Insights into the Mechanism, Regio-/Diastereoselectivities and Ligand Role of Nickel-Initiated [3+2] Cycloadditions between Vinylcyclopropane and <i>N</i>-Tosylbenzaldimine

Insights into the Mechanism, Regio-/Diastereoselectivities and Ligand Role of Nickel-Initiated [3+2] Cycloadditions between Vinylcyclopropane and <i>N</i>-Tosylbenzaldimine

Density functional theory (DFT) was employed to explore the reaction mechanism, regio- and diastereoselectivities of nickel-initiated [3+2] cycloaddition between vinylcyclopropane (VCP) and <i>N</i>-tosylbenzaldimine assisted by phosphine ligands. Four different binding modes of the nick...

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Bibliographic Details
Main Authors: Weihua Mu, Lin Zhu, Shuya Xia, Xue Tan, Liangfei Duan, Guanghao Meng, Guo Liu
Format: Article
Language:English
Published: MDPI AG 2024-01-01
Series:Catalysts
Subjects:
nickel
catalysis
vinylcyclopropane (VCP)
[3+2] cycloaddition
mechanism
DFT
Online Access:https://www.mdpi.com/2073-4344/14/1/82

Internet

https://www.mdpi.com/2073-4344/14/1/82

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