Enhanced Mechanistic Understanding Through the Detection of Radical Intermediates in Organic Reactions

Enhanced Mechanistic Understanding Through the Detection of Radical Intermediates in Organic Reactions

Two applications of a radical trap based on a homolytic substitution reaction (SH2') are presented for the trapping of short-lived radical intermediates in organic reactions. The first example is a photochemical cyanomethylation catalyzed by a Ru complex. Two intermediate radicals in the radica...

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Bibliographic Details
Main Authors: Ivan Ocaña, Peter J. H. Williams, James Donald, Neil Griffin, George Hodges, Andrew R. Rickard, Victor Chechik
Format: Article
Language:deu
Published: Swiss Chemical Society 2024-03-01
Series:CHIMIA
Subjects:
Mass spectrometry
Mechanistic studies
Radical reactions
Radical trapping
Online Access:https://www.chimia.ch/chimia/article/view/7145

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