Exploration of the Effect of Oxygen on Superconductivity in MgB<sub>2</sub> Bulk by Using Boron Powder with Different Particle and Purification

In this study, boron powder with different particle sizes was purified by both chemical and heat treatment methods. The reduction in the particle size can improve the chemical purification with no effort on the heat treatment. The superconducting properties of the powder drastically changed even wit...

Full description

Bibliographic Details
Main Authors: Liangqun Yang, Hongli Suo, Lin Ma, Min Liu, Wanli Zhao, Jianhua Liu, Lei Wang, Zili Zhang, Qiuliang Wang
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/11/3/278
_version_ 1797541685559820288
author Liangqun Yang
Hongli Suo
Lin Ma
Min Liu
Wanli Zhao
Jianhua Liu
Lei Wang
Zili Zhang
Qiuliang Wang
author_facet Liangqun Yang
Hongli Suo
Lin Ma
Min Liu
Wanli Zhao
Jianhua Liu
Lei Wang
Zili Zhang
Qiuliang Wang
author_sort Liangqun Yang
collection DOAJ
description In this study, boron powder with different particle sizes was purified by both chemical and heat treatment methods. The reduction in the particle size can improve the chemical purification with no effort on the heat treatment. The superconducting properties of the powder drastically changed even with only a partial elimination of oxygen. On the one hand, less oxygen content resulted in high <i>T</i><sub>c</sub> and <i>J</i><sub>c</sub> values under the low magnetic field, and most importantly, a significant improvement in the superconducting connectivity (<i>A</i><sub>f</sub> value). On the other hand, the degradation of <i>J</i><sub>c</sub> under a high field and a change in the pinning mechanism were also found, along with decreasing oxygen. This result indicated that oxygen, probably MgO, might act as the pinning center and as an obstacle for the supercurrent in MgB<sub>2</sub> at the same time. This work paves the way for obtaining pure oxygen-free MgB<sub>2</sub> and understanding the real effect of oxygen in MgB<sub>2</sub>.
first_indexed 2024-03-10T13:19:23Z
format Article
id doaj.art-83252068b1fc49d085995b253d1e1259
institution Directory Open Access Journal
issn 2073-4352
language English
last_indexed 2024-03-10T13:19:23Z
publishDate 2021-03-01
publisher MDPI AG
record_format Article
series Crystals
spelling doaj.art-83252068b1fc49d085995b253d1e12592023-11-21T10:07:05ZengMDPI AGCrystals2073-43522021-03-0111327810.3390/cryst11030278Exploration of the Effect of Oxygen on Superconductivity in MgB<sub>2</sub> Bulk by Using Boron Powder with Different Particle and PurificationLiangqun Yang0Hongli Suo1Lin Ma2Min Liu3Wanli Zhao4Jianhua Liu5Lei Wang6Zili Zhang7Qiuliang Wang8Beijing University of Technology, Beijing 100124, ChinaBeijing University of Technology, Beijing 100124, ChinaBeijing University of Technology, Beijing 100124, ChinaBeijing University of Technology, Beijing 100124, ChinaBeijing University of Technology, Beijing 100124, ChinaInstitute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, ChinaInstitute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, ChinaInstitute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, ChinaInstitute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, ChinaIn this study, boron powder with different particle sizes was purified by both chemical and heat treatment methods. The reduction in the particle size can improve the chemical purification with no effort on the heat treatment. The superconducting properties of the powder drastically changed even with only a partial elimination of oxygen. On the one hand, less oxygen content resulted in high <i>T</i><sub>c</sub> and <i>J</i><sub>c</sub> values under the low magnetic field, and most importantly, a significant improvement in the superconducting connectivity (<i>A</i><sub>f</sub> value). On the other hand, the degradation of <i>J</i><sub>c</sub> under a high field and a change in the pinning mechanism were also found, along with decreasing oxygen. This result indicated that oxygen, probably MgO, might act as the pinning center and as an obstacle for the supercurrent in MgB<sub>2</sub> at the same time. This work paves the way for obtaining pure oxygen-free MgB<sub>2</sub> and understanding the real effect of oxygen in MgB<sub>2</sub>.https://www.mdpi.com/2073-4352/11/3/278boron powderpurificationparticle sizeMgB<sub>2</sub>superconducting connectivity
spellingShingle Liangqun Yang
Hongli Suo
Lin Ma
Min Liu
Wanli Zhao
Jianhua Liu
Lei Wang
Zili Zhang
Qiuliang Wang
Exploration of the Effect of Oxygen on Superconductivity in MgB<sub>2</sub> Bulk by Using Boron Powder with Different Particle and Purification
Crystals
boron powder
purification
particle size
MgB<sub>2</sub>
superconducting connectivity
title Exploration of the Effect of Oxygen on Superconductivity in MgB<sub>2</sub> Bulk by Using Boron Powder with Different Particle and Purification
title_full Exploration of the Effect of Oxygen on Superconductivity in MgB<sub>2</sub> Bulk by Using Boron Powder with Different Particle and Purification
title_fullStr Exploration of the Effect of Oxygen on Superconductivity in MgB<sub>2</sub> Bulk by Using Boron Powder with Different Particle and Purification
title_full_unstemmed Exploration of the Effect of Oxygen on Superconductivity in MgB<sub>2</sub> Bulk by Using Boron Powder with Different Particle and Purification
title_short Exploration of the Effect of Oxygen on Superconductivity in MgB<sub>2</sub> Bulk by Using Boron Powder with Different Particle and Purification
title_sort exploration of the effect of oxygen on superconductivity in mgb sub 2 sub bulk by using boron powder with different particle and purification
topic boron powder
purification
particle size
MgB<sub>2</sub>
superconducting connectivity
url https://www.mdpi.com/2073-4352/11/3/278
work_keys_str_mv AT liangqunyang explorationoftheeffectofoxygenonsuperconductivityinmgbsub2subbulkbyusingboronpowderwithdifferentparticleandpurification
AT honglisuo explorationoftheeffectofoxygenonsuperconductivityinmgbsub2subbulkbyusingboronpowderwithdifferentparticleandpurification
AT linma explorationoftheeffectofoxygenonsuperconductivityinmgbsub2subbulkbyusingboronpowderwithdifferentparticleandpurification
AT minliu explorationoftheeffectofoxygenonsuperconductivityinmgbsub2subbulkbyusingboronpowderwithdifferentparticleandpurification
AT wanlizhao explorationoftheeffectofoxygenonsuperconductivityinmgbsub2subbulkbyusingboronpowderwithdifferentparticleandpurification
AT jianhualiu explorationoftheeffectofoxygenonsuperconductivityinmgbsub2subbulkbyusingboronpowderwithdifferentparticleandpurification
AT leiwang explorationoftheeffectofoxygenonsuperconductivityinmgbsub2subbulkbyusingboronpowderwithdifferentparticleandpurification
AT zilizhang explorationoftheeffectofoxygenonsuperconductivityinmgbsub2subbulkbyusingboronpowderwithdifferentparticleandpurification
AT qiuliangwang explorationoftheeffectofoxygenonsuperconductivityinmgbsub2subbulkbyusingboronpowderwithdifferentparticleandpurification