Bis(2-phenyl-4,6-di-2-pyridyl-1,3,5-triazine-κ3N4,N5,N6)ruthenium(II) bis(hexafluoridophosphate)
The asymmetric unit of the title compound, [Ru(C19H13N5)2](PF6)2, consists of an RuII complex cation and two hexafluoridophosphate anions. The RuII atom is coordinated by three N atoms from the two outer pyridine and the central triazine rings of each of two tridentate ligands in a distorted octahed...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807066883 |
| _version_ | 1828883678280810496 |
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| author | Matthew I. J. Polson Garry S. Hanan |
| author_facet | Matthew I. J. Polson Garry S. Hanan |
| author_sort | Matthew I. J. Polson |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Ru(C19H13N5)2](PF6)2, consists of an RuII complex cation and two hexafluoridophosphate anions. The RuII atom is coordinated by three N atoms from the two outer pyridine and the central triazine rings of each of two tridentate ligands in a distorted octahedral environment. The ligands are approximately orthogonal to one another, with a dihedral angle of 88.34 (2)° between planes through the three six-membered rings of the two ligands. The pendant phenyl substituents are almost coplanar with the triazine rings to which they are bound, with dihedral angles of 5.41 (9) and 14.90 (10)°. This is reflected in the previously reported photophysical results with an increased lifetime of the triplet metal to ligand charge transfer (3MLCT) excited state [Fang, Taylor, Hanan, Loiseau, Passalacqua, Campagna, Nierengarten & Van Dorsselaer (2002). J. Am. Chem. Soc. 124, 7912–7913]. |
| first_indexed | 2024-12-13T10:52:56Z |
| format | Article |
| id | doaj.art-8213f32395554e7e8d3c9ddcdb9dad6f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:52:56Z |
| publishDate | 2008-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8213f32395554e7e8d3c9ddcdb9dad6f2022-12-21T23:49:45ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m254m25510.1107/S1600536807066883Bis(2-phenyl-4,6-di-2-pyridyl-1,3,5-triazine-κ3N4,N5,N6)ruthenium(II) bis(hexafluoridophosphate)Matthew I. J. PolsonGarry S. HananThe asymmetric unit of the title compound, [Ru(C19H13N5)2](PF6)2, consists of an RuII complex cation and two hexafluoridophosphate anions. The RuII atom is coordinated by three N atoms from the two outer pyridine and the central triazine rings of each of two tridentate ligands in a distorted octahedral environment. The ligands are approximately orthogonal to one another, with a dihedral angle of 88.34 (2)° between planes through the three six-membered rings of the two ligands. The pendant phenyl substituents are almost coplanar with the triazine rings to which they are bound, with dihedral angles of 5.41 (9) and 14.90 (10)°. This is reflected in the previously reported photophysical results with an increased lifetime of the triplet metal to ligand charge transfer (3MLCT) excited state [Fang, Taylor, Hanan, Loiseau, Passalacqua, Campagna, Nierengarten & Van Dorsselaer (2002). J. Am. Chem. Soc. 124, 7912–7913].http://scripts.iucr.org/cgi-bin/paper?S1600536807066883 |
| spellingShingle | Matthew I. J. Polson Garry S. Hanan Bis(2-phenyl-4,6-di-2-pyridyl-1,3,5-triazine-κ3N4,N5,N6)ruthenium(II) bis(hexafluoridophosphate) Acta Crystallographica Section E |
| title | Bis(2-phenyl-4,6-di-2-pyridyl-1,3,5-triazine-κ3N4,N5,N6)ruthenium(II) bis(hexafluoridophosphate) |
| title_full | Bis(2-phenyl-4,6-di-2-pyridyl-1,3,5-triazine-κ3N4,N5,N6)ruthenium(II) bis(hexafluoridophosphate) |
| title_fullStr | Bis(2-phenyl-4,6-di-2-pyridyl-1,3,5-triazine-κ3N4,N5,N6)ruthenium(II) bis(hexafluoridophosphate) |
| title_full_unstemmed | Bis(2-phenyl-4,6-di-2-pyridyl-1,3,5-triazine-κ3N4,N5,N6)ruthenium(II) bis(hexafluoridophosphate) |
| title_short | Bis(2-phenyl-4,6-di-2-pyridyl-1,3,5-triazine-κ3N4,N5,N6)ruthenium(II) bis(hexafluoridophosphate) |
| title_sort | bis 2 phenyl 4 6 di 2 pyridyl 1 3 5 triazine 954 3n4 n5 n6 ruthenium ii bis hexafluoridophosphate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536807066883 |
| work_keys_str_mv | AT matthewijpolson bis2phenyl46di2pyridyl135triazine9543n4n5n6rutheniumiibishexafluoridophosphate AT garryshanan bis2phenyl46di2pyridyl135triazine9543n4n5n6rutheniumiibishexafluoridophosphate |