Aqua{μ-1,4-bis[(1,4,7,10-tetraazacyclododecan-1-yl)methyl]benzene}(nitrato-κO)dicopper(II) tris(nitrate) trihydrate
In the title dinuclear CuII complex, [Cu2(NO3)(C24H46N8)(H2O)](NO3)3·3H2O, the two CuII molecules both have a square-pyramidal geometry, but the ligands in the axial positions are different: a water molecule and a nitrate ion. All nitrate ions, water molecules, and N—H groups are involved in an inte...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2023-06-01
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314623004625 |
| _version_ | 1797692266208296960 |
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| author | Yoshimi Ichimaru Koichi Kato Kirara Sugiura Sarina Ogawa Wanchun Jin Masaaki Kurihara Yoshihiro Yamaguchi Masanori Imai Hiromasa Kurosaki |
| author_facet | Yoshimi Ichimaru Koichi Kato Kirara Sugiura Sarina Ogawa Wanchun Jin Masaaki Kurihara Yoshihiro Yamaguchi Masanori Imai Hiromasa Kurosaki |
| author_sort | Yoshimi Ichimaru |
| collection | DOAJ |
| description | In the title dinuclear CuII complex, [Cu2(NO3)(C24H46N8)(H2O)](NO3)3·3H2O, the two CuII molecules both have a square-pyramidal geometry, but the ligands in the axial positions are different: a water molecule and a nitrate ion. All nitrate ions, water molecules, and N—H groups are involved in an intermolecular hydrogen-bond network. |
| first_indexed | 2024-03-12T02:26:06Z |
| format | Article |
| id | doaj.art-82617049051142299001ea2dfd085a92 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-03-12T02:26:06Z |
| publishDate | 2023-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-82617049051142299001ea2dfd085a922023-09-05T13:04:54ZengInternational Union of CrystallographyIUCrData2414-31462023-06-0186x23046210.1107/S2414314623004625zl4054Aqua{μ-1,4-bis[(1,4,7,10-tetraazacyclododecan-1-yl)methyl]benzene}(nitrato-κO)dicopper(II) tris(nitrate) trihydrateYoshimi Ichimaru0Koichi Kato1Kirara Sugiura2Sarina Ogawa3Wanchun Jin4Masaaki Kurihara5Yoshihiro Yamaguchi6Masanori Imai7Hiromasa Kurosaki8Faculty of Pharmaceutical Sciences, Shonan University of Medical Sciences, 16-48, Kamishinano, Totsuka-ku, Yokohama, Kanagawa 244-0806, JapanFaculty of Pharmaceutical Sciences, Shonan University of Medical Sciences, 16-48, Kamishinano, Totsuka-ku, Yokohama, Kanagawa 244-0806, JapanCollege of Pharmacy, Kinjo Gakuin University, 2-1723 Omori, Nagoya 463-8521, JapanCollege of Pharmacy, Kinjo Gakuin University, 2-1723 Omori, Nagoya 463-8521, JapanCollege of Pharmacy, Kinjo Gakuin University, 2-1723 Omori, Nagoya 463-8521, JapanFaculty of Pharmaceutical Sciences, Shonan University of Medical Sciences, 16-48, Kamishinano, Totsuka-ku, Yokohama, Kanagawa 244-0806, JapanEnvironmental Safety Center, Kumamoto University, 39-1 Kurokami 2-Chome, Chuo-ku, Kumamoto, 860-8555, JapanCollege of Pharmacy, Kinjo Gakuin University, 2-1723 Omori, Nagoya 463-8521, JapanCollege of Pharmacy, Kinjo Gakuin University, 2-1723 Omori, Nagoya 463-8521, JapanIn the title dinuclear CuII complex, [Cu2(NO3)(C24H46N8)(H2O)](NO3)3·3H2O, the two CuII molecules both have a square-pyramidal geometry, but the ligands in the axial positions are different: a water molecule and a nitrate ion. All nitrate ions, water molecules, and N—H groups are involved in an intermolecular hydrogen-bond network.http://scripts.iucr.org/cgi-bin/paper?S2414314623004625crystal structurecopper(ii) complexcyclenp-xylenedinuclear complex |
| spellingShingle | Yoshimi Ichimaru Koichi Kato Kirara Sugiura Sarina Ogawa Wanchun Jin Masaaki Kurihara Yoshihiro Yamaguchi Masanori Imai Hiromasa Kurosaki Aqua{μ-1,4-bis[(1,4,7,10-tetraazacyclododecan-1-yl)methyl]benzene}(nitrato-κO)dicopper(II) tris(nitrate) trihydrate IUCrData crystal structure copper(ii) complex cyclen p-xylene dinuclear complex |
| title | Aqua{μ-1,4-bis[(1,4,7,10-tetraazacyclododecan-1-yl)methyl]benzene}(nitrato-κO)dicopper(II) tris(nitrate) trihydrate |
| title_full | Aqua{μ-1,4-bis[(1,4,7,10-tetraazacyclododecan-1-yl)methyl]benzene}(nitrato-κO)dicopper(II) tris(nitrate) trihydrate |
| title_fullStr | Aqua{μ-1,4-bis[(1,4,7,10-tetraazacyclododecan-1-yl)methyl]benzene}(nitrato-κO)dicopper(II) tris(nitrate) trihydrate |
| title_full_unstemmed | Aqua{μ-1,4-bis[(1,4,7,10-tetraazacyclododecan-1-yl)methyl]benzene}(nitrato-κO)dicopper(II) tris(nitrate) trihydrate |
| title_short | Aqua{μ-1,4-bis[(1,4,7,10-tetraazacyclododecan-1-yl)methyl]benzene}(nitrato-κO)dicopper(II) tris(nitrate) trihydrate |
| title_sort | aqua μ 1 4 bis 1 4 7 10 tetraazacyclododecan 1 yl methyl benzene nitrato κo dicopper ii tris nitrate trihydrate |
| topic | crystal structure copper(ii) complex cyclen p-xylene dinuclear complex |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314623004625 |
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