Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ2N3,O4)iron(II)
In the title compound, [Fe(C5H3N2O4)2(H2O)2], the FeII ion lies on an inversion centre and is coordinated by two N and two O atoms from two 5-carboxy-1H-imidazole-4-carboxylate ligands and two water molecules in a distorted octahedral geometry. An intramolecular O—H...O hydrogen bond o...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811024779 |
| _version_ | 1798019294752145408 |
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| author | Chao-Jun Du Xing-Hua Song Li-Sheng Wang Chao-Ling Du |
| author_facet | Chao-Jun Du Xing-Hua Song Li-Sheng Wang Chao-Ling Du |
| author_sort | Chao-Jun Du |
| collection | DOAJ |
| description | In the title compound, [Fe(C5H3N2O4)2(H2O)2], the FeII ion lies on an inversion centre and is coordinated by two N and two O atoms from two 5-carboxy-1H-imidazole-4-carboxylate ligands and two water molecules in a distorted octahedral geometry. An intramolecular O—H...O hydrogen bond occurs. In the crystal, intermolecular N—H...O and O—H...O hydrogen bonds form a three-dimensional network, which consolidates the packing. |
| first_indexed | 2024-04-11T16:37:00Z |
| format | Article |
| id | doaj.art-828adeaf00f849578a48a68ae7bcecb4 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:37:00Z |
| publishDate | 2011-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-828adeaf00f849578a48a68ae7bcecb42022-12-22T04:13:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m997m99710.1107/S1600536811024779Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ2N3,O4)iron(II)Chao-Jun DuXing-Hua SongLi-Sheng WangChao-Ling DuIn the title compound, [Fe(C5H3N2O4)2(H2O)2], the FeII ion lies on an inversion centre and is coordinated by two N and two O atoms from two 5-carboxy-1H-imidazole-4-carboxylate ligands and two water molecules in a distorted octahedral geometry. An intramolecular O—H...O hydrogen bond occurs. In the crystal, intermolecular N—H...O and O—H...O hydrogen bonds form a three-dimensional network, which consolidates the packing.http://scripts.iucr.org/cgi-bin/paper?S1600536811024779 |
| spellingShingle | Chao-Jun Du Xing-Hua Song Li-Sheng Wang Chao-Ling Du Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ2N3,O4)iron(II) Acta Crystallographica Section E |
| title | Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ2N3,O4)iron(II) |
| title_full | Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ2N3,O4)iron(II) |
| title_fullStr | Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ2N3,O4)iron(II) |
| title_full_unstemmed | Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ2N3,O4)iron(II) |
| title_short | Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ2N3,O4)iron(II) |
| title_sort | diaquabis 5 carboxy 1h imidazole 4 carboxylato amp 954 2n3 o4 iron ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811024779 |
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