Heterogeneous Catalyst based on Nickel Modified into Indonesian Natural Zeolite in Green Diesel Production from Crude Palm Oil
Green diesel is an alternative renewable and environmentally friendly fuel in the transportation sector. This study aimed to modify Indonesian natural zeolite (NZ) with nickel and apply it as a catalyst in green diesel production from crude palm oil (CPO). The materials were prepared wi...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Universitas Indonesia
2022-10-01
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| Series: | International Journal of Technology |
| Subjects: | |
| Online Access: | https://ijtech.eng.ui.ac.id/article/view/4695 |
| _version_ | 1797963157453406208 |
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| author | Fauzan Ibnu Prihadiyono Witri Wahyu Lestari Riandy Putra Arifti Nur Laily Aqna Indri Sri Cahyani Grandprix T M Kadja |
| author_facet | Fauzan Ibnu Prihadiyono Witri Wahyu Lestari Riandy Putra Arifti Nur Laily Aqna Indri Sri Cahyani Grandprix T M Kadja |
| author_sort | Fauzan Ibnu Prihadiyono |
| collection | DOAJ |
| description | Green diesel is an
alternative renewable and environmentally friendly fuel in the transportation
sector. This study aimed to modify
Indonesian natural zeolite (NZ) with nickel and apply it as a catalyst in green
diesel production from crude palm oil (CPO). The materials were prepared with
different Ni content of 3, 5, and 10 wt.% and characterized in detail using
X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM), Transmission
Electron Microscope (TEM), Fourier Transform infra-red Spectroscopy (FTIR), and
Surface Area Analyzer (SAA). Catalytic tests were performed in a batch reactor
at a temperature of 375 °C and a pressure of 12 bar for 2 hours. Gas
Chromatography-Mass Spectrometry (GC–MS) analysis was used to determine the
liquid product. Based on XRD analysis, the crystallinity of materials tends to
decrease after being modified with Ni. Concomitantly, the presence of Ni was
indicated by new peaks with increasing intensity at 2? = 44°, 55°, and 76°. SEM
analysis shows morphological changes in materials with decreasing particle
sizes. The presence of Ni is also known by the presence of small spheres
scattered in the material and black shades observed in TEM analysis. Based on
IUPAC, the resulting isotherm graph is categorized as type I with type IV loop
hysteresis and classified as micropore with an average pore size is <2 nm.
The highest activity and selectivity on C15 were achieved up to
77.34% and 53.11% when 3% of Ni modified NZ was applied as Catalyst compared to
NZ, and other Ni modified NZ. |
| first_indexed | 2024-04-11T01:25:00Z |
| format | Article |
| id | doaj.art-831bf39d582a4bd5bc4e2d31e623c197 |
| institution | Directory Open Access Journal |
| issn | 2086-9614 2087-2100 |
| language | English |
| last_indexed | 2024-04-11T01:25:00Z |
| publishDate | 2022-10-01 |
| publisher | Universitas Indonesia |
| record_format | Article |
| series | International Journal of Technology |
| spelling | doaj.art-831bf39d582a4bd5bc4e2d31e623c1972023-01-03T10:43:14ZengUniversitas IndonesiaInternational Journal of Technology2086-96142087-21002022-10-0113493194310.14716/ijtech.v13i4.46954695Heterogeneous Catalyst based on Nickel Modified into Indonesian Natural Zeolite in Green Diesel Production from Crude Palm OilFauzan Ibnu Prihadiyono0Witri Wahyu Lestari1Riandy Putra2Arifti Nur Laily Aqna3Indri Sri Cahyani4Grandprix T M Kadja5Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami No.36A, Kentingan–Jebres Surakarta, Central Java, Indonesia, 57126Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami No.36A, Kentingan–Jebres Surakarta, Central Java, Indonesia, 571261. Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami No.36A, Kentingan–Jebres Surakarta, Central Java, Indonesia, 57126 2. Department of CheChemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami No.36A, Kentingan–Jebres Surakarta, Central Java, Indonesia, 57126Universitas SebelasaChemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami No.36A, Kentingan–Jebres Surakarta, Central Java, Indonesia, 571261. Division of Inorganic and Physical Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jalan Ganesha no. 10, Bandung 40132, Indonesia 2. Center for Catalysis and ReGreen diesel is an alternative renewable and environmentally friendly fuel in the transportation sector. This study aimed to modify Indonesian natural zeolite (NZ) with nickel and apply it as a catalyst in green diesel production from crude palm oil (CPO). The materials were prepared with different Ni content of 3, 5, and 10 wt.% and characterized in detail using X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM), Transmission Electron Microscope (TEM), Fourier Transform infra-red Spectroscopy (FTIR), and Surface Area Analyzer (SAA). Catalytic tests were performed in a batch reactor at a temperature of 375 °C and a pressure of 12 bar for 2 hours. Gas Chromatography-Mass Spectrometry (GC–MS) analysis was used to determine the liquid product. Based on XRD analysis, the crystallinity of materials tends to decrease after being modified with Ni. Concomitantly, the presence of Ni was indicated by new peaks with increasing intensity at 2? = 44°, 55°, and 76°. SEM analysis shows morphological changes in materials with decreasing particle sizes. The presence of Ni is also known by the presence of small spheres scattered in the material and black shades observed in TEM analysis. Based on IUPAC, the resulting isotherm graph is categorized as type I with type IV loop hysteresis and classified as micropore with an average pore size is <2 nm. The highest activity and selectivity on C15 were achieved up to 77.34% and 53.11% when 3% of Ni modified NZ was applied as Catalyst compared to NZ, and other Ni modified NZ.https://ijtech.eng.ui.ac.id/article/view/4695crude palm oilgreen dieselhydrodeoxygenationnatural zeolitenickel |
| spellingShingle | Fauzan Ibnu Prihadiyono Witri Wahyu Lestari Riandy Putra Arifti Nur Laily Aqna Indri Sri Cahyani Grandprix T M Kadja Heterogeneous Catalyst based on Nickel Modified into Indonesian Natural Zeolite in Green Diesel Production from Crude Palm Oil International Journal of Technology crude palm oil green diesel hydrodeoxygenation natural zeolite nickel |
| title | Heterogeneous Catalyst based on Nickel Modified into Indonesian Natural Zeolite in Green Diesel Production from Crude Palm Oil |
| title_full | Heterogeneous Catalyst based on Nickel Modified into Indonesian Natural Zeolite in Green Diesel Production from Crude Palm Oil |
| title_fullStr | Heterogeneous Catalyst based on Nickel Modified into Indonesian Natural Zeolite in Green Diesel Production from Crude Palm Oil |
| title_full_unstemmed | Heterogeneous Catalyst based on Nickel Modified into Indonesian Natural Zeolite in Green Diesel Production from Crude Palm Oil |
| title_short | Heterogeneous Catalyst based on Nickel Modified into Indonesian Natural Zeolite in Green Diesel Production from Crude Palm Oil |
| title_sort | heterogeneous catalyst based on nickel modified into indonesian natural zeolite in green diesel production from crude palm oil |
| topic | crude palm oil green diesel hydrodeoxygenation natural zeolite nickel |
| url | https://ijtech.eng.ui.ac.id/article/view/4695 |
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