(7aS)-(–)-Dimethyl(1-oxido-3-oxo-5,6,7,7a-tetrahydro-3H-pyrrolizin-2-yl)sulfonium
In the zwitterionic title compound, C9H13NO2S, the pyrrolidine heterocycle adopts an envelope conformation (with the C atom in the 7-position as the flap). The negative charge is delocalized over the two carbonyl groups and the C atom connecting them. The positive charge is located on the S atom. Tw...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812003601 |
| _version_ | 1798024482147794944 |
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| author | Angel Mendoza Marcos Flores-Alamo Joel L. Terán Jorge R. Juárez Leonardo Gutiérrez-Lazcano |
| author_facet | Angel Mendoza Marcos Flores-Alamo Joel L. Terán Jorge R. Juárez Leonardo Gutiérrez-Lazcano |
| author_sort | Angel Mendoza |
| collection | DOAJ |
| description | In the zwitterionic title compound, C9H13NO2S, the pyrrolidine heterocycle adopts an envelope conformation (with the C atom in the 7-position as the flap). The negative charge is delocalized over the two carbonyl groups and the C atom connecting them. The positive charge is located on the S atom. Two intermolecular C—H...O interactions are observed. The molecular geometry at the S atom is trigonal pyramidal. |
| first_indexed | 2024-04-11T18:03:07Z |
| format | Article |
| id | doaj.art-82bee253d3384585b5955df2af42283b |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:03:07Z |
| publishDate | 2012-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-82bee253d3384585b5955df2af42283b2022-12-22T04:10:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683o752o75210.1107/S1600536812003601(7aS)-(–)-Dimethyl(1-oxido-3-oxo-5,6,7,7a-tetrahydro-3H-pyrrolizin-2-yl)sulfoniumAngel MendozaMarcos Flores-AlamoJoel L. TeránJorge R. JuárezLeonardo Gutiérrez-LazcanoIn the zwitterionic title compound, C9H13NO2S, the pyrrolidine heterocycle adopts an envelope conformation (with the C atom in the 7-position as the flap). The negative charge is delocalized over the two carbonyl groups and the C atom connecting them. The positive charge is located on the S atom. Two intermolecular C—H...O interactions are observed. The molecular geometry at the S atom is trigonal pyramidal.http://scripts.iucr.org/cgi-bin/paper?S1600536812003601 |
| spellingShingle | Angel Mendoza Marcos Flores-Alamo Joel L. Terán Jorge R. Juárez Leonardo Gutiérrez-Lazcano (7aS)-(–)-Dimethyl(1-oxido-3-oxo-5,6,7,7a-tetrahydro-3H-pyrrolizin-2-yl)sulfonium Acta Crystallographica Section E |
| title | (7aS)-(–)-Dimethyl(1-oxido-3-oxo-5,6,7,7a-tetrahydro-3H-pyrrolizin-2-yl)sulfonium |
| title_full | (7aS)-(–)-Dimethyl(1-oxido-3-oxo-5,6,7,7a-tetrahydro-3H-pyrrolizin-2-yl)sulfonium |
| title_fullStr | (7aS)-(–)-Dimethyl(1-oxido-3-oxo-5,6,7,7a-tetrahydro-3H-pyrrolizin-2-yl)sulfonium |
| title_full_unstemmed | (7aS)-(–)-Dimethyl(1-oxido-3-oxo-5,6,7,7a-tetrahydro-3H-pyrrolizin-2-yl)sulfonium |
| title_short | (7aS)-(–)-Dimethyl(1-oxido-3-oxo-5,6,7,7a-tetrahydro-3H-pyrrolizin-2-yl)sulfonium |
| title_sort | 7as amp 8211 dimethyl 1 oxido 3 oxo 5 6 7 7a tetrahydro 3h pyrrolizin 2 yl sulfonium |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812003601 |
| work_keys_str_mv | AT angelmendoza 7asamp8211dimethyl1oxido3oxo5677atetrahydro3hpyrrolizin2ylsulfonium AT marcosfloresalamo 7asamp8211dimethyl1oxido3oxo5677atetrahydro3hpyrrolizin2ylsulfonium AT joellteramp225n 7asamp8211dimethyl1oxido3oxo5677atetrahydro3hpyrrolizin2ylsulfonium AT jorgerjuamp225rez 7asamp8211dimethyl1oxido3oxo5677atetrahydro3hpyrrolizin2ylsulfonium AT leonardogutiamp233rrezlazcano 7asamp8211dimethyl1oxido3oxo5677atetrahydro3hpyrrolizin2ylsulfonium |