A nanoscale observation to explain the discrepancy of electron exchange capacities between biochar containing comparable surface redox-active moieties
Highlights The microscopic distribution of RAMs on biochar was achieved by combining C-AFM and a mediated electrochemical method. The uneven distribution of RAMs enabled biochar to possess outstanding EEC by enhancing accessibility. The removal of submicron particles that only occupied 1-4‰wt reduce...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Springer
2022-07-01
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| Series: | Biochar |
| Subjects: | |
| Online Access: | https://doi.org/10.1007/s42773-022-00165-y |
| _version_ | 1818163080219066368 |
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| author | Shasha Li Liming Shao Hua Zhang Xuemin Lu Fan Lü Pinjing He |
| author_facet | Shasha Li Liming Shao Hua Zhang Xuemin Lu Fan Lü Pinjing He |
| author_sort | Shasha Li |
| collection | DOAJ |
| description | Highlights The microscopic distribution of RAMs on biochar was achieved by combining C-AFM and a mediated electrochemical method. The uneven distribution of RAMs enabled biochar to possess outstanding EEC by enhancing accessibility. The removal of submicron particles that only occupied 1-4‰wt reduced EDC to 72% for st700 and 53% for ind400. The removal of submicron particles changed the EAC of st700 to 87% and ind400 to 1.40 times as raw chars. Condensed aromatic structures were indispensable to EAC, while both heteroatoms and amorphous aromatics contributed to EDC. |
| first_indexed | 2024-12-11T16:43:52Z |
| format | Article |
| id | doaj.art-82b4a40584f540fe963f1c08418ac6e3 |
| institution | Directory Open Access Journal |
| issn | 2524-7972 2524-7867 |
| language | English |
| last_indexed | 2024-12-11T16:43:52Z |
| publishDate | 2022-07-01 |
| publisher | Springer |
| record_format | Article |
| series | Biochar |
| spelling | doaj.art-82b4a40584f540fe963f1c08418ac6e32022-12-22T00:58:16ZengSpringerBiochar2524-79722524-78672022-07-014111510.1007/s42773-022-00165-yA nanoscale observation to explain the discrepancy of electron exchange capacities between biochar containing comparable surface redox-active moietiesShasha Li0Liming Shao1Hua Zhang2Xuemin Lu3Fan Lü4Pinjing He5State Key Laboratory of Pollution Control and Resource Reuse, Tongji UniversityInstitute of Waste Treatment and Reclamation, Tongji UniversityState Key Laboratory of Pollution Control and Resource Reuse, Tongji UniversityState Key Laboratory of Pollution Control and Resource Reuse, Tongji UniversityState Key Laboratory of Pollution Control and Resource Reuse, Tongji UniversityInstitute of Waste Treatment and Reclamation, Tongji UniversityHighlights The microscopic distribution of RAMs on biochar was achieved by combining C-AFM and a mediated electrochemical method. The uneven distribution of RAMs enabled biochar to possess outstanding EEC by enhancing accessibility. The removal of submicron particles that only occupied 1-4‰wt reduced EDC to 72% for st700 and 53% for ind400. The removal of submicron particles changed the EAC of st700 to 87% and ind400 to 1.40 times as raw chars. Condensed aromatic structures were indispensable to EAC, while both heteroatoms and amorphous aromatics contributed to EDC.https://doi.org/10.1007/s42773-022-00165-yBiocharPyrogenic charsRedox propertyElectron exchange capacityC-AFM |
| spellingShingle | Shasha Li Liming Shao Hua Zhang Xuemin Lu Fan Lü Pinjing He A nanoscale observation to explain the discrepancy of electron exchange capacities between biochar containing comparable surface redox-active moieties Biochar Biochar Pyrogenic chars Redox property Electron exchange capacity C-AFM |
| title | A nanoscale observation to explain the discrepancy of electron exchange capacities between biochar containing comparable surface redox-active moieties |
| title_full | A nanoscale observation to explain the discrepancy of electron exchange capacities between biochar containing comparable surface redox-active moieties |
| title_fullStr | A nanoscale observation to explain the discrepancy of electron exchange capacities between biochar containing comparable surface redox-active moieties |
| title_full_unstemmed | A nanoscale observation to explain the discrepancy of electron exchange capacities between biochar containing comparable surface redox-active moieties |
| title_short | A nanoscale observation to explain the discrepancy of electron exchange capacities between biochar containing comparable surface redox-active moieties |
| title_sort | nanoscale observation to explain the discrepancy of electron exchange capacities between biochar containing comparable surface redox active moieties |
| topic | Biochar Pyrogenic chars Redox property Electron exchange capacity C-AFM |
| url | https://doi.org/10.1007/s42773-022-00165-y |
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