Effect of Microstructure of Surface Layer in Steel Vessel Used for Sponge Titanium Manufacturing on Fe Elution

To make clear factors affecting Fe elution into molten Mg during sponge titanium production process and reasons why Fe elution from the steel vessel in the first use is high while it considerably reduces in the second use in the actual mill, immersion experiments into molten Mg at 950ºC were conduct...

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Main Authors: Watanabe Meiji, Taki Kazuhiro, Yamaguchi Masanori, Inoue Yosuke
Format: Article
Language:English
Published: EDP Sciences 2020-01-01
Series:MATEC Web of Conferences
Online Access:https://www.matec-conferences.org/articles/matecconf/pdf/2020/17/matecconf_ti2019_07005.pdf
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author Watanabe Meiji
Taki Kazuhiro
Yamaguchi Masanori
Inoue Yosuke
author_facet Watanabe Meiji
Taki Kazuhiro
Yamaguchi Masanori
Inoue Yosuke
author_sort Watanabe Meiji
collection DOAJ
description To make clear factors affecting Fe elution into molten Mg during sponge titanium production process and reasons why Fe elution from the steel vessel in the first use is high while it considerably reduces in the second use in the actual mill, immersion experiments into molten Mg at 950ºC were conducted using specially designed specimens simulating the first and the second uses of the vessel, and microstructure change of the steel during the use was investigated in detail. TiFe, TiFe2 and Ti-diffused steel layers formed on the surface of the steel specimen after the treatment similar to the first use of the vessel. The outermost portion of Ti-diffused steel contained 3mass% Ti, which should have transferred to the α phase at this temperature. Fe elution from TiFe and TiFe2 was almost zero, while Fe elution from Fe-3mass%Ti was 1/4 of that from the unused steel. By taking the information on the phases appeared on the surface of the actual vessel into account, Fe elution from the vessel at the second use was estimated as 1/16 of that at the first use, which is well consistent with the value in the actual production mill.
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spelling doaj.art-828cd924fb3642adaf4a2309ce23f7602022-12-21T18:32:20ZengEDP SciencesMATEC Web of Conferences2261-236X2020-01-013210700510.1051/matecconf/202032107005matecconf_ti2019_07005Effect of Microstructure of Surface Layer in Steel Vessel Used for Sponge Titanium Manufacturing on Fe ElutionWatanabe MeijiTaki KazuhiroYamaguchi MasanoriInoue YosukeTo make clear factors affecting Fe elution into molten Mg during sponge titanium production process and reasons why Fe elution from the steel vessel in the first use is high while it considerably reduces in the second use in the actual mill, immersion experiments into molten Mg at 950ºC were conducted using specially designed specimens simulating the first and the second uses of the vessel, and microstructure change of the steel during the use was investigated in detail. TiFe, TiFe2 and Ti-diffused steel layers formed on the surface of the steel specimen after the treatment similar to the first use of the vessel. The outermost portion of Ti-diffused steel contained 3mass% Ti, which should have transferred to the α phase at this temperature. Fe elution from TiFe and TiFe2 was almost zero, while Fe elution from Fe-3mass%Ti was 1/4 of that from the unused steel. By taking the information on the phases appeared on the surface of the actual vessel into account, Fe elution from the vessel at the second use was estimated as 1/16 of that at the first use, which is well consistent with the value in the actual production mill.https://www.matec-conferences.org/articles/matecconf/pdf/2020/17/matecconf_ti2019_07005.pdf
spellingShingle Watanabe Meiji
Taki Kazuhiro
Yamaguchi Masanori
Inoue Yosuke
Effect of Microstructure of Surface Layer in Steel Vessel Used for Sponge Titanium Manufacturing on Fe Elution
MATEC Web of Conferences
title Effect of Microstructure of Surface Layer in Steel Vessel Used for Sponge Titanium Manufacturing on Fe Elution
title_full Effect of Microstructure of Surface Layer in Steel Vessel Used for Sponge Titanium Manufacturing on Fe Elution
title_fullStr Effect of Microstructure of Surface Layer in Steel Vessel Used for Sponge Titanium Manufacturing on Fe Elution
title_full_unstemmed Effect of Microstructure of Surface Layer in Steel Vessel Used for Sponge Titanium Manufacturing on Fe Elution
title_short Effect of Microstructure of Surface Layer in Steel Vessel Used for Sponge Titanium Manufacturing on Fe Elution
title_sort effect of microstructure of surface layer in steel vessel used for sponge titanium manufacturing on fe elution
url https://www.matec-conferences.org/articles/matecconf/pdf/2020/17/matecconf_ti2019_07005.pdf
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AT yamaguchimasanori effectofmicrostructureofsurfacelayerinsteelvesselusedforspongetitaniummanufacturingonfeelution
AT inoueyosuke effectofmicrostructureofsurfacelayerinsteelvesselusedforspongetitaniummanufacturingonfeelution