Unveiling the MIL-53(Al) MOF: Tuning Photoluminescence and Structural Properties via Volatile Organic Compounds Interactions
MIL-53(Al) is a metal-organic framework (MOF) with unique properties, including structural flexibility, thermal stability, and luminescence. Its ability to adsorb volatile organic compounds (VOCs) and water vapor makes it a promising platform for sensing applications. This study investigated the ads...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2024-02-01
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| Series: | Nanomaterials |
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| Online Access: | https://www.mdpi.com/2079-4991/14/5/388 |
| _version_ | 1797264094447796224 |
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| author | Tanzeel Ul Rehman Simonpietro Agnello Franco Mario Gelardi Martina Maria Calvino Giuseppe Lazzara Gianpiero Buscarino Marco Cannas |
| author_facet | Tanzeel Ul Rehman Simonpietro Agnello Franco Mario Gelardi Martina Maria Calvino Giuseppe Lazzara Gianpiero Buscarino Marco Cannas |
| author_sort | Tanzeel Ul Rehman |
| collection | DOAJ |
| description | MIL-53(Al) is a metal-organic framework (MOF) with unique properties, including structural flexibility, thermal stability, and luminescence. Its ability to adsorb volatile organic compounds (VOCs) and water vapor makes it a promising platform for sensing applications. This study investigated the adsorption mechanism of MIL-53(Al) with different VOCs, including ketones, alcohols, aromatics, and water molecules, focusing on structural transformations due to pore size variation and photoluminescence properties. The reported results assess MIL-53(Al) selectivity towards different VOCs and provide insights into their fundamental properties and potential applications in sensing. |
| first_indexed | 2024-04-25T00:23:26Z |
| format | Article |
| id | doaj.art-82d7dab5ca084ac691561048ab7981e5 |
| institution | Directory Open Access Journal |
| issn | 2079-4991 |
| language | English |
| last_indexed | 2024-04-25T00:23:26Z |
| publishDate | 2024-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Nanomaterials |
| spelling | doaj.art-82d7dab5ca084ac691561048ab7981e52024-03-12T16:51:25ZengMDPI AGNanomaterials2079-49912024-02-0114538810.3390/nano14050388Unveiling the MIL-53(Al) MOF: Tuning Photoluminescence and Structural Properties via Volatile Organic Compounds InteractionsTanzeel Ul Rehman0Simonpietro Agnello1Franco Mario Gelardi2Martina Maria Calvino3Giuseppe Lazzara4Gianpiero Buscarino5Marco Cannas6Dipartimento di Fisica e Chimica−Emilio Segrè, Università degli Studi di Palermo, 90123 Palermo, ItalyDipartimento di Fisica e Chimica−Emilio Segrè, Università degli Studi di Palermo, 90123 Palermo, ItalyDipartimento di Fisica e Chimica−Emilio Segrè, Università degli Studi di Palermo, 90123 Palermo, ItalyDipartimento di Fisica e Chimica−Emilio Segrè, Università degli Studi di Palermo, 90123 Palermo, ItalyDipartimento di Fisica e Chimica−Emilio Segrè, Università degli Studi di Palermo, 90123 Palermo, ItalyDipartimento di Fisica e Chimica−Emilio Segrè, Università degli Studi di Palermo, 90123 Palermo, ItalyDipartimento di Fisica e Chimica−Emilio Segrè, Università degli Studi di Palermo, 90123 Palermo, ItalyMIL-53(Al) is a metal-organic framework (MOF) with unique properties, including structural flexibility, thermal stability, and luminescence. Its ability to adsorb volatile organic compounds (VOCs) and water vapor makes it a promising platform for sensing applications. This study investigated the adsorption mechanism of MIL-53(Al) with different VOCs, including ketones, alcohols, aromatics, and water molecules, focusing on structural transformations due to pore size variation and photoluminescence properties. The reported results assess MIL-53(Al) selectivity towards different VOCs and provide insights into their fundamental properties and potential applications in sensing.https://www.mdpi.com/2079-4991/14/5/388Metal-Organic FrameworksMIL-53(Al)guest-adsorptionstructural transitionsphotoluminescenceVOCs |
| spellingShingle | Tanzeel Ul Rehman Simonpietro Agnello Franco Mario Gelardi Martina Maria Calvino Giuseppe Lazzara Gianpiero Buscarino Marco Cannas Unveiling the MIL-53(Al) MOF: Tuning Photoluminescence and Structural Properties via Volatile Organic Compounds Interactions Nanomaterials Metal-Organic Frameworks MIL-53(Al) guest-adsorption structural transitions photoluminescence VOCs |
| title | Unveiling the MIL-53(Al) MOF: Tuning Photoluminescence and Structural Properties via Volatile Organic Compounds Interactions |
| title_full | Unveiling the MIL-53(Al) MOF: Tuning Photoluminescence and Structural Properties via Volatile Organic Compounds Interactions |
| title_fullStr | Unveiling the MIL-53(Al) MOF: Tuning Photoluminescence and Structural Properties via Volatile Organic Compounds Interactions |
| title_full_unstemmed | Unveiling the MIL-53(Al) MOF: Tuning Photoluminescence and Structural Properties via Volatile Organic Compounds Interactions |
| title_short | Unveiling the MIL-53(Al) MOF: Tuning Photoluminescence and Structural Properties via Volatile Organic Compounds Interactions |
| title_sort | unveiling the mil 53 al mof tuning photoluminescence and structural properties via volatile organic compounds interactions |
| topic | Metal-Organic Frameworks MIL-53(Al) guest-adsorption structural transitions photoluminescence VOCs |
| url | https://www.mdpi.com/2079-4991/14/5/388 |
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