Coordination Networks Based on Boronate and Benzoxaborolate Ligands
Despite the extensive range of investigations on boronic acids (R-B(OH)2), some aspects of their reactivity still need to be explored. This is the case for the coordination chemistry of boronate anions (R-B(OH)3−), which has only recently been started to be studied. The purpose of this review is to...
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| Format: | Article |
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MDPI AG
2016-05-01
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| Series: | Crystals |
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| Online Access: | http://www.mdpi.com/2073-4352/6/5/48 |
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| author | Saad Sene Marie Alix Pizzoccaro Joris Vezzani Marc Reinholdt Philippe Gaveau Dorothée Berthomieu Sylvie Bégu Christel Gervais Christian Bonhomme Guillaume Renaudin Adel Mesbah Arie van der Lee Mark E. Smith Danielle Laurencin |
| author_facet | Saad Sene Marie Alix Pizzoccaro Joris Vezzani Marc Reinholdt Philippe Gaveau Dorothée Berthomieu Sylvie Bégu Christel Gervais Christian Bonhomme Guillaume Renaudin Adel Mesbah Arie van der Lee Mark E. Smith Danielle Laurencin |
| author_sort | Saad Sene |
| collection | DOAJ |
| description | Despite the extensive range of investigations on boronic acids (R-B(OH)2), some aspects of their reactivity still need to be explored. This is the case for the coordination chemistry of boronate anions (R-B(OH)3−), which has only recently been started to be studied. The purpose of this review is to summarize some of the key features of boronate ligands (and of their cyclic derivatives, benzoxaborolates) in materials: (i) coordination properties; (ii) spectroscopic signatures; and (iii) emerging applications. |
| first_indexed | 2024-04-13T07:29:19Z |
| format | Article |
| id | doaj.art-82d563ccac564bdb947a28c8fe7be633 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-04-13T07:29:19Z |
| publishDate | 2016-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-82d563ccac564bdb947a28c8fe7be6332022-12-22T02:56:24ZengMDPI AGCrystals2073-43522016-05-01654810.3390/cryst6050048cryst6050048Coordination Networks Based on Boronate and Benzoxaborolate LigandsSaad Sene0Marie Alix Pizzoccaro1Joris Vezzani2Marc Reinholdt3Philippe Gaveau4Dorothée Berthomieu5Sylvie Bégu6Christel Gervais7Christian Bonhomme8Guillaume Renaudin9Adel Mesbah10Arie van der Lee11Mark E. Smith12Danielle Laurencin13Institut Charles Gerhardt de Montpellier, UMR 5253, CNRS UM ENSCM, Montpellier 34095, FranceInstitut Charles Gerhardt de Montpellier, UMR 5253, CNRS UM ENSCM, Montpellier 34095, FranceInstitut Charles Gerhardt de Montpellier, UMR 5253, CNRS UM ENSCM, Montpellier 34095, FranceInstitut Charles Gerhardt de Montpellier, UMR 5253, CNRS UM ENSCM, Montpellier 34095, FranceInstitut Charles Gerhardt de Montpellier, UMR 5253, CNRS UM ENSCM, Montpellier 34095, FranceInstitut Charles Gerhardt de Montpellier, UMR 5253, CNRS UM ENSCM, Montpellier 34095, FranceInstitut Charles Gerhardt de Montpellier, UMR 5253, CNRS UM ENSCM, Montpellier 34095, FranceLaboratoire de Chimie de la Matière Condensée de Paris, UMR 7574, Sorbonne Universités, UPMC Univ Paris 06, CNRS, Collège de France, Paris 75252, FranceLaboratoire de Chimie de la Matière Condensée de Paris, UMR 7574, Sorbonne Universités, UPMC Univ Paris 06, CNRS, Collège de France, Paris 75252, FranceUniversité Clermont Auvergne, SIGMA Clermont, Institut de Chimie de Clermont-Ferrand, BP 10448, F-63000 Clermont-Ferrand, FranceInstitut de Chimie Séparative de Marcoule, UMR 5257, CNRS CEA UM ENSCM, Bagnols-sur-Cèze 30207, FranceInstitut Européen des Membranes, CNRS-UMR 5635, UM, Montpellier 34095, FranceVice-Chancellor’s Office, University House, Lancaster University, Lancaster LA1 4YW, UKInstitut Charles Gerhardt de Montpellier, UMR 5253, CNRS UM ENSCM, Montpellier 34095, FranceDespite the extensive range of investigations on boronic acids (R-B(OH)2), some aspects of their reactivity still need to be explored. This is the case for the coordination chemistry of boronate anions (R-B(OH)3−), which has only recently been started to be studied. The purpose of this review is to summarize some of the key features of boronate ligands (and of their cyclic derivatives, benzoxaborolates) in materials: (i) coordination properties; (ii) spectroscopic signatures; and (iii) emerging applications.http://www.mdpi.com/2073-4352/6/5/48boronatetri-hydroxyboratebenzoxaborolateboronic acidbenzoxaborolecoordination polymersolid state NMRIR spectroscopycrystallographyDFT |
| spellingShingle | Saad Sene Marie Alix Pizzoccaro Joris Vezzani Marc Reinholdt Philippe Gaveau Dorothée Berthomieu Sylvie Bégu Christel Gervais Christian Bonhomme Guillaume Renaudin Adel Mesbah Arie van der Lee Mark E. Smith Danielle Laurencin Coordination Networks Based on Boronate and Benzoxaborolate Ligands Crystals boronate tri-hydroxyborate benzoxaborolate boronic acid benzoxaborole coordination polymer solid state NMR IR spectroscopy crystallography DFT |
| title | Coordination Networks Based on Boronate and Benzoxaborolate Ligands |
| title_full | Coordination Networks Based on Boronate and Benzoxaborolate Ligands |
| title_fullStr | Coordination Networks Based on Boronate and Benzoxaborolate Ligands |
| title_full_unstemmed | Coordination Networks Based on Boronate and Benzoxaborolate Ligands |
| title_short | Coordination Networks Based on Boronate and Benzoxaborolate Ligands |
| title_sort | coordination networks based on boronate and benzoxaborolate ligands |
| topic | boronate tri-hydroxyborate benzoxaborolate boronic acid benzoxaborole coordination polymer solid state NMR IR spectroscopy crystallography DFT |
| url | http://www.mdpi.com/2073-4352/6/5/48 |
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