Simultaneous Detection of CO<sub>2</sub> and CH<sub>4</sub> Using a DFB Diode Laser-Based Absorption Spectrometer

In this paper, an attractive gas sensing technique based on fiber optical sensing ideal was developed for the detection of multi-gas species simultaneously. Calibration-free laser absorption spectroscopy (LAS) was used and combined with a multi-pass optical absorption cell, two fiber-coupled near-in...

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Main Authors: Xu Wu, Yulong Du, Shijian Shi, Cong Jiang, Xueliang Deng, Song Zhu, Xiaolong Jin, Jingsong Li
Format: Article
Language:English
Published: MDPI AG 2022-09-01
Series:Chemosensors
Subjects:
Online Access:https://www.mdpi.com/2227-9040/10/10/390
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author Xu Wu
Yulong Du
Shijian Shi
Cong Jiang
Xueliang Deng
Song Zhu
Xiaolong Jin
Jingsong Li
author_facet Xu Wu
Yulong Du
Shijian Shi
Cong Jiang
Xueliang Deng
Song Zhu
Xiaolong Jin
Jingsong Li
author_sort Xu Wu
collection DOAJ
description In this paper, an attractive gas sensing technique based on fiber optical sensing ideal was developed for the detection of multi-gas species simultaneously. Calibration-free laser absorption spectroscopy (LAS) was used and combined with a multi-pass optical absorption cell, two fiber-coupled near-infrared (NIR) distributed feedback (DFB) diode lasers are used and coupled into a single optical path for measuring CO<sub>2</sub> and CH<sub>4</sub> absorption spectra simultaneously. The optimal sampling pressure, laser tuning characteristics, spectral sampling points, and potential optical interference are theoretically and experimentally investigated in detail. The results indicated that the proposed technique has good reliability and has been successfully demonstrated for ambient CO<sub>2</sub> and CH<sub>4</sub> detection by using a single sample cell and detector. An Allan–Werle deviation analysis shows that detection limits of 0.12 ppm for CH<sub>4</sub> and 35.97 ppm for CO<sub>2</sub> can be obtained with an integration time of 181 s and 166 s, respectively. The proposed technique can be expanded to measure more molecules simultaneously by combing laser array and may pave a new way for developing a low-cost and ultra-compact multi-gas laser spectroscopy sensing system.
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spelling doaj.art-82b348b0882642478e6b82a5086db09a2023-11-23T23:29:53ZengMDPI AGChemosensors2227-90402022-09-01101039010.3390/chemosensors10100390Simultaneous Detection of CO<sub>2</sub> and CH<sub>4</sub> Using a DFB Diode Laser-Based Absorption SpectrometerXu Wu0Yulong Du1Shijian Shi2Cong Jiang3Xueliang Deng4Song Zhu5Xiaolong Jin6Jingsong Li7Laser Spectroscopy and Sensing Laboratory, Anhui University, Hefei 230601, ChinaLaser Spectroscopy and Sensing Laboratory, Anhui University, Hefei 230601, ChinaLaser Spectroscopy and Sensing Laboratory, Anhui University, Hefei 230601, ChinaLaser Spectroscopy and Sensing Laboratory, Anhui University, Hefei 230601, ChinaHefei Meteorological Bureau, Hefei 230041, ChinaHefei Meteorological Bureau, Hefei 230041, ChinaHefei Meteorological Bureau, Hefei 230041, ChinaLaser Spectroscopy and Sensing Laboratory, Anhui University, Hefei 230601, ChinaIn this paper, an attractive gas sensing technique based on fiber optical sensing ideal was developed for the detection of multi-gas species simultaneously. Calibration-free laser absorption spectroscopy (LAS) was used and combined with a multi-pass optical absorption cell, two fiber-coupled near-infrared (NIR) distributed feedback (DFB) diode lasers are used and coupled into a single optical path for measuring CO<sub>2</sub> and CH<sub>4</sub> absorption spectra simultaneously. The optimal sampling pressure, laser tuning characteristics, spectral sampling points, and potential optical interference are theoretically and experimentally investigated in detail. The results indicated that the proposed technique has good reliability and has been successfully demonstrated for ambient CO<sub>2</sub> and CH<sub>4</sub> detection by using a single sample cell and detector. An Allan–Werle deviation analysis shows that detection limits of 0.12 ppm for CH<sub>4</sub> and 35.97 ppm for CO<sub>2</sub> can be obtained with an integration time of 181 s and 166 s, respectively. The proposed technique can be expanded to measure more molecules simultaneously by combing laser array and may pave a new way for developing a low-cost and ultra-compact multi-gas laser spectroscopy sensing system.https://www.mdpi.com/2227-9040/10/10/390laser absorption spectroscopycalibration-freemulti-gas detectionCO<sub>2</sub>CH<sub>4</sub>
spellingShingle Xu Wu
Yulong Du
Shijian Shi
Cong Jiang
Xueliang Deng
Song Zhu
Xiaolong Jin
Jingsong Li
Simultaneous Detection of CO<sub>2</sub> and CH<sub>4</sub> Using a DFB Diode Laser-Based Absorption Spectrometer
Chemosensors
laser absorption spectroscopy
calibration-free
multi-gas detection
CO<sub>2</sub>
CH<sub>4</sub>
title Simultaneous Detection of CO<sub>2</sub> and CH<sub>4</sub> Using a DFB Diode Laser-Based Absorption Spectrometer
title_full Simultaneous Detection of CO<sub>2</sub> and CH<sub>4</sub> Using a DFB Diode Laser-Based Absorption Spectrometer
title_fullStr Simultaneous Detection of CO<sub>2</sub> and CH<sub>4</sub> Using a DFB Diode Laser-Based Absorption Spectrometer
title_full_unstemmed Simultaneous Detection of CO<sub>2</sub> and CH<sub>4</sub> Using a DFB Diode Laser-Based Absorption Spectrometer
title_short Simultaneous Detection of CO<sub>2</sub> and CH<sub>4</sub> Using a DFB Diode Laser-Based Absorption Spectrometer
title_sort simultaneous detection of co sub 2 sub and ch sub 4 sub using a dfb diode laser based absorption spectrometer
topic laser absorption spectroscopy
calibration-free
multi-gas detection
CO<sub>2</sub>
CH<sub>4</sub>
url https://www.mdpi.com/2227-9040/10/10/390
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