Temperature-induced oligomerization of polycyclic aromatic hydrocarbons at ambient and high pressures
Abstract Temperature-induced oligomerization of polycyclic aromatic hydrocarbons (PAHs) was found at 500–773 K and ambient and high (3.5 GPa) pressures. The most intensive oligomerization at 1 bar and 3.5 GPa occurs at 740–823 K. PAH carbonization at high pressure is the final stage of oligomerizati...
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| Format: | Article |
| Language: | English |
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Nature Portfolio
2017-08-01
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| Series: | Scientific Reports |
| Online Access: | https://doi.org/10.1038/s41598-017-08529-2 |
| _version_ | 1818844078627880960 |
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| author | Artem D. Chanyshev Konstantin D. Litasov Yoshihiro Furukawa Konstantin A. Kokh Anton F. Shatskiy |
| author_facet | Artem D. Chanyshev Konstantin D. Litasov Yoshihiro Furukawa Konstantin A. Kokh Anton F. Shatskiy |
| author_sort | Artem D. Chanyshev |
| collection | DOAJ |
| description | Abstract Temperature-induced oligomerization of polycyclic aromatic hydrocarbons (PAHs) was found at 500–773 K and ambient and high (3.5 GPa) pressures. The most intensive oligomerization at 1 bar and 3.5 GPa occurs at 740–823 K. PAH carbonization at high pressure is the final stage of oligomerization and occurs as a result of sequential oligomerization and polymerization of the starting material, caused by overlapping of π-orbitals, a decrease of intermolecular distances, and finally the dehydrogenation and polycondensation of benzene rings. Being important for building blocks of life, PAHs and their oligomers can be formed in the interior of the terrestrial planets with radii less than 2270 km. |
| first_indexed | 2024-12-19T05:08:03Z |
| format | Article |
| id | doaj.art-829d0c6f2f0e4066950ebd1948d078ec |
| institution | Directory Open Access Journal |
| issn | 2045-2322 |
| language | English |
| last_indexed | 2024-12-19T05:08:03Z |
| publishDate | 2017-08-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Scientific Reports |
| spelling | doaj.art-829d0c6f2f0e4066950ebd1948d078ec2022-12-21T20:34:53ZengNature PortfolioScientific Reports2045-23222017-08-01711810.1038/s41598-017-08529-2Temperature-induced oligomerization of polycyclic aromatic hydrocarbons at ambient and high pressuresArtem D. Chanyshev0Konstantin D. Litasov1Yoshihiro Furukawa2Konstantin A. Kokh3Anton F. Shatskiy4V.S. Sobolev Institute of Geology and Mineralogy SB RASV.S. Sobolev Institute of Geology and Mineralogy SB RASDepartment of Earth and Planetary Materials Science, Graduate School of Science, Tohoku UniversityV.S. Sobolev Institute of Geology and Mineralogy SB RASV.S. Sobolev Institute of Geology and Mineralogy SB RASAbstract Temperature-induced oligomerization of polycyclic aromatic hydrocarbons (PAHs) was found at 500–773 K and ambient and high (3.5 GPa) pressures. The most intensive oligomerization at 1 bar and 3.5 GPa occurs at 740–823 K. PAH carbonization at high pressure is the final stage of oligomerization and occurs as a result of sequential oligomerization and polymerization of the starting material, caused by overlapping of π-orbitals, a decrease of intermolecular distances, and finally the dehydrogenation and polycondensation of benzene rings. Being important for building blocks of life, PAHs and their oligomers can be formed in the interior of the terrestrial planets with radii less than 2270 km.https://doi.org/10.1038/s41598-017-08529-2 |
| spellingShingle | Artem D. Chanyshev Konstantin D. Litasov Yoshihiro Furukawa Konstantin A. Kokh Anton F. Shatskiy Temperature-induced oligomerization of polycyclic aromatic hydrocarbons at ambient and high pressures Scientific Reports |
| title | Temperature-induced oligomerization of polycyclic aromatic hydrocarbons at ambient and high pressures |
| title_full | Temperature-induced oligomerization of polycyclic aromatic hydrocarbons at ambient and high pressures |
| title_fullStr | Temperature-induced oligomerization of polycyclic aromatic hydrocarbons at ambient and high pressures |
| title_full_unstemmed | Temperature-induced oligomerization of polycyclic aromatic hydrocarbons at ambient and high pressures |
| title_short | Temperature-induced oligomerization of polycyclic aromatic hydrocarbons at ambient and high pressures |
| title_sort | temperature induced oligomerization of polycyclic aromatic hydrocarbons at ambient and high pressures |
| url | https://doi.org/10.1038/s41598-017-08529-2 |
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