Cadmium distribution coefficeints and Cd transport in structured soils

In the case of cadmium transport via soil macropores, the short-term duration of an interaction between the reactive solute in aqueous phase and soil, as well as cadmium precipitation or adsorption on particles < 10-5 m should be taken into account. Two distribution coefficients are proposed...

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Main Authors: Ľ. Lichner, A. Čipáková
Format: Article
Language:English
Published: Czech Academy of Agricultural Sciences 2002-03-01
Series:Plant, Soil and Environment
Subjects:
Online Access:https://pse.agriculturejournals.cz/artkey/pse-200203-0002_cadmium-distribution-coefficeints-and-cd-transport-in-structured-soils.php
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author Ľ. Lichner
A. Čipáková
author_facet Ľ. Lichner
A. Čipáková
author_sort Ľ. Lichner
collection DOAJ
description In the case of cadmium transport via soil macropores, the short-term duration of an interaction between the reactive solute in aqueous phase and soil, as well as cadmium precipitation or adsorption on particles < 10-5 m should be taken into account. Two distribution coefficients are proposed for predicting the cadmium transport in a structured soil: the matrix distribution coefficient Kdm, equal to the equilibrium distribution coefficient Kdeq and estimated using the conventional batch technique, and the macropore distribution coefficient KdM, estimated using the modified batch technique. It was found that the conventional approach (using the coefficient Kdeq only) would underestimate a penetration of the part of Cd transported in the macropores about 255-times in the loamy-sand soil in Kalinkovo, 20-times in the loam soil in Macov, and 122-times in the clay soil in Jurová in comparison with the approach proposed in this study.
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spelling doaj.art-83745fc241484b1aa9b925cd3fc46e9b2023-02-23T03:44:45ZengCzech Academy of Agricultural SciencesPlant, Soil and Environment1214-11781805-93682002-03-014839610010.17221/4206-PSEpse-200203-0002Cadmium distribution coefficeints and Cd transport in structured soilsĽ. Lichner0A. Čipáková1Institute of Hydrology, Slovak Academy of Sciences, Bratislava, Slovak RepublicInstitute of Hydrology, Slovak Academy of Sciences, Bratislava, Slovak RepublicIn the case of cadmium transport via soil macropores, the short-term duration of an interaction between the reactive solute in aqueous phase and soil, as well as cadmium precipitation or adsorption on particles < 10-5 m should be taken into account. Two distribution coefficients are proposed for predicting the cadmium transport in a structured soil: the matrix distribution coefficient Kdm, equal to the equilibrium distribution coefficient Kdeq and estimated using the conventional batch technique, and the macropore distribution coefficient KdM, estimated using the modified batch technique. It was found that the conventional approach (using the coefficient Kdeq only) would underestimate a penetration of the part of Cd transported in the macropores about 255-times in the loamy-sand soil in Kalinkovo, 20-times in the loam soil in Macov, and 122-times in the clay soil in Jurová in comparison with the approach proposed in this study.https://pse.agriculturejournals.cz/artkey/pse-200203-0002_cadmium-distribution-coefficeints-and-cd-transport-in-structured-soils.phpcadmiumdistribution coefficientpenetrationstructured soil
spellingShingle Ľ. Lichner
A. Čipáková
Cadmium distribution coefficeints and Cd transport in structured soils
Plant, Soil and Environment
cadmium
distribution coefficient
penetration
structured soil
title Cadmium distribution coefficeints and Cd transport in structured soils
title_full Cadmium distribution coefficeints and Cd transport in structured soils
title_fullStr Cadmium distribution coefficeints and Cd transport in structured soils
title_full_unstemmed Cadmium distribution coefficeints and Cd transport in structured soils
title_short Cadmium distribution coefficeints and Cd transport in structured soils
title_sort cadmium distribution coefficeints and cd transport in structured soils
topic cadmium
distribution coefficient
penetration
structured soil
url https://pse.agriculturejournals.cz/artkey/pse-200203-0002_cadmium-distribution-coefficeints-and-cd-transport-in-structured-soils.php
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