Optimizing the magnetic separation of strontium ion using modified zeolite with nano iron particles

This work aims at investigating the adsorption behavior of a magnetic adsorbent (zeolite/Fe0) consisting of zeolite and nano iron particles toward strontium (Sr) by batch kinetic and equilibrium studies. In the kinetic data demonstration, pseudo-first-order, pseudo-second-order, Elovich and diffusio...

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Main Authors: Tamer Shubair, Atsushi Tahara, Shahjalal Khandaker
Format: Article
Language:English
Published: Elsevier 2022-12-01
Series:Case Studies in Chemical and Environmental Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666016422000652
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author Tamer Shubair
Atsushi Tahara
Shahjalal Khandaker
author_facet Tamer Shubair
Atsushi Tahara
Shahjalal Khandaker
author_sort Tamer Shubair
collection DOAJ
description This work aims at investigating the adsorption behavior of a magnetic adsorbent (zeolite/Fe0) consisting of zeolite and nano iron particles toward strontium (Sr) by batch kinetic and equilibrium studies. In the kinetic data demonstration, pseudo-first-order, pseudo-second-order, Elovich and diffusion-based models were employed. The equilibrium data were analyzed using Langmuir, Freundlich, Dubinin–Radushkevich, Redlich–Peterson and Temkin isotherm models. Statistical analyses were also used to optimize the regression goodness and assess the model sensitive parameters that can affect the Sr removal process reliability. The adsorption kinetic data were found to be well fitted with the pseudo-second-order model, which showed that the process was quite rapid. The Langmuir adsorption isotherm was the best model to describe the adsorption process, indicating that the Sr removal mechanism was monolayer chemisorption involving ion exchange. It was confirmed that the zeolite/Fe0 is an appropriate adsorbent material for the removal of Sr from contaminated water.
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spelling doaj.art-83352634d35e4813a6ab1cea7db7b2422022-12-22T04:21:52ZengElsevierCase Studies in Chemical and Environmental Engineering2666-01642022-12-016100243Optimizing the magnetic separation of strontium ion using modified zeolite with nano iron particlesTamer Shubair0Atsushi Tahara1Shahjalal Khandaker2Department of Earth Resources Engineering, Faculty of Engineering, Kyushu University, 744 Motooka, Nishiku, Fukuoka, 819-0395, Japan; Corresponding author.Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Kasuga-Koen Kasuga, Fukuoka, 816-8580, JapanDepartment of Textile Engineering, Dhaka University of Engineering & Technology, Gazipur, 1707, BangladeshThis work aims at investigating the adsorption behavior of a magnetic adsorbent (zeolite/Fe0) consisting of zeolite and nano iron particles toward strontium (Sr) by batch kinetic and equilibrium studies. In the kinetic data demonstration, pseudo-first-order, pseudo-second-order, Elovich and diffusion-based models were employed. The equilibrium data were analyzed using Langmuir, Freundlich, Dubinin–Radushkevich, Redlich–Peterson and Temkin isotherm models. Statistical analyses were also used to optimize the regression goodness and assess the model sensitive parameters that can affect the Sr removal process reliability. The adsorption kinetic data were found to be well fitted with the pseudo-second-order model, which showed that the process was quite rapid. The Langmuir adsorption isotherm was the best model to describe the adsorption process, indicating that the Sr removal mechanism was monolayer chemisorption involving ion exchange. It was confirmed that the zeolite/Fe0 is an appropriate adsorbent material for the removal of Sr from contaminated water.http://www.sciencedirect.com/science/article/pii/S2666016422000652StrontiumKineticIsothermStatistical analysesZeolite
spellingShingle Tamer Shubair
Atsushi Tahara
Shahjalal Khandaker
Optimizing the magnetic separation of strontium ion using modified zeolite with nano iron particles
Case Studies in Chemical and Environmental Engineering
Strontium
Kinetic
Isotherm
Statistical analyses
Zeolite
title Optimizing the magnetic separation of strontium ion using modified zeolite with nano iron particles
title_full Optimizing the magnetic separation of strontium ion using modified zeolite with nano iron particles
title_fullStr Optimizing the magnetic separation of strontium ion using modified zeolite with nano iron particles
title_full_unstemmed Optimizing the magnetic separation of strontium ion using modified zeolite with nano iron particles
title_short Optimizing the magnetic separation of strontium ion using modified zeolite with nano iron particles
title_sort optimizing the magnetic separation of strontium ion using modified zeolite with nano iron particles
topic Strontium
Kinetic
Isotherm
Statistical analyses
Zeolite
url http://www.sciencedirect.com/science/article/pii/S2666016422000652
work_keys_str_mv AT tamershubair optimizingthemagneticseparationofstrontiumionusingmodifiedzeolitewithnanoironparticles
AT atsushitahara optimizingthemagneticseparationofstrontiumionusingmodifiedzeolitewithnanoironparticles
AT shahjalalkhandaker optimizingthemagneticseparationofstrontiumionusingmodifiedzeolitewithnanoironparticles