-2,2′-bipyridyl-κ2N,N′)cobalt(III) bromide trihydrate |
| title_short | (Carbonato-κ2O,O′)bis(5,5′-dimethyl-2,2′-bipyridyl-κ2N,N′)cobalt(III) bromide trihydrate |
| title_sort | carbonato amp 954 2o o amp 8242 bis 5 5 amp 8242 dimethyl 2 2 amp 8242 bipyridyl amp 954 2n n amp 8242 cobalt iii bromide trihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681200894X |
| work_keys_str_mv | AT kannanarunkumar carbonatoamp9542ooamp8242bis55amp8242dimethyl22amp8242bipyridylamp9542nnamp8242cobaltiiibromidetrihydrate AT parthsarathimeera carbonatoamp9542ooamp8242bis55amp8242dimethyl22amp8242bipyridylamp9542nnamp8242cobaltiiibromidetrihydrate AT madhavanamuthaselvi carbonatoamp9542ooamp8242bis55amp8242dimethyl22amp8242bipyridylamp9542nnamp8242cobaltiiibromidetrihydrate AT arunachalamdayalan carbonatoamp9542ooamp8242bis55amp8242dimethyl22amp8242bipyridylamp9542nnamp8242cobaltiiibromidetrihydrate |