Modification of Chitosan Membranes via Methane Ion Beam

Chitosan has been used for biomedical applications in recent years, primarily because of its biocompatibility. A chitosan membrane with a 30 μm thickness was prepared and investigated for its surface modification using methane ions. Methane ions were implanted into the chitosan membrane using a Kauf...

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Main Authors: Nasim Gholami, Babak Jaleh, Reza Golbedaghi, Majid Mojtahedzadeh Larijani, Pikul Wanichapichart, Mahmoud Nasrollahzadeh, Rajender S. Varma
Format: Article
Language:English
Published: MDPI AG 2020-05-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/25/10/2292
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author Nasim Gholami
Babak Jaleh
Reza Golbedaghi
Majid Mojtahedzadeh Larijani
Pikul Wanichapichart
Mahmoud Nasrollahzadeh
Rajender S. Varma
author_facet Nasim Gholami
Babak Jaleh
Reza Golbedaghi
Majid Mojtahedzadeh Larijani
Pikul Wanichapichart
Mahmoud Nasrollahzadeh
Rajender S. Varma
author_sort Nasim Gholami
collection DOAJ
description Chitosan has been used for biomedical applications in recent years, primarily because of its biocompatibility. A chitosan membrane with a 30 μm thickness was prepared and investigated for its surface modification using methane ions. Methane ions were implanted into the chitosan membrane using a Kaufman ion source; bombardment was accomplished using three accelerating voltages of ion beams—30, 55, and 80 kV. The influence of the ion bombardment on morphology, crystallinity, and hydrophilicity was investigated. Attenuated total reflectance Fourier-transform infrared (ATR-FTIR) spectroscopy analysis showed that a triplet bond appeared after the implantation of methane ions (acceleration voltage: 80 kV), culminating in the creation of a more amorphous membrane structure. The analyses of atomic force microscopy (AFM) images showed that, with the increase in bombardment energy, the roughness of the surface changed. These results revealed that ion bombardment improved the hydrophilicity of the membranes and the water fluxes of chitosan membranes altered after methane ion bombardment.
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spelling doaj.art-833017a207714317a35153fe524ded552023-11-20T00:17:53ZengMDPI AGMolecules1420-30492020-05-012510229210.3390/molecules25102292Modification of Chitosan Membranes via Methane Ion BeamNasim Gholami0Babak Jaleh1Reza Golbedaghi2Majid Mojtahedzadeh Larijani3Pikul Wanichapichart4Mahmoud Nasrollahzadeh5Rajender S. Varma6Physics Department, Bu-Ali Sina University, Hamedan 65174, IranPhysics Department, Bu-Ali Sina University, Hamedan 65174, IranChemistry Department, Payame Noor University, Tehran 19395–4697, IranPhysics and Accelerators Research School, Nuclear Science and Technology Research Institute, Tehran 14155–1339, IranDepartment of Physics, Membrane Science and Technology Research Center, Prince of Songkla University, Songkhla 90110, ThailandDepartment of Chemistry, Faculty of Science, University of Qom, Qom 3716146611, IranRegional Centre of Advanced Technologies and Materials, Palacky University, Šlechtitelů 27, 783 71 Olomouc, Czech RepublicChitosan has been used for biomedical applications in recent years, primarily because of its biocompatibility. A chitosan membrane with a 30 μm thickness was prepared and investigated for its surface modification using methane ions. Methane ions were implanted into the chitosan membrane using a Kaufman ion source; bombardment was accomplished using three accelerating voltages of ion beams—30, 55, and 80 kV. The influence of the ion bombardment on morphology, crystallinity, and hydrophilicity was investigated. Attenuated total reflectance Fourier-transform infrared (ATR-FTIR) spectroscopy analysis showed that a triplet bond appeared after the implantation of methane ions (acceleration voltage: 80 kV), culminating in the creation of a more amorphous membrane structure. The analyses of atomic force microscopy (AFM) images showed that, with the increase in bombardment energy, the roughness of the surface changed. These results revealed that ion bombardment improved the hydrophilicity of the membranes and the water fluxes of chitosan membranes altered after methane ion bombardment.https://www.mdpi.com/1420-3049/25/10/2292chitosan membranemethane ionsurface modificationcharacterizationATR-FTIR
spellingShingle Nasim Gholami
Babak Jaleh
Reza Golbedaghi
Majid Mojtahedzadeh Larijani
Pikul Wanichapichart
Mahmoud Nasrollahzadeh
Rajender S. Varma
Modification of Chitosan Membranes via Methane Ion Beam
Molecules
chitosan membrane
methane ion
surface modification
characterization
ATR-FTIR
title Modification of Chitosan Membranes via Methane Ion Beam
title_full Modification of Chitosan Membranes via Methane Ion Beam
title_fullStr Modification of Chitosan Membranes via Methane Ion Beam
title_full_unstemmed Modification of Chitosan Membranes via Methane Ion Beam
title_short Modification of Chitosan Membranes via Methane Ion Beam
title_sort modification of chitosan membranes via methane ion beam
topic chitosan membrane
methane ion
surface modification
characterization
ATR-FTIR
url https://www.mdpi.com/1420-3049/25/10/2292
work_keys_str_mv AT nasimgholami modificationofchitosanmembranesviamethaneionbeam
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AT majidmojtahedzadehlarijani modificationofchitosanmembranesviamethaneionbeam
AT pikulwanichapichart modificationofchitosanmembranesviamethaneionbeam
AT mahmoudnasrollahzadeh modificationofchitosanmembranesviamethaneionbeam
AT rajendersvarma modificationofchitosanmembranesviamethaneionbeam